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The title compound, hexacarbonyl-1
3C,2
3C-
-dicyclohexylphosphido-1:2
2P-bis(dicyclohexylphosphine)-1
P,2
P-
-hydrido-dirhenium(Re-Re), [Re2H(C12H22P)(C12H23P)2(CO)6], has an Re-Re bond length of 3.2185 (8) Å which is symmetrically bridged by a H and a P atom. Two terminal PH(C6H11)2 ligands adopt cis positions with respect to the phosphido bridge and have a mutually trans configuration.
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