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Reaction of carbazole with barium metal in dry tetrahydrofuran yields colourless blocks of the title compound, [Ba(C4H8O)5](C12H8N)2.C4H8O. The structure contains sevenfold-coordinated barium counter cations, which are surrounded by two carbazole monoanions and five tetrahydrofuran molecules in a C2 symmetric environment.
Supporting information
 | Crystallographic Information File (CIF) Contains datablocks Carbazole-barium, global |
 | Structure factor file (SHELXL table format) Supplementary material |
 | Portable Document Format (PDF) file Supplementary material |
CCDC reference: 129003

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