4-Methylpyridinium Pentachloro(4-methylpyridine-N)titanate(IV) Acetonitrile Solvate at 143K

Hensen, K.; Pickel, P.; Lemke, A.; Bolte, M.

doi:10.1107/S0108270197008949

4-Methylpyridinium Pentachloro(4-methylpyridine-N)titanate(IV) Acetonitrile Solvate at 143K

K. Hensen, P. Pickel, A. Lemke and M. Bolte

The structure of the title compound, (C₆H₈N)[TiCl₅(C₆H₇N)].C₂H₃N, consists of discrete complexes in which the Ti atom has a distorted pseudo-octahedral coordination with an N-hydro-4-methylpyridinium cation as counterion. The 4-methylpyridine ligand and one chloro ligand occupy axial positions with the other four chloro ligands in the equatorial plane. The acetonitrile solvent molecule occupies a cavity in the structure.

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4-Methylpyridinium Pentachloro(4-methylpyridine-N)titanate(IV) Acetonitrile Solvate at 143K

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	Crystallographic Information File (CIF) Contains datablocks he15, global
	Structure factor file (CIF format) Contains datablock he15