Aqua(4,4'-dicarbomethoxy-2,2'-bipyridine-N,N')(3,6-dichloro-4,5-dihydroxy-1,2-benzoquinonato-O4,O5)copper(II) Acetonitrile Hemisolvate

Zheng, L.-M.; Schmalle, H.W.; Ferlay, S.; Decurtins, S.

doi:10.1107/S0108270198006507

Aqua(4,4'-dicarbomethoxy-2,2'-bipyridine-N,N')(3,6-dichloro-4,5-dihydroxy-1,2-benzoquinonato-O⁴,O⁵)copper(II) Acetonitrile Hemisolvate

L.-M. Zheng, H. W. Schmalle, S. Ferlay and S. Decurtins

The title compound, [Cu(C₆Cl₂O₄)(C₁₄H₁₂N₂O₄)(H₂O)].0.5CH₃CN, adopts a slightly distorted square-pyramidal geometry around the five coordinated copper(II) atoms, where the bidentate benzoquinone anion and the bidentate bipyridine ligand form the basal plane. The apical elongated position is occupied by a water molecule. The acetonitrile solvate molecule is disordered.

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Aqua(4,4'-dicarbomethoxy-2,2'-bipyridine-N,N')(3,6-dichloro-4,5-dihydroxy-1,2-benzoquinonato-O⁴,O⁵)copper(II) Acetonitrile Hemisolvate

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	Crystallographic Information File (CIF) Contains datablocks lim4rev, global
	Structure factor file (CIF format) Contains datablock lim4rev