An ABC-ring Analogue of Paclitaxel (TaxolTM)

Banwell, M.G.; Hockless, D.C.R.; Peters, S.C.

doi:10.1107/S0108270195010869

An ABC-ring Analogue of Paclitaxel (Taxol^TM)

M. G. Banwell, D. C. R. Hockless and S. C. Peters

The X-ray crystal structure determination of the title compound (C₂₀H₂₂BrNO₅, systematic name methyl 14-bromo-6-methoxy-1,3-dioxo-2,3,3a,9,10,11,12,13,13a,13b-decahydro-1H-8,12-methanocyclodeca[e]isoindol-12-yl acetate), an ABC-ring analogue of the diterpene paclitaxel reveals that the stereochemical relationships between C(3), C(4) and C(5) (C13a, C13b and C3a, respectively, by systematic numbering) are the same as observed in the natural product.

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An ABC-ring Analogue of Paclitaxel (Taxol^TM)

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	Crystallographic Information File (CIF) Contains datablock mgb2
	Structure factor file (CIF format) Supplementary material