A Cyano-Bridged Ionic Pair Complex: [FeNd2(CN)6(C10H8N2)4(H2 O)8][Fe(CN)6].8H2O

Yi, T.; Gao, S.; Chen, X.-W.; Yan, C.-H.; Li, B.-G.

doi:10.1107/S0108270197012675

A Cyano-Bridged Ionic Pair Complex: [FeNd₂(CN)₆(C₁₀H₈N₂)₄(H₂ O)₈][Fe(CN)₆].8H₂O

T. Yi, S. Gao, X.-W. Chen, C.-H. Yan and B.-G. Li

The title compound, octaaqua-2 [kappa]

⁴O,3

⁴O-tetrakis(2,2'-bipyridyl)-2 [kappa]

⁴N,N';3

⁴N,N'- di--cyano-1 [kappa]

C:2

N;1

C:3

N-tetracyano-1 [kappa]

⁴C-irondineodymium hexacyanoferrate octahydrate, is an ion-pair complex composed of an octahedral hexacyanoferrate(III) anion, a centrosymmetric cyano-linked [NdFeNd] trinuclear cation, and eight solvate water molecules.

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A Cyano-Bridged Ionic Pair Complex: [FeNd₂(CN)₆(C₁₀H₈N₂)₄(H₂ O)₈][Fe(CN)₆].8H₂O

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	Crystallographic Information File (CIF) Contains datablock NdFeCN
	Structure factor file (CIF format) Contains datablock ndfe