Penta­chloro-1,3,6-tris­(diethyl­phenyl­phosphino)­dirhenium(II,III)

The title complex [systematic name: penta­chloro-1[kappa]³Cl,2[kappa]²Cl-tris(diethylphenylphosphino)-1[kappa]P,2[kappa]²P-dirhenium(II,III)(Re-Re)], 1,3,6-Re₂Cl₅(PEt₂Ph)₃ or [Re₂Cl₅(C₁₀H₁₅P)₃], consists of dirhenium mol­ecules with eclipsed structures similar to those of previously characterized 1,3,6-Re₂Cl₅(PR₃)₃ compounds. The Re-Re bond distance is 2.2262 (3) Å and the metal-metal bond order is 3.5.

S1. Comment

Although many dirhenium compounds with multiple metal–metal bonds and tertiary phosphine ligands (PR₃) of the type Re₂Cl₅(PR₃)₃ are known (Cotton & Walton, 1993), none containing diethylphenylphosphine ligands have been reported previously. Structures have been determined for 1,2,7- and 1,3,6-Re₂Cl₅(trimethylphosphine)₃ and 1,3,6-Re₂Cl₅(triethylphosphine)₃ (Cotton et al., 1990), 1,2,7- and 1,3,6-Re₂Cl₅(dimethylphenylphosphine)₃ (Cotton et al., 1998), and 1,3,6-Re₂Cl₅(tri-n-propylphosphine)₃ (Cotton et al., 1999) and 1,3,6-Re₂Cl₅(dicyclohexylphosphine)₃ (Angaridis et al., 2002). The title compound, (I), was prepared from the quadruply bonded [Re₂Cl₈]^2- ion in a solvent mixture containing a room-temperature ionic liquid.

As expected, the molecular structure of (I) is similar to that of the five previously characterized 1,3,6-Re₂Cl₅(PR₃)₃ compounds. In each molecule, one Re atom is bound to two trans-phosphine ligands, while the other Re atom is bound to one phosphine ligand. The two Re atoms are also bound to one another, with a metal–metal bond order of 3.5. The rotational conformation is essentially eclipsed, as opposed to the somewhat staggered conformations adopted by 1,3,6-Re₂Cl₅(dicyclohexylphosphine)₃ and the two known 1,2,7-Re₂Cl₅(PR₃)₃ complexes. The Re—Re bond distance of 2.2262 (3) Å is slightly longer than those found in the other 1,3,6-Re₂Cl₅(PR₃)₃ compounds. This is presumably due to some additional steric crowding introduced by the larger PEt₂Ph ligands. Average Re—P and Re—Cl bond lengths [2.459 (6) and 2.345 (4) Å, respectively] are well within the ranges [2.425 (4)–2.478 (5) Å for Re—P and 2.313 (4)–2.416 (8) Å for Re—Cl] observed before in these complexes. A threefold disordering of the dirhenium unit is a common feature of multiply-bonded dirhenium complexes of the types Re₂Cl₄(PR₃)₃ and Re₂Cl₅(PR₃)₃ (Cotton et al., 1999), but no such disorder exists in 1,3,6-Re₂Cl₅(PEt₂Ph)₃.

S2. Experimental

Tetra-n-butylammonium octachlorodirhenate(III) (508 mg, 0.445 mmol) was combined with 1-butyl-3-methylimidazolium hexafluorophosphate (7 ml) and ethanol (7 ml) in a round-bottomed flask under a nitrogen atmosphere. Two drops of concentrated hydrochloric acid were added followed by diethylphenylphosphine (1.00 g, 6.02 mmol). The mixture was stirred for 30 min at 298 K. Tetrahydrofuran (15 ml) was added and the mixture was stirred for 1 h. Diethyl ether (60 ml) was added next and the mixture was stirred for 2 h, then allowed to sit for 14 h. This resulted in two distinct liquid layers, i.e. a larger brown–green top layer and a small dark-brown bottom layer. The layers were separated in air using a separatory funnel and the top layer was placed in a large Schlenk flask. Dark crystals of the title compound formed as this solution was allowed to slowly evaporate.

S3. Refinement

H atoms were placed in calculated positions and refined as rifing with C—H distances in the range 0.94–0.98 Å, and U_iso values of 1.2U_eq of the parent atom or 1.5U_eq of the parent atom for methyl groups. The highest peak in the final difference map is located 1.03 Å from atom Re2.

Computing details

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Siemens, 1996); software used to prepare material for publication: SHELXL97.

Figures

Fig. 1. The molecular structure of the title compound drawn with 50% displacement ellipsoids. H atoms have been omitted for clarity.

Pentachloro-1κ³Cl,2κ²Cl-tris(diethylphenylphosphino)-1κP,2κ²P- dirhenium(II,III)(Re—Re)

Crystal data

[Re2Cl5(C10H15P)3]	Dx = 1.927 Mg m^−3
Mr = 1048.22	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pbca	Cell parameters from 4402 reflections
a = 15.5374 (7) Å	θ = 2.4–27.4°
b = 20.7751 (9) Å	µ = 7.22 mm^−1
c = 22.3924 (10) Å	T = 213 K
V = 7228.1 (6) Å^3	Plate, red
Z = 8	0.12 × 0.11 × 0.08 mm
F(000) = 4040

Data collection

Bruker SMART diffractometer	8235 independent reflections
Radiation source: normal-focus sealed tube	5875 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.053
ω scans	θmax = 27.6°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Blessing, 1995)	h = −20→18
Tmin = 0.410, Tmax = 0.561	k = −21→27
34336 measured reflections	l = −24→28

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.048	H-atom parameters constrained
S = 1.01	w = 1/[σ^2(Fo^2) + (0.01P)^2] where P = (Fo^2 + 2Fc^2)/3
8235 reflections	(Δ/σ)max = 0.009
367 parameters	Δρmax = 1.64 e Å^−3
0 restraints	Δρmin = −1.11 e Å^−3

Special details

Experimental. Data were collected as 0.3deg omega-scans for three different positions of phi. The center of the detector was positioned 50 mm from the crystal at a 2-theta swing angle of -28deg, allowing the collection of a complete and highly redundant data set to at least 55deg 2-theta. Diffraction spots were integrated using an ellisoid-mask profile-fitting routine.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Re1	0.060261 (12)	0.164476 (10)	0.309358 (8)	0.02178 (5)
Re2	0.034854 (12)	0.267171 (10)	0.331621 (8)	0.02161 (5)
Cl1	0.20442 (8)	0.13431 (7)	0.32603 (6)	0.0332 (3)
Cl2	−0.07278 (8)	0.12664 (6)	0.27447 (5)	0.0314 (3)
Cl3	−0.01176 (8)	0.27246 (7)	0.43046 (5)	0.0332 (3)
Cl4	−0.10976 (8)	0.28271 (7)	0.30502 (6)	0.0378 (3)
Cl5	0.06926 (8)	0.33197 (7)	0.24935 (5)	0.0322 (3)
P1	0.02328 (9)	0.10440 (7)	0.40104 (6)	0.0274 (3)
P2	0.09768 (8)	0.16714 (7)	0.20299 (5)	0.0255 (3)
P3	0.17498 (8)	0.29998 (7)	0.37212 (6)	0.0259 (3)
C1	0.0810 (3)	0.1164 (2)	0.4717 (2)	0.0269 (12)
C2	0.0414 (4)	0.1425 (3)	0.5208 (2)	0.0368 (14)
H2A	−0.0161	0.1561	0.5180	0.044*
C3	0.0853 (4)	0.1492 (3)	0.5747 (2)	0.0451 (16)
H3A	0.0571	0.1665	0.6082	0.054*
C4	0.1698 (4)	0.1305 (3)	0.5786 (3)	0.0471 (17)
H4A	0.1999	0.1352	0.6148	0.056*
C5	0.2100 (4)	0.1052 (3)	0.5303 (2)	0.0422 (15)
H5A	0.2680	0.0927	0.5332	0.051*
C6	0.1669 (4)	0.0974 (3)	0.4770 (2)	0.0369 (14)
H6A	0.1954	0.0792	0.4440	0.044*
C7	0.0469 (4)	0.0189 (2)	0.3859 (2)	0.0417 (15)
H7A	0.1094	0.0145	0.3817	0.050*
H7B	0.0300	−0.0059	0.4212	0.050*
C8	0.0057 (4)	−0.0119 (3)	0.3324 (3)	0.0592 (19)
H8A	−0.0562	−0.0064	0.3346	0.089*
H8B	0.0195	−0.0574	0.3318	0.089*
H8C	0.0273	0.0083	0.2963	0.089*
C9	−0.0907 (3)	0.1078 (3)	0.4198 (2)	0.0347 (14)
H9A	−0.1026	0.1502	0.4370	0.042*
H9B	−0.1237	0.1045	0.3826	0.042*
C10	−0.1245 (4)	0.0569 (3)	0.4629 (2)	0.0534 (18)
H10A	−0.1101	0.0144	0.4480	0.080*
H10B	−0.1865	0.0609	0.4663	0.080*
H10C	−0.0983	0.0631	0.5018	0.080*
C11	0.1188 (3)	0.0832 (3)	0.1850 (2)	0.0317 (13)
C12	0.0530 (4)	0.0411 (3)	0.1695 (2)	0.0397 (14)
H12A	−0.0034	0.0570	0.1657	0.048*
C13	0.0680 (4)	−0.0226 (3)	0.1596 (3)	0.0570 (18)
H13A	0.0223	−0.0499	0.1491	0.068*
C14	0.1498 (4)	−0.0468 (3)	0.1648 (3)	0.0587 (19)
H14A	0.1602	−0.0908	0.1582	0.070*
C15	0.2165 (4)	−0.0062 (3)	0.1799 (3)	0.0555 (18)
H15A	0.2727	−0.0225	0.1834	0.067*
C16	0.2011 (4)	0.0580 (3)	0.1899 (2)	0.0402 (14)
H16A	0.2471	0.0853	0.2003	0.048*
C17	0.1949 (3)	0.2098 (3)	0.1818 (2)	0.0305 (13)
H17A	0.1862	0.2556	0.1901	0.037*
H17B	0.2418	0.1949	0.2076	0.037*
C18	0.2241 (3)	0.2030 (3)	0.1167 (2)	0.0387 (15)
H18A	0.2240	0.1579	0.1055	0.058*
H18B	0.2818	0.2203	0.1124	0.058*
H18C	0.1850	0.2266	0.0910	0.058*
C19	0.0104 (3)	0.1932 (3)	0.1544 (2)	0.0348 (14)
H19A	−0.0432	0.1754	0.1705	0.042*
H19B	0.0062	0.2402	0.1577	0.042*
C20	0.0133 (4)	0.1768 (3)	0.0881 (2)	0.0476 (17)
H20A	0.0524	0.2060	0.0679	0.071*
H20B	−0.0438	0.1811	0.0712	0.071*
H20C	0.0333	0.1330	0.0831	0.071*
C21	0.1606 (3)	0.3832 (3)	0.3959 (2)	0.0289 (12)
C22	0.1721 (3)	0.4331 (3)	0.3562 (3)	0.0401 (15)
H22A	0.1880	0.4241	0.3166	0.048*
C23	0.1604 (4)	0.4964 (3)	0.3738 (3)	0.0547 (18)
H23A	0.1689	0.5298	0.3462	0.066*
C24	0.1368 (4)	0.5104 (3)	0.4307 (4)	0.061 (2)
H24A	0.1288	0.5534	0.4425	0.073*
C25	0.1247 (4)	0.4617 (3)	0.4707 (3)	0.0566 (19)
H25A	0.1082	0.4716	0.5100	0.068*
C26	0.1364 (3)	0.3982 (3)	0.4543 (3)	0.0424 (15)
H26A	0.1281	0.3651	0.4824	0.051*
C27	0.2658 (3)	0.3022 (3)	0.3203 (2)	0.0336 (13)
H27A	0.2857	0.2579	0.3143	0.040*
H27B	0.2446	0.3179	0.2818	0.040*
C28	0.3437 (3)	0.3430 (3)	0.3379 (2)	0.0512 (17)
H28A	0.3257	0.3872	0.3440	0.077*
H28B	0.3863	0.3414	0.3062	0.077*
H28C	0.3686	0.3264	0.3745	0.077*
C29	0.2088 (3)	0.2553 (3)	0.4376 (2)	0.0327 (13)
H29A	0.1630	0.2588	0.4675	0.039*
H29B	0.2127	0.2098	0.4263	0.039*
C30	0.2923 (3)	0.2734 (3)	0.4675 (2)	0.0546 (19)
H30A	0.3398	0.2655	0.4403	0.082*
H30B	0.2999	0.2477	0.5033	0.082*
H30C	0.2911	0.3187	0.4781	0.082*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Re1	0.02020 (10)	0.02311 (10)	0.02205 (9)	0.00098 (9)	0.00060 (8)	0.00143 (9)
Re2	0.01974 (10)	0.02304 (10)	0.02207 (9)	0.00016 (9)	−0.00047 (8)	0.00132 (9)
Cl1	0.0243 (7)	0.0403 (8)	0.0349 (7)	0.0084 (6)	−0.0016 (6)	0.0014 (7)
Cl2	0.0247 (7)	0.0370 (8)	0.0326 (7)	−0.0065 (6)	−0.0011 (6)	0.0000 (6)
Cl3	0.0328 (8)	0.0388 (8)	0.0278 (6)	−0.0001 (6)	0.0079 (5)	−0.0010 (6)
Cl4	0.0241 (8)	0.0388 (8)	0.0505 (8)	0.0033 (6)	−0.0076 (6)	0.0037 (7)
Cl5	0.0368 (8)	0.0313 (7)	0.0284 (6)	−0.0018 (6)	−0.0017 (6)	0.0055 (6)
P1	0.0285 (8)	0.0269 (7)	0.0268 (7)	0.0021 (6)	0.0001 (6)	0.0059 (6)
P2	0.0250 (7)	0.0281 (7)	0.0233 (7)	−0.0013 (6)	0.0021 (5)	−0.0014 (6)
P3	0.0221 (8)	0.0301 (8)	0.0256 (7)	−0.0026 (6)	0.0001 (6)	−0.0003 (6)
C1	0.035 (3)	0.021 (3)	0.025 (3)	0.003 (2)	−0.002 (2)	0.008 (2)
C2	0.036 (3)	0.036 (3)	0.038 (3)	0.008 (3)	0.001 (3)	0.004 (3)
C3	0.067 (5)	0.034 (4)	0.033 (3)	0.013 (3)	−0.003 (3)	−0.002 (3)
C4	0.065 (5)	0.041 (4)	0.035 (3)	0.006 (3)	−0.021 (3)	−0.001 (3)
C5	0.041 (4)	0.045 (4)	0.041 (3)	0.007 (3)	−0.009 (3)	0.002 (3)
C6	0.042 (4)	0.039 (3)	0.030 (3)	0.006 (3)	−0.001 (3)	0.006 (3)
C7	0.057 (4)	0.026 (3)	0.042 (3)	0.003 (3)	−0.007 (3)	0.008 (3)
C8	0.093 (5)	0.029 (3)	0.055 (4)	0.008 (3)	−0.010 (4)	−0.002 (3)
C9	0.023 (3)	0.048 (4)	0.033 (3)	−0.006 (3)	0.002 (2)	0.014 (3)
C10	0.046 (4)	0.060 (5)	0.054 (4)	−0.015 (3)	0.008 (3)	0.018 (4)
C11	0.034 (3)	0.034 (3)	0.027 (3)	0.001 (2)	0.005 (2)	−0.006 (3)
C12	0.035 (3)	0.035 (3)	0.049 (3)	0.001 (3)	0.001 (3)	−0.009 (3)
C13	0.043 (4)	0.040 (4)	0.089 (5)	−0.009 (3)	0.015 (4)	−0.017 (4)
C14	0.063 (5)	0.029 (4)	0.084 (5)	−0.001 (3)	0.029 (4)	−0.008 (4)
C15	0.042 (4)	0.041 (4)	0.083 (5)	0.011 (3)	0.015 (4)	−0.006 (4)
C16	0.037 (4)	0.038 (4)	0.046 (3)	0.000 (3)	0.007 (3)	−0.003 (3)
C17	0.029 (3)	0.033 (3)	0.029 (3)	−0.004 (2)	0.006 (2)	0.000 (2)
C18	0.034 (3)	0.048 (4)	0.034 (3)	−0.001 (3)	0.011 (3)	0.004 (3)
C19	0.031 (3)	0.045 (3)	0.028 (3)	0.002 (3)	−0.003 (2)	0.001 (3)
C20	0.054 (4)	0.055 (4)	0.034 (3)	0.001 (3)	−0.011 (3)	−0.001 (3)
C21	0.018 (3)	0.031 (3)	0.038 (3)	−0.004 (2)	−0.003 (2)	−0.002 (3)
C22	0.033 (4)	0.038 (4)	0.049 (4)	−0.008 (3)	−0.003 (3)	0.002 (3)
C23	0.043 (4)	0.040 (4)	0.082 (5)	−0.008 (3)	−0.018 (4)	0.015 (4)
C24	0.040 (4)	0.037 (4)	0.105 (6)	0.003 (3)	−0.019 (4)	−0.023 (5)
C25	0.048 (4)	0.055 (5)	0.067 (5)	0.005 (4)	−0.005 (4)	−0.027 (4)
C26	0.041 (4)	0.039 (4)	0.047 (4)	−0.002 (3)	0.000 (3)	−0.013 (3)
C27	0.023 (3)	0.042 (3)	0.036 (3)	−0.001 (2)	0.004 (2)	−0.006 (3)
C28	0.031 (3)	0.073 (5)	0.049 (4)	−0.015 (3)	0.005 (3)	−0.013 (4)
C29	0.034 (3)	0.033 (3)	0.031 (3)	0.000 (3)	−0.007 (2)	−0.001 (3)
C30	0.037 (4)	0.085 (6)	0.041 (3)	0.004 (4)	−0.012 (3)	0.004 (4)

Geometric parameters (Å, º)

Re1—Re2	2.2262 (3)	C12—H12A	0.9400
Re1—Cl2	2.3453 (12)	C13—C14	1.372 (8)
Re1—Cl1	2.3556 (12)	C13—H13A	0.9400
Re1—P2	2.4525 (12)	C14—C15	1.378 (8)
Re1—P1	2.4703 (13)	C14—H14A	0.9400
Re2—Cl3	2.3314 (12)	C15—C16	1.375 (8)
Re2—Cl5	2.3436 (12)	C15—H15A	0.9400
Re2—Cl4	2.3469 (13)	C16—H16A	0.9400
Re2—P3	2.4551 (13)	C17—C18	1.534 (6)
P1—C9	1.821 (5)	C17—H17A	0.9800
P1—C1	1.835 (5)	C17—H17B	0.9800
P1—C7	1.845 (5)	C18—H18A	0.9700
P2—C17	1.814 (5)	C18—H18B	0.9700
P2—C11	1.819 (5)	C18—H18C	0.9700
P2—C19	1.822 (5)	C19—C20	1.523 (6)
P3—C29	1.813 (5)	C19—H19A	0.9800
P3—C21	1.822 (5)	C19—H19B	0.9800
P3—C27	1.827 (5)	C20—H20A	0.9700
C1—C2	1.371 (6)	C20—H20B	0.9700
C1—C6	1.397 (7)	C20—H20C	0.9700
C2—C3	1.393 (7)	C21—C22	1.377 (7)
C2—H2A	0.9400	C21—C26	1.396 (7)
C3—C4	1.374 (7)	C22—C23	1.383 (8)
C3—H3A	0.9400	C22—H22A	0.9400
C4—C5	1.355 (7)	C23—C24	1.357 (8)
C4—H4A	0.9400	C23—H23A	0.9400
C5—C6	1.378 (7)	C24—C25	1.363 (8)
C5—H5A	0.9400	C24—H24A	0.9400
C6—H6A	0.9400	C25—C26	1.383 (8)
C7—C8	1.502 (7)	C25—H25A	0.9400
C7—H7A	0.9800	C26—H26A	0.9400
C7—H7B	0.9800	C27—C28	1.530 (7)
C8—H8A	0.9700	C27—H27A	0.9800
C8—H8B	0.9700	C27—H27B	0.9800
C8—H8C	0.9700	C28—H28A	0.9700
C9—C10	1.524 (7)	C28—H28B	0.9700
C9—H9A	0.9800	C28—H28C	0.9700
C9—H9B	0.9800	C29—C30	1.508 (6)
C10—H10A	0.9700	C29—H29A	0.9800
C10—H10B	0.9700	C29—H29B	0.9800
C10—H10C	0.9700	C30—H30A	0.9700
C11—C16	1.386 (7)	C30—H30B	0.9700
C11—C12	1.390 (7)	C30—H30C	0.9700
C12—C13	1.362 (7)
Re2—Re1—Cl2	103.86 (3)	C12—C11—P2	121.7 (4)
Re2—Re1—Cl1	112.83 (3)	C13—C12—C11	121.7 (5)
Cl2—Re1—Cl1	143.29 (5)	C13—C12—H12A	119.1
Re2—Re1—P2	103.76 (4)	C11—C12—H12A	119.1
Cl2—Re1—P2	83.86 (4)	C12—C13—C14	120.1 (6)
Cl1—Re1—P2	86.25 (4)	C12—C13—H13A	119.9
Re2—Re1—P1	104.88 (3)	C14—C13—H13A	119.9
Cl2—Re1—P1	84.40 (4)	C13—C14—C15	119.5 (6)
Cl1—Re1—P1	87.42 (4)	C13—C14—H14A	120.3
P2—Re1—P1	150.89 (5)	C15—C14—H14A	120.3
Re1—Re2—Cl3	108.23 (4)	C16—C15—C14	120.2 (6)
Re1—Re2—Cl5	109.51 (3)	C16—C15—H15A	119.9
Cl3—Re2—Cl5	142.19 (5)	C14—C15—H15A	119.9
Re1—Re2—Cl4	104.17 (3)	C15—C16—C11	121.0 (6)
Cl3—Re2—Cl4	86.39 (5)	C15—C16—H16A	119.5
Cl5—Re2—Cl4	86.55 (5)	C11—C16—H16A	119.5
Re1—Re2—P3	101.04 (3)	C18—C17—P2	116.8 (4)
Cl3—Re2—P3	84.93 (4)	C18—C17—H17A	108.1
Cl5—Re2—P3	85.91 (4)	P2—C17—H17A	108.1
Cl4—Re2—P3	154.77 (5)	C18—C17—H17B	108.1
C9—P1—C1	105.7 (2)	P2—C17—H17B	108.1
C9—P1—C7	105.8 (3)	H17A—C17—H17B	107.3
C1—P1—C7	101.0 (2)	C17—C18—H18A	109.5
C9—P1—Re1	113.50 (17)	C17—C18—H18B	109.5
C1—P1—Re1	122.29 (16)	H18A—C18—H18B	109.5
C7—P1—Re1	106.70 (18)	C17—C18—H18C	109.5
C17—P2—C11	105.1 (2)	H18A—C18—H18C	109.5
C17—P2—C19	108.6 (2)	H18B—C18—H18C	109.5
C11—P2—C19	106.7 (2)	C20—C19—P2	119.6 (4)
C17—P2—Re1	117.53 (16)	C20—C19—H19A	107.4
C11—P2—Re1	103.65 (17)	P2—C19—H19A	107.4
C19—P2—Re1	114.24 (16)	C20—C19—H19B	107.4
C29—P3—C21	106.6 (2)	P2—C19—H19B	107.4
C29—P3—C27	107.5 (2)	H19A—C19—H19B	107.0
C21—P3—C27	104.8 (2)	C19—C20—H20A	109.5
C29—P3—Re2	114.44 (17)	C19—C20—H20B	109.5
C21—P3—Re2	105.23 (16)	H20A—C20—H20B	109.5
C27—P3—Re2	117.23 (16)	C19—C20—H20C	109.5
C2—C1—C6	118.1 (5)	H20A—C20—H20C	109.5
C2—C1—P1	121.7 (4)	H20B—C20—H20C	109.5
C6—C1—P1	120.1 (4)	C22—C21—C26	118.1 (5)
C1—C2—C3	121.0 (5)	C22—C21—P3	120.7 (4)
C1—C2—H2A	119.5	C26—C21—P3	121.2 (4)
C3—C2—H2A	119.5	C21—C22—C23	121.0 (6)
C4—C3—C2	119.7 (5)	C21—C22—H22A	119.5
C4—C3—H3A	120.2	C23—C22—H22A	119.5
C2—C3—H3A	120.2	C24—C23—C22	120.4 (7)
C5—C4—C3	120.0 (5)	C24—C23—H23A	119.8
C5—C4—H4A	120.0	C22—C23—H23A	119.8
C3—C4—H4A	120.0	C23—C24—C25	119.6 (6)
C4—C5—C6	120.9 (6)	C23—C24—H24A	120.2
C4—C5—H5A	119.5	C25—C24—H24A	120.2
C6—C5—H5A	119.5	C24—C25—C26	121.0 (6)
C5—C6—C1	120.3 (5)	C24—C25—H25A	119.5
C5—C6—H6A	119.9	C26—C25—H25A	119.5
C1—C6—H6A	119.9	C25—C26—C21	119.8 (6)
C8—C7—P1	118.1 (4)	C25—C26—H26A	120.1
C8—C7—H7A	107.8	C21—C26—H26A	120.1
P1—C7—H7A	107.8	C28—C27—P3	117.5 (4)
C8—C7—H7B	107.8	C28—C27—H27A	107.9
P1—C7—H7B	107.8	P3—C27—H27A	107.9
H7A—C7—H7B	107.1	C28—C27—H27B	107.9
C7—C8—H8A	109.5	P3—C27—H27B	107.9
C7—C8—H8B	109.5	H27A—C27—H27B	107.2
H8A—C8—H8B	109.5	C27—C28—H28A	109.5
C7—C8—H8C	109.5	C27—C28—H28B	109.5
H8A—C8—H8C	109.5	H28A—C28—H28B	109.5
H8B—C8—H8C	109.5	C27—C28—H28C	109.5
C10—C9—P1	117.0 (4)	H28A—C28—H28C	109.5
C10—C9—H9A	108.0	H28B—C28—H28C	109.5
P1—C9—H9A	108.0	C30—C29—P3	118.7 (4)
C10—C9—H9B	108.0	C30—C29—H29A	107.6
P1—C9—H9B	108.0	P3—C29—H29A	107.6
H9A—C9—H9B	107.3	C30—C29—H29B	107.6
C9—C10—H10A	109.5	P3—C29—H29B	107.6
C9—C10—H10B	109.5	H29A—C29—H29B	107.1
H10A—C10—H10B	109.5	C29—C30—H30A	109.5
C9—C10—H10C	109.5	C29—C30—H30B	109.5
H10A—C10—H10C	109.5	H30A—C30—H30B	109.5
H10B—C10—H10C	109.5	C29—C30—H30C	109.5
C16—C11—C12	117.4 (5)	H30A—C30—H30C	109.5
C16—C11—P2	120.7 (4)	H30B—C30—H30C	109.5
Cl1—Re1—Re2—P3	−4.10 (5)	Cl2—Re1—Re2—Cl4	−1.88 (5)
P2—Re1—Re2—Cl5	−6.28 (5)	P1—Re1—Re2—Cl3	1.16 (5)