[Bis(3,5-diisopropylpyrazol-1-yl-[kappa]N²)dihydroborato](triphenylphos­phane-[kappa]P)copper(I)

In the title compound, [Cu(C₁₈H₃₂BN₄)(C₁₈H₁₅P)], the Cu^I ion is coordinated by two N atoms from the anionic bidentate chelating bis(3,5-diisopropylpyrazol-1-yl)dihydroborate lig­and [average Cu-N distance = 1.994 (3) Å] and the P atom from a triphenylphosphane ligand [Cu-P distance = 2.1676 (8) Å] in a trigonal geometry [the sum of the angles around the Cu^I atom is 359.6 (1)°]. The N-Cu-N angle between adjacent coordinated pyrazole-ring N atoms is 98.99 (9)°, while the average N-Cu-P angle between the coordinated pyrazole N atom and the triphenylphosphane P atom is 130.3 (1)°.

S1. Comment

ENTER TEXT

S2. Experimental

ENTER COMPOUND PREPARATION DETAILS

S3. Refinement

ENTER SPECIAL DETAILS OF THE REFINEMENT

Computing details

Data collection: CrystalClear (Rigaku, 2010); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: CrystalStructure 4.0; software used to prepare material for publication: CrystalStructure 4.0 (Rigaku, 2010).

Figures

ENTER FIGURE CAPTIONS

(I)

Crystal data

C36H47BCuN4P	F(000) = 1360.00
Mr = 641.12	Dx = 1.217 Mg m^−3
Monoclinic, Cc	Mo Kα radiation, λ = 0.71070 Å
Hall symbol: C -2yc	Cell parameters from 309 reflections
a = 13.3372 (5) Å	θ = 3.0–27.5°
b = 14.3257 (5) Å	µ = 0.70 mm^−1
c = 18.4712 (10) Å	T = 184 K
β = 97.6540 (8)°	Chip, colourless
V = 3497.8 (3) Å^3	0.40 × 0.20 × 0.20 mm
Z = 4

Data collection

Rigaku Mercury70 diffractometer	5155 reflections with F^2 > 2.0σ(F^2)
Detector resolution: 7.314 pixels mm^-1	Rint = 0.020
ω scans	θmax = 27.5°
Absorption correction: multi-scan REQAB (Rigaku, 1998)	h = −11→17
Tmin = 0.736, Tmax = 0.869	k = −18→18
14044 measured reflections	l = −23→16
5245 independent reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.030	H-atom parameters constrained
wR(F^2) = 0.081	w = 1/[σ^2(Fo^2) + (0.0498P)^2 + 1.8074P] where P = (Fo^2 + 2Fc^2)/3
S = 1.06	(Δ/σ)max = 0.001
5245 reflections	Δρmax = 0.37 e Å^−3
388 parameters	Δρmin = −0.25 e Å^−3
2 restraints	Absolute structure: Flack, 1983. 1237 Friedel Pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.004 (10)
Secondary atom site location: difference Fourier map

Special details

Geometry. ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY

Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F². R-factor (gt) are based on F. The threshold expression of F² > 2.0 σ(F²) is used only for calculating R-factor (gt).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.31480 (2)	0.610908 (19)	0.454410 (17)	0.02498 (8)
P1	0.15530 (5)	0.57801 (5)	0.44862 (3)	0.02372 (13)
N11	0.38523 (16)	0.67342 (16)	0.37920 (11)	0.0271 (5)
N12	0.48479 (17)	0.64832 (15)	0.38025 (10)	0.0262 (5)
N21	0.43528 (16)	0.57730 (16)	0.52580 (11)	0.0246 (5)
N22	0.52110 (16)	0.55387 (15)	0.49740 (11)	0.0237 (4)
C11	0.2342 (4)	0.8055 (5)	0.2464 (3)	0.094 (2)
C12	0.2693 (4)	0.8908 (4)	0.3633 (4)	0.090 (2)
C13	0.2703 (3)	0.7978 (3)	0.32736 (16)	0.0403 (7)
C14	0.3723 (2)	0.7533 (2)	0.34109 (13)	0.0304 (6)
C15	0.4634 (3)	0.7802 (2)	0.31810 (14)	0.0325 (6)
C16	0.5325 (2)	0.7127 (2)	0.34395 (13)	0.0294 (6)
C17	0.6431 (3)	0.7044 (3)	0.33530 (16)	0.0390 (7)
C18	0.6569 (3)	0.6452 (3)	0.2695 (2)	0.0560 (9)
C19	0.6914 (4)	0.8000 (3)	0.3303 (3)	0.0628 (11)
C21	0.3765 (6)	0.6972 (4)	0.6606 (4)	0.121 (3)
C22	0.3925 (4)	0.5422 (4)	0.7182 (2)	0.0732 (15)
C23	0.3768 (3)	0.5946 (3)	0.64687 (15)	0.0344 (6)
C24	0.4555 (2)	0.56912 (19)	0.59877 (13)	0.0252 (5)
C25	0.55418 (19)	0.53866 (18)	0.61684 (13)	0.0266 (5)
C26	0.5942 (2)	0.52903 (18)	0.55152 (13)	0.0256 (5)
C27	0.6969 (2)	0.4970 (2)	0.53795 (14)	0.0320 (6)
C28	0.7701 (3)	0.5769 (3)	0.5383 (3)	0.0536 (9)
C29	0.7388 (3)	0.4228 (4)	0.5928 (3)	0.0584 (10)
C41	0.0940 (3)	0.5693 (2)	0.35432 (14)	0.0305 (6)
C42	0.1557 (3)	0.5516 (3)	0.30124 (16)	0.0393 (7)
C43	0.1142 (3)	0.5405 (3)	0.22812 (17)	0.0511 (9)
C44	0.0130 (3)	0.5482 (3)	0.20788 (17)	0.0518 (9)
C45	−0.0492 (3)	0.5672 (3)	0.25971 (18)	0.0522 (9)
C46	−0.0094 (3)	0.5777 (3)	0.33281 (16)	0.0416 (7)
C47	0.07774 (19)	0.66003 (18)	0.49249 (14)	0.0269 (5)
C48	0.0423 (3)	0.7422 (2)	0.45733 (18)	0.0414 (7)
C49	−0.0101 (3)	0.8080 (3)	0.4939 (3)	0.0505 (9)
C50	−0.0253 (3)	0.7927 (3)	0.5647 (3)	0.0505 (9)
C51	0.0090 (3)	0.7122 (3)	0.60018 (19)	0.0451 (8)
C52	0.0609 (3)	0.6462 (2)	0.56455 (15)	0.0341 (6)
C53	0.1295 (2)	0.46526 (17)	0.48882 (12)	0.0249 (5)
C54	0.0332 (3)	0.4262 (2)	0.48232 (15)	0.0327 (6)
C55	0.0170 (3)	0.3399 (2)	0.51144 (16)	0.0374 (7)
C56	0.0971 (3)	0.2909 (2)	0.54849 (16)	0.0406 (7)
C57	0.1931 (3)	0.3288 (3)	0.55576 (19)	0.0464 (8)
C58	0.2096 (3)	0.4156 (2)	0.52536 (17)	0.0383 (7)
B1	0.5173 (3)	0.5508 (3)	0.41243 (15)	0.0310 (7)
H1	0.5848	0.5342	0.3995	0.0372*
H2	0.4684	0.5028	0.3917	0.0372*
H3	0.2924	0.8149	0.2200	0.1126*
H4	0.1878	0.8585	0.2374	0.1126*
H5	0.1990	0.7479	0.2292	0.1126*
H6	0.2026	0.9018	0.3784	0.1085*
H7	0.2838	0.9395	0.3289	0.1085*
H8	0.3210	0.8922	0.4063	0.1085*
H9	0.2217	0.7566	0.3492	0.0483*
H10	0.4753	0.8339	0.2904	0.0390*
H11	0.6782	0.6724	0.3797	0.0468*
H12	0.6554	0.6853	0.2264	0.0672*
H13	0.6021	0.5993	0.2613	0.0672*
H14	0.7220	0.6128	0.2783	0.0672*
H15	0.7187	0.8214	0.3794	0.0753*
H16	0.6403	0.8444	0.3083	0.0753*
H17	0.7462	0.7958	0.3000	0.0753*
H18	0.4455	0.7216	0.6627	0.1457*
H19	0.3511	0.7094	0.7070	0.1457*
H20	0.3327	0.7281	0.6209	0.1457*
H21	0.3267	0.5298	0.7345	0.0878*
H22	0.4341	0.5797	0.7550	0.0878*
H23	0.4267	0.4829	0.7114	0.0878*
H24	0.3090	0.5769	0.6206	0.0412*
H25	0.5879	0.5267	0.6645	0.0319*
H26	0.6897	0.4680	0.4883	0.0383*
H27	0.8050	0.5860	0.5879	0.0643*
H28	0.7332	0.6338	0.5219	0.0643*
H29	0.8198	0.5627	0.5052	0.0643*
H30	0.7186	0.3608	0.5737	0.0701*
H31	0.7119	0.4329	0.6391	0.0701*
H32	0.8127	0.4269	0.6011	0.0701*
H33	0.2269	0.5470	0.3146	0.0471*
H34	0.1572	0.5275	0.1923	0.0614*
H35	−0.0147	0.5405	0.1581	0.0621*
H36	−0.1200	0.5732	0.2455	0.0626*
H37	−0.0531	0.5908	0.3681	0.0499*
H38	0.0539	0.7536	0.4085	0.0496*
H39	−0.0353	0.8632	0.4695	0.0607*
H40	−0.0598	0.8381	0.5896	0.0606*
H41	−0.0028	0.7017	0.6491	0.0542*
H42	0.0851	0.5910	0.5896	0.0409*
H43	−0.0225	0.4597	0.4573	0.0392*
H44	−0.0492	0.3140	0.5061	0.0449*
H45	0.0862	0.2315	0.5689	0.0487*
H46	0.2482	0.2955	0.5816	0.0557*
H47	0.2761	0.4407	0.5298	0.0459*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.01940 (13)	0.02913 (15)	0.02610 (13)	−0.00009 (13)	0.00187 (9)	0.00505 (12)
P1	0.0203 (3)	0.0265 (3)	0.0241 (3)	0.0007 (3)	0.0018 (2)	0.0044 (3)
N11	0.0235 (11)	0.0300 (11)	0.0277 (10)	0.0033 (9)	0.0036 (8)	0.0085 (8)
N12	0.0279 (11)	0.0289 (11)	0.0229 (10)	0.0040 (10)	0.0072 (8)	0.0037 (8)
N21	0.0180 (10)	0.0339 (12)	0.0224 (10)	−0.0004 (9)	0.0044 (8)	0.0027 (8)
N22	0.0213 (11)	0.0260 (11)	0.0242 (10)	0.0043 (9)	0.0042 (8)	0.0022 (8)
C11	0.088 (4)	0.128 (5)	0.056 (3)	0.050 (4)	−0.025 (3)	0.002 (3)
C12	0.052 (3)	0.097 (5)	0.118 (5)	0.042 (3)	−0.004 (3)	−0.045 (4)
C13	0.0308 (15)	0.0452 (18)	0.0444 (16)	0.0091 (14)	0.0034 (12)	0.0159 (13)
C14	0.0314 (14)	0.0344 (15)	0.0257 (12)	0.0028 (12)	0.0049 (10)	0.0067 (10)
C15	0.0369 (16)	0.0343 (15)	0.0281 (12)	0.0023 (12)	0.0110 (11)	0.0088 (10)
C16	0.0348 (15)	0.0331 (14)	0.0225 (11)	0.0027 (12)	0.0120 (10)	0.0005 (10)
C17	0.0355 (17)	0.0500 (19)	0.0347 (15)	0.0056 (14)	0.0165 (12)	0.0054 (12)
C18	0.058 (3)	0.061 (3)	0.054 (2)	0.015 (2)	0.0299 (17)	−0.0074 (17)
C19	0.049 (3)	0.059 (3)	0.087 (3)	−0.012 (2)	0.033 (2)	−0.013 (2)
C21	0.190 (7)	0.049 (3)	0.159 (6)	0.027 (4)	0.148 (6)	0.009 (3)
C22	0.074 (3)	0.105 (4)	0.049 (2)	0.035 (3)	0.039 (2)	0.037 (3)
C23	0.0282 (15)	0.0486 (17)	0.0279 (13)	0.0037 (13)	0.0099 (10)	0.0052 (11)
C24	0.0270 (14)	0.0264 (13)	0.0221 (11)	−0.0017 (11)	0.0033 (9)	0.0011 (9)
C25	0.0253 (13)	0.0297 (13)	0.0241 (11)	0.0023 (11)	0.0010 (9)	0.0010 (9)
C26	0.0240 (13)	0.0247 (12)	0.0272 (12)	0.0007 (11)	0.0007 (9)	0.0021 (9)
C27	0.0279 (14)	0.0372 (15)	0.0308 (13)	0.0092 (12)	0.0041 (10)	0.0020 (11)
C28	0.0303 (17)	0.055 (3)	0.078 (3)	0.0014 (16)	0.0166 (16)	0.0014 (18)
C29	0.0361 (19)	0.066 (3)	0.073 (3)	0.0193 (18)	0.0072 (17)	0.029 (2)
C41	0.0316 (15)	0.0319 (14)	0.0268 (12)	−0.0002 (12)	−0.0008 (10)	0.0043 (10)
C42	0.0346 (17)	0.051 (2)	0.0327 (14)	0.0015 (15)	0.0047 (12)	−0.0060 (13)
C43	0.056 (3)	0.067 (3)	0.0306 (15)	−0.0002 (19)	0.0064 (14)	−0.0104 (14)
C44	0.060 (3)	0.063 (3)	0.0291 (15)	0.0017 (19)	−0.0072 (14)	0.0014 (14)
C45	0.0372 (18)	0.076 (3)	0.0390 (17)	0.0082 (18)	−0.0123 (13)	0.0031 (16)
C46	0.0295 (16)	0.060 (2)	0.0343 (15)	0.0026 (15)	0.0005 (12)	0.0041 (13)
C47	0.0210 (13)	0.0254 (13)	0.0341 (13)	−0.0025 (10)	0.0027 (10)	0.0008 (10)
C48	0.0445 (18)	0.0281 (14)	0.0521 (17)	0.0028 (13)	0.0088 (13)	0.0064 (12)
C49	0.046 (2)	0.0252 (15)	0.081 (3)	0.0059 (14)	0.0101 (17)	0.0008 (14)
C50	0.0374 (19)	0.0380 (19)	0.078 (3)	0.0001 (15)	0.0133 (16)	−0.0214 (16)
C51	0.0412 (19)	0.0479 (19)	0.0487 (18)	−0.0034 (16)	0.0147 (14)	−0.0152 (15)
C52	0.0340 (15)	0.0343 (15)	0.0342 (14)	0.0004 (13)	0.0055 (11)	−0.0015 (11)
C53	0.0268 (13)	0.0245 (12)	0.0236 (11)	−0.0005 (10)	0.0036 (9)	0.0005 (9)
C54	0.0278 (14)	0.0324 (15)	0.0372 (14)	−0.0015 (11)	0.0023 (11)	0.0050 (11)
C55	0.0378 (16)	0.0340 (15)	0.0414 (15)	−0.0117 (13)	0.0091 (12)	0.0010 (11)
C56	0.0514 (19)	0.0259 (14)	0.0453 (16)	−0.0030 (14)	0.0093 (13)	0.0061 (11)
C57	0.0401 (18)	0.0353 (17)	0.062 (2)	0.0022 (14)	−0.0010 (15)	0.0176 (14)
C58	0.0295 (16)	0.0328 (15)	0.0506 (17)	−0.0016 (12)	−0.0021 (12)	0.0105 (12)
B1	0.0382 (18)	0.0320 (16)	0.0233 (13)	0.0084 (13)	0.0061 (11)	0.0017 (10)

Geometric parameters (Å, º)

Cu1—P1	2.1676 (8)	C11—H3	0.980
Cu1—N11	1.990 (3)	C11—H4	0.980
Cu1—N21	1.997 (2)	C11—H5	0.980
P1—C41	1.827 (3)	C12—H6	0.980
P1—C47	1.825 (3)	C12—H7	0.980
P1—C53	1.829 (3)	C12—H8	0.980
N11—N12	1.373 (4)	C13—H9	1.000
N11—C14	1.342 (4)	C15—H10	0.950
N12—C16	1.348 (4)	C17—H11	1.000
N12—B1	1.557 (4)	C18—H12	0.980
N21—N22	1.363 (4)	C18—H13	0.980
N21—C24	1.344 (3)	C18—H14	0.980
N22—C26	1.348 (3)	C19—H15	0.980
N22—B1	1.564 (4)	C19—H16	0.980
C11—C13	1.513 (6)	C19—H17	0.980
C12—C13	1.489 (7)	C21—H18	0.980
C13—C14	1.494 (5)	C21—H19	0.980
C14—C15	1.393 (5)	C21—H20	0.980
C15—C16	1.377 (4)	C22—H21	0.980
C16—C17	1.509 (5)	C22—H22	0.980
C17—C18	1.513 (6)	C22—H23	0.980
C17—C19	1.521 (6)	C23—H24	1.000
C21—C23	1.492 (6)	C25—H25	0.950
C22—C23	1.506 (6)	C27—H26	1.000
C23—C24	1.507 (5)	C28—H27	0.980
C24—C25	1.385 (4)	C28—H28	0.980
C25—C26	1.389 (4)	C28—H29	0.980
C26—C27	1.498 (4)	C29—H30	0.980
C27—C28	1.503 (5)	C29—H31	0.980
C27—C29	1.523 (5)	C29—H32	0.980
C41—C42	1.385 (5)	C42—H33	0.950
C41—C46	1.389 (5)	C43—H34	0.950
C42—C43	1.399 (5)	C44—H35	0.950
C43—C44	1.355 (6)	C45—H36	0.950
C44—C45	1.375 (6)	C46—H37	0.950
C45—C46	1.392 (5)	C48—H38	0.950
C47—C48	1.396 (4)	C49—H39	0.950
C47—C52	1.393 (4)	C50—H40	0.950
C48—C49	1.400 (5)	C51—H41	0.950
C49—C50	1.366 (6)	C52—H42	0.950
C50—C51	1.375 (5)	C54—H43	0.950
C51—C52	1.388 (5)	C55—H44	0.950
C53—C54	1.392 (4)	C56—H45	0.950
C53—C58	1.382 (4)	C57—H46	0.950
C54—C55	1.377 (5)	C58—H47	0.950
C55—C56	1.381 (5)	B1—H1	0.990
C56—C57	1.380 (5)	B1—H2	0.990
C57—C58	1.395 (5)
Cu1···C13	3.558 (4)	C43···H21^v	2.9967
Cu1···C23	3.549 (3)	C43···H42^v	3.1607
Cu1···C42	3.410 (3)	C44···H10^xii	3.4931
Cu1···C58	3.464 (4)	C44···H18^iv	3.4903
Cu1···B1	3.033 (4)	C44···H32^xiii	3.1223
N11···N22	3.151 (3)	C44···H42^v	3.2002
N11···C11	3.513 (6)	C45···H7^xii	3.2718
N11···C12	3.471 (6)	C45···H10^xii	3.3979
N12···N21	3.029 (3)	C45···H14^xiv	3.1834
N12···C18	3.271 (5)	C45···H18^iv	3.5122
N21···C21	3.207 (7)	C45···H19^iv	3.5508
N22···C28	3.323 (4)	C45···H32^xiii	3.2473
C11···C15	3.186 (6)	C46···H7^xii	3.3894
C12···C15	3.238 (7)	C46···H10^xii	3.5796
C15···C18	3.438 (6)	C48···H30^ii	3.4181
C15···C19	3.032 (6)	C49···H2^ii	3.3608
C17···B1	3.212 (5)	C49···H26^ii	3.5284
C21···C25	3.455 (8)	C49···H30^ii	3.2944
C22···C25	3.039 (6)	C49···H47^ii	3.5616
C25···C28	3.437 (5)	C50···H12^viii	3.5935
C25···C29	3.050 (5)	C50···H30^ii	3.3784
C27···B1	3.198 (4)	C50···H46^ii	3.0794
C41···C44	2.792 (4)	C50···H47^ii	3.3873
C41···C48	3.253 (5)	C51···H12^viii	3.1926
C41···C54	3.311 (4)	C51···H27^xiv	3.2489
C42···C45	2.748 (5)	C51···H29^xiv	3.5841
C43···C46	2.754 (5)	C51···H30^ii	3.5987
C46···C47	3.244 (4)	C52···H29^xiv	3.4679
C46···C48	3.301 (5)	C52···H34^ix	3.5505
C46···C53	3.593 (4)	C52···H35^ix	3.4096
C46···C54	3.499 (5)	C53···H15^xii	3.2229
C47···C50	2.787 (5)	C54···H8^xii	3.0260
C47···C54	3.403 (4)	C54···H29^xiv	3.5248
C48···C51	2.767 (5)	C54···H35^ix	3.4257
C49···C52	2.764 (5)	C55···H8^xii	3.1321
C52···C53	3.139 (4)	C55···H18^xii	3.5068
C52···C54	3.497 (4)	C55···H32^xiv	3.5941
C53···C56	2.787 (4)	C55···H35^ix	3.2806
C54···C57	2.750 (5)	C56···H5^ix	3.4778
C55···C58	2.770 (5)	C56···H18^xii	3.2655
N22···C49^i	3.547 (4)	C56···H28^xii	2.9729
C26···C49^i	3.564 (5)	C57···H5^ix	3.3784
C49···N22^ii	3.547 (4)	C57···H15^xii	3.3223
C49···C26^ii	3.564 (5)	C57···H28^xii	2.9267
Cu1···H2	2.9277	C57···H34^ix	3.3396
Cu1···H9	3.0051	C57···H40^i	3.2753
Cu1···H20	3.4839	C58···H15^xii	3.0321
Cu1···H24	3.1199	C58···H34^ix	3.3526
Cu1···H33	2.8422	C58···H40^i	3.3355
Cu1···H47	2.8878	B1···H6^i	3.3866
P1···H9	3.3370	B1···H22^v	3.5106
P1···H24	3.5447	B1···H39^i	3.0037
P1···H33	2.8049	H1···C12^i	3.3416
P1···H37	2.9777	H1···H6^i	2.5262
P1···H38	2.9047	H1···H7^i	3.3924
P1···H42	2.8873	H1···H22^v	3.5216
P1···H43	2.9362	H1···H39^i	3.2847
P1···H47	2.8404	H2···C22^v	3.2932
N11···H1	3.3070	H2···C49^i	3.3608
N11···H2	2.6815	H2···H6^i	3.4804
N11···H8	3.3046	H2···H21^v	3.2798
N11···H9	2.4818	H2···H22^v	2.7693
N11···H10	3.1544	H2···H23^v	3.3079
N11···H33	2.9145	H2···H39^i	2.4669
N12···H10	3.1287	H3···H25^iv	3.5904
N12···H11	2.6036	H3···H27^iv	2.8460
N12···H13	2.9472	H3···H41^vi	3.1904
N21···H1	3.3223	H3···H46^v	2.9964
N21···H2	2.7866	H4···C25^iv	3.0414
N21···H18	3.2549	H4···H18^iv	3.5319
N21···H20	3.2043	H4···H22^iv	3.5536
N21···H24	2.5865	H4···H25^iv	2.4113
N21···H25	3.1381	H4···H27^iv	3.4432
N21···H47	2.8951	H4···H31^iv	3.5346
N22···H25	3.1214	H4···H45^v	3.4738
N22···H26	2.5884	H5···C56^v	3.4778
N22···H28	3.0299	H5···C57^v	3.3784
C11···H6	2.8819	H5···H18^iv	3.4680
C11···H7	2.4859	H5···H45^v	3.1525
C11···H8	3.2717	H5···H46^v	2.9540
C11···H10	3.2360	H6···C27^ii	3.2574
C12···H3	2.9163	H6···B1^ii	3.3866
C12···H4	2.4761	H6···H1^ii	2.5262
C12···H5	3.2533	H6···H2^ii	3.4804
C12···H10	3.3186	H6···H14^ii	3.5697
C13···H10	2.9515	H6···H26^ii	2.2675
C13···H38	3.4818	H6···H29^ii	3.5033
C14···H3	2.5074	H7···C18^ii	3.5020
C14···H4	3.2775	H7···C45^iii	3.2718
C14···H5	2.8889	H7···C46^iii	3.3894
C14···H6	3.2472	H7···H1^ii	3.3924
C14···H7	2.9137	H7···H13^ii	3.4454
C14···H8	2.4700	H7···H14^ii	2.7406
C14···H33	3.5331	H7···H26^ii	3.3748
C15···H3	2.7625	H7···H36^iii	2.8667
C15···H7	3.3334	H7···H37^iii	3.0884
C15···H8	3.1083	H7···H43^iii	3.2794
C15···H9	3.3653	H8···C27^ii	3.4606
C15···H11	3.3193	H8···C54^iii	3.0260
C15···H12	3.5260	H8···C55^iii	3.1321
C15···H13	3.4287	H8···H26^ii	2.6912
C15···H15	3.4922	H8···H29^ii	3.0524
C15···H16	2.5617	H8···H30^ii	3.5699
C16···H1	2.8079	H8···H37^iii	3.4251
C16···H2	3.2784	H8···H43^iii	2.3787
C16···H12	2.9164	H8···H44^iii	2.6064
C16···H13	2.4918	H10···C44^iii	3.4931
C16···H14	3.2749	H10···C45^iii	3.3979
C16···H15	2.9305	H10···C46^iii	3.5796
C16···H16	2.5136	H10···H41^vi	2.7117
C16···H17	3.2890	H10···H43^iii	3.5686
C17···H1	2.8636	H12···C29^v	3.2326
C17···H10	2.9397	H12···C50^vi	3.5935
C18···H1	3.1357	H12···C51^vi	3.1926
C18···H15	3.2742	H12···H19^vi	3.0756
C18···H16	2.9574	H12···H20^vi	3.4856
C18···H17	2.4920	H12···H25^v	3.3266
C19···H10	2.9185	H12···H30^v	3.1205
C19···H12	2.5237	H12···H31^v	2.5213
C19···H13	3.3025	H12···H36^vii	3.3751
C19···H14	2.8966	H12···H40^vi	3.5789
C21···H21	2.8804	H12···H41^vi	2.8824
C21···H22	2.4721	H13···C22^v	3.4591
C21···H23	3.2544	H13···C25^v	3.3133
C22···H18	2.8890	H13···H7^i	3.4454
C22···H19	2.4612	H13···H22^v	3.3973
C22···H20	3.2525	H13···H23^v	2.6707
C22···H25	2.9180	H13···H25^v	2.5292
C23···H25	2.9554	H13···H31^v	2.8863
C23···H47	3.2508	H14···C12^i	3.5658
C24···H18	2.4949	H14···C29^v	3.4999
C24···H19	3.2741	H14···C45^vii	3.1834
C24···H20	2.8664	H14···H6^i	3.5697
C24···H21	3.2698	H14···H7^i	2.7406
C24···H22	2.9415	H14···H19^vi	3.4332
C24···H23	2.4930	H14···H25^v	3.2567
C24···H47	3.1491	H14···H31^v	2.6394
C25···H18	3.1642	H14···H36^vii	2.3381
C25···H22	3.2424	H14···H37^vii	3.2439
C25···H23	2.7151	H15···C53^iii	3.2229
C25···H24	3.3252	H15···C57^iii	3.3223
C25···H26	3.3279	H15···C58^iii	3.0321
C25···H27	3.5236	H15···H33^iii	3.4534
C25···H28	3.4279	H15···H39^vii	3.5276
C25···H30	3.5214	H15···H47^iii	3.2648
C25···H31	2.5807	H16···C41^iii	3.4084
C26···H1	2.7946	H16···C42^iii	2.9791
C26···H2	3.2179	H16···C43^iii	3.1730
C26···H27	2.9196	H16···H21^vi	3.4914
C26···H28	2.5026	H16···H33^iii	3.1195
C26···H29	3.2722	H16···H34^iii	3.4121
C26···H30	2.9235	H16···H41^vi	3.3506
C26···H31	2.5105	H17···C21^vi	3.2953
C26···H32	3.2811	H17···C22^vi	3.5022
C27···H1	2.8352	H17···H19^vi	2.3563
C27···H25	2.9438	H17···H21^vi	3.0347
C28···H1	3.3708	H17···H22^vi	3.2722
C28···H11	3.3170	H18···C44^x	3.4903
C28···H30	3.2554	H18···C45^x	3.5122
C28···H31	2.9514	H18···C55^iii	3.5068
C28···H32	2.4711	H18···C56^iii	3.2655
C29···H25	2.9539	H18···H4^x	3.5319
C29···H27	2.5059	H18···H5^x	3.4680
C29···H28	3.2919	H18···H32^ii	3.5424
C29···H29	2.8762	H18···H35^x	3.4519
C41···H9	3.1863	H18···H36^x	3.4786
C41···H34	3.2696	H18···H44^iii	3.1919
C41···H36	3.2657	H18···H45^iii	2.7229
C41···H38	2.8985	H19···C19^viii	3.3215
C41···H43	3.0473	H19···C45^x	3.5508
C42···H5	3.1959	H19···H12^viii	3.0756
C42···H9	3.1578	H19···H14^viii	3.4332
C42···H35	3.2527	H19···H17^viii	2.3563
C42···H37	3.2426	H19···H30^ii	3.5688
C43···H5	3.1781	H19···H36^x	3.2056
C43···H36	3.2161	H20···C29^ii	3.0726
C44···H33	3.2436	H20···H12^viii	3.4856
C44···H37	3.2568	H20···H30^ii	2.5170
C45···H34	3.2189	H20···H31^ii	3.3843
C46···H33	3.2425	H20···H32^ii	2.8792
C46···H35	3.2615	H20···H44^iii	3.0638
C46···H38	2.9488	H21···C42^ix	2.9723
C46···H43	2.8789	H21···C43^ix	2.9967
C47···H37	2.8698	H21···H2^ix	3.2798
C47···H39	3.2799	H21···H16^viii	3.4914
C47···H41	3.2726	H21···H17^viii	3.0347
C47···H43	3.1959	H21···H33^ix	2.3878
C48···H6	3.5711	H21···H34^ix	2.4340
C48···H9	3.3211	H22···B1^ix	3.5106
C48···H37	2.9123	H22···H1^ix	3.5216
C48···H40	3.2548	H22···H2^ix	2.7693
C48···H42	3.2574	H22···H4^x	3.5536
C49···H41	3.2359	H22···H13^ix	3.3973
C50···H38	3.2509	H22···H17^viii	3.2722
C50···H42	3.2475	H22···H33^ix	3.5998
C51···H39	3.2367	H23···H2^ix	3.3079
C52···H24	3.4782	H23···H13^ix	2.6707
C52···H38	3.2584	H23···H33^ix	3.5033
C52···H40	3.2499	H23···H34^ix	3.5678
C52···H43	3.4219	H23···H40^i	3.0836
C53···H24	3.5591	H24···H34^ix	2.9677
C53···H37	3.5620	H25···C11^x	3.3297
C53···H42	2.7115	H25···C18^ix	3.1935
C53···H44	3.2679	H25···H3^x	3.5904
C53···H46	3.2613	H25···H4^x	2.4113
C54···H37	3.2691	H25···H12^ix	3.3266
C54···H42	3.1009	H25···H13^ix	2.5292
C54···H45	3.2456	H25···H14^ix	3.2567
C54···H47	3.2488	H25···H40^i	3.5168
C55···H46	3.2448	H25···H45^iii	3.4233
C56···H43	3.2417	H26···C12^i	2.8865
C56···H47	3.2627	H26···C49^i	3.5284
C57···H44	3.2461	H26···H6^i	2.2675
C58···H24	3.0939	H26···H7^i	3.3748
C58···H42	3.3169	H26···H8^i	2.6912
C58···H43	3.2440	H26···H39^i	3.3321
C58···H45	3.2662	H27···C11^x	3.5514
B1···H11	2.8888	H27···C51^vii	3.2489
B1···H13	3.2243	H27···H3^x	2.8460
B1···H26	2.7924	H27···H4^x	3.4432
B1···H28	3.4990	H27···H35^xi	3.1493
H1···H11	2.3922	H27···H41^vii	3.1341
H1···H13	2.7569	H27···H45^iii	3.5649
H1···H14	3.2741	H27···H46^iii	3.0933
H1···H26	2.2212	H28···C56^iii	2.9729
H1···H28	3.1420	H28···C57^iii	2.9267
H1···H29	3.4891	H28···H45^iii	2.6468
H2···H13	3.4693	H28···H46^iii	2.5612
H2···H26	3.2777	H29···C12^i	3.5952
H2···H33	3.4037	H29···C51^vii	3.5841
H3···H6	3.5331	H29···C52^vii	3.4679
H3···H7	2.7033	H29···C54^vii	3.5248
H3···H8	3.5877	H29···H6^i	3.5033
H3···H9	2.8081	H29···H8^i	3.0524
H3···H10	2.6208	H29···H37^vii	3.2546
H4···H6	2.6583	H29···H43^vii	2.8078
H4···H7	2.2944	H30···C21^i	3.4063
H4···H8	3.4127	H30···C48^i	3.4181
H4···H9	2.5197	H30···C49^i	3.2944
H5···H6	3.5242	H30···C50^i	3.3784
H5···H7	3.4124	H30···C51^i	3.5987
H5···H9	2.1992	H30···H8^i	3.5699
H5···H33	3.2787	H30···H12^ix	3.1205
H5···H34	3.2624	H30···H19^i	3.5688
H6···H9	2.1734	H30···H20^i	2.5170
H6···H38	3.0075	H30···H44^vii	3.5540
H7···H9	2.7880	H31···C18^ix	2.8402
H7···H10	3.1309	H31···H4^x	3.5346
H8···H9	2.5037	H31···H12^ix	2.5213
H8···H10	3.2706	H31···H13^ix	2.8863
H9···H33	3.0720	H31···H14^ix	2.6394
H9···H38	2.6196	H31···H20^i	3.3843
H10···H12	3.5294	H31···H36^xi	2.7793
H10···H15	3.4424	H32···C21^i	3.5368
H10···H16	2.1865	H32···C44^xi	3.1223
H11···H12	2.8131	H32···C45^xi	3.2473
H11···H13	2.5136	H32···C55^vii	3.5941
H11···H14	2.2066	H32···H18^i	3.5424
H11···H15	2.2022	H32···H20^i	2.8792
H11···H16	2.8095	H32···H35^xi	2.4445
H11···H17	2.5434	H32···H36^xi	2.6986
H11···H26	3.5405	H32···H44^vii	3.1541
H11···H28	2.6894	H33···C19^xii	3.5867
H11···H29	3.2013	H33···C22^v	3.2758
H12···H15	3.4443	H33···H15^xii	3.4534
H12···H16	2.7578	H33···H16^xii	3.1195
H12···H17	2.3200	H33···H21^v	2.3878
H13···H17	3.4299	H33···H22^v	3.5998
H14···H15	3.5275	H33···H23^v	3.5033
H14···H16	3.5594	H34···C22^v	3.2667
H14···H17	2.6655	H34···C52^v	3.5505
H18···H21	3.5171	H34···C57^v	3.3396
H18···H22	2.6697	H34···C58^v	3.3526
H18···H23	3.5528	H34···H16^xii	3.4121
H18···H24	2.7989	H34···H21^v	2.4340
H18···H25	3.3744	H34···H23^v	3.5678
H19···H21	2.6508	H34···H24^v	2.9677
H19···H22	2.2809	H34···H42^v	2.6319
H19···H23	3.3961	H34···H46^v	3.5700
H19···H24	2.4953	H35···C29^xiii	3.3887
H20···H21	3.5386	H35···C52^v	3.4096
H20···H22	3.4052	H35···C54^v	3.4257
H20···H24	2.1886	H35···C55^v	3.2806
H21···H24	2.1907	H35···H18^iv	3.4519
H22···H24	2.8005	H35···H27^xiii	3.1493
H22···H25	2.9142	H35···H32^xiii	2.4445
H23···H24	2.5276	H35···H41^v	3.4791
H23···H25	2.5026	H35···H42^v	2.7166
H24···H42	2.9720	H35···H44^v	3.4787
H24···H47	2.5730	H36···C18^xiv	3.2356
H25···H27	3.4931	H36···C29^xiii	3.1761
H25···H30	3.5041	H36···H7^xii	2.8667
H25···H31	2.2289	H36···H12^xiv	3.3751
H26···H27	2.8026	H36···H14^xiv	2.3381
H26···H28	2.5038	H36···H18^iv	3.4786
H26···H29	2.1921	H36···H19^iv	3.2056
H26···H30	2.1984	H36···H31^xiii	2.7793
H26···H31	2.8073	H36···H32^xiii	2.6986
H26···H32	2.5436	H37···H7^xii	3.0884
H27···H30	3.4244	H37···H8^xii	3.4251
H27···H31	2.7505	H37···H14^xiv	3.2439
H27···H32	2.2931	H37···H29^xiv	3.2546
H28···H32	3.4112	H39···N21^ii	3.2782
H29···H30	3.4990	H39···N22^ii	2.8609
H29···H31	3.5489	H39···C26^ii	3.1967
H29···H32	2.6407	H39···B1^ii	3.0037
H33···H34	2.3410	H39···H1^ii	3.2847
H34···H35	2.3036	H39···H2^ii	2.4669
H35···H36	2.3233	H39···H15^xiv	3.5276
H36···H37	2.3352	H39···H26^ii	3.3321
H37···H38	2.7832	H39···H47^ii	3.0893
H37···H43	2.4959	H40···C24^ii	3.3182
H38···H39	2.3482	H40···C25^ii	3.2575
H39···H40	2.3118	H40···C26^ii	3.5456
H40···H41	2.3206	H40···C57^ii	3.2753
H41···H42	2.3332	H40···C58^ii	3.3355
H42···H43	3.2603	H40···H12^viii	3.5789
H43···H44	2.3189	H40···H23^ii	3.0836
H44···H45	2.3343	H40···H25^ii	3.5168
H45···H46	2.3292	H40···H46^ii	2.6186
H46···H47	2.3412	H40···H47^ii	2.7434
Cu1···H44^iii	3.4936	H41···C15^viii	3.2228
N11···H44^iii	3.1250	H41···H3^viii	3.1904
N12···H44^iii	3.3942	H41···H10^viii	2.7117
N21···H39^i	3.2782	H41···H12^viii	2.8824
N21···H44^iii	3.4200	H41···H16^viii	3.3506
N21···H45^iii	3.0228	H41···H27^xiv	3.1341
N22···H39^i	2.8609	H41···H35^ix	3.4791
N22···H45^iii	2.9437	H42···C43^ix	3.1607
C11···H25^iv	3.3297	H42···C44^ix	3.2002
C11···H27^iv	3.5514	H42···H34^ix	2.6319
C11···H46^v	3.3963	H42···H35^ix	2.7166
C12···H1^ii	3.3416	H43···C12^xii	3.2274
C12···H14^ii	3.5658	H43···H7^xii	3.2794
C12···H26^ii	2.8865	H43···H8^xii	2.3787
C12···H29^ii	3.5952	H43···H10^xii	3.5686
C12···H43^iii	3.2274	H43···H29^xiv	2.8078
C12···H44^iii	3.5094	H44···Cu1^xii	3.4936
C14···H44^iii	3.2074	H44···N11^xii	3.1250
C15···H41^vi	3.2228	H44···N12^xii	3.3942
C15···H44^iii	3.5314	H44···N21^xii	3.4200
C18···H7^i	3.5020	H44···C12^xii	3.5094
C18···H25^v	3.1935	H44···C14^xii	3.2074
C18···H31^v	2.8402	H44···C15^xii	3.5314
C18···H36^vii	3.2356	H44···C21^xii	3.5609
C19···H19^vi	3.3215	H44···H8^xii	2.6064
C19···H33^iii	3.5867	H44···H18^xii	3.1919
C21···H17^viii	3.2953	H44···H20^xii	3.0638
C21···H30^ii	3.4063	H44···H30^xiv	3.5540
C21···H32^ii	3.5368	H44···H32^xiv	3.1541
C21···H44^iii	3.5609	H44···H35^ix	3.4787
C21···H45^iii	3.4922	H45···N21^xii	3.0228
C22···H2^ix	3.2932	H45···N22^xii	2.9437
C22···H13^ix	3.4591	H45···C21^xii	3.4922
C22···H17^viii	3.5022	H45···C24^xii	3.0022
C22···H33^ix	3.2758	H45···C25^xii	2.9494
C22···H34^ix	3.2667	H45···C26^xii	2.9214
C24···H40^i	3.3182	H45···C28^xii	3.4074
C24···H45^iii	3.0022	H45···H4^ix	3.4738
C25···H4^x	3.0414	H45···H5^ix	3.1525
C25···H13^ix	3.3133	H45···H18^xii	2.7229
C25···H40^i	3.2575	H45···H25^xii	3.4233
C25···H45^iii	2.9494	H45···H27^xii	3.5649
C26···H39^i	3.1967	H45···H28^xii	2.6468
C26···H40^i	3.5456	H46···C11^ix	3.3963
C26···H45^iii	2.9214	H46···C28^xii	3.2554
C27···H6^i	3.2574	H46···C50^i	3.0794
C27···H8^i	3.4606	H46···H3^ix	2.9964
C28···H45^iii	3.4074	H46···H5^ix	2.9540
C28···H46^iii	3.2554	H46···H27^xii	3.0933
C29···H12^ix	3.2326	H46···H28^xii	2.5612
C29···H14^ix	3.4999	H46···H34^ix	3.5700
C29···H20^i	3.0726	H46···H40^i	2.6186
C29···H35^xi	3.3887	H47···C49^i	3.5616
C29···H36^xi	3.1761	H47···C50^i	3.3873
C41···H16^xii	3.4084	H47···H15^xii	3.2648
C42···H16^xii	2.9791	H47···H39^i	3.0893
C42···H21^v	2.9723	H47···H40^i	2.7434
C43···H16^xii	3.1730
P1—Cu1—N11	127.93 (6)	C14—C13—H9	107.683
P1—Cu1—N21	132.71 (7)	C14—C15—H10	127.161
N11—Cu1—N21	98.99 (9)	C16—C15—H10	127.164
Cu1—P1—C41	111.92 (10)	C16—C17—H11	107.873
Cu1—P1—C47	116.66 (9)	C18—C17—H11	107.882
Cu1—P1—C53	114.10 (9)	C19—C17—H11	107.876
C41—P1—C47	105.04 (13)	C17—C18—H12	109.465
C41—P1—C53	104.00 (12)	C17—C18—H13	109.471
C47—P1—C53	103.88 (12)	C17—C18—H14	109.474
Cu1—N11—N12	114.69 (16)	H12—C18—H13	109.471
Cu1—N11—C14	135.2 (2)	H12—C18—H14	109.472
N12—N11—C14	106.7 (3)	H13—C18—H14	109.475
N11—N12—C16	109.5 (2)	C17—C19—H15	109.481
N11—N12—B1	117.4 (3)	C17—C19—H16	109.464
C16—N12—B1	132.6 (3)	C17—C19—H17	109.467
Cu1—N21—N22	116.63 (15)	H15—C19—H16	109.476
Cu1—N21—C24	135.99 (19)	H15—C19—H17	109.471
N22—N21—C24	107.4 (2)	H16—C19—H17	109.469
N21—N22—C26	109.9 (2)	C23—C21—H18	109.474
N21—N22—B1	118.5 (2)	C23—C21—H19	109.484
C26—N22—B1	131.3 (3)	C23—C21—H20	109.467
C11—C13—C12	110.8 (4)	H18—C21—H19	109.468
C11—C13—C14	111.2 (3)	H18—C21—H20	109.471
C12—C13—C14	111.6 (3)	H19—C21—H20	109.464
N11—C14—C13	120.2 (3)	C23—C22—H21	109.470
N11—C14—C15	109.9 (3)	C23—C22—H22	109.466
C13—C14—C15	129.9 (3)	C23—C22—H23	109.473
C14—C15—C16	105.7 (3)	H21—C22—H22	109.474
N12—C16—C15	108.3 (3)	H21—C22—H23	109.472
N12—C16—C17	122.1 (3)	H22—C22—H23	109.473
C15—C16—C17	129.5 (3)	C21—C23—H24	107.970
C16—C17—C18	110.7 (3)	C22—C23—H24	107.959
C16—C17—C19	111.3 (3)	C24—C23—H24	107.968
C18—C17—C19	111.0 (4)	C24—C25—H25	126.740
C21—C23—C22	110.3 (4)	C26—C25—H25	126.728
C21—C23—C24	110.9 (4)	C26—C27—H26	107.618
C22—C23—C24	111.6 (3)	C28—C27—H26	107.619
N21—C24—C23	120.5 (3)	C29—C27—H26	107.618
N21—C24—C25	109.0 (3)	C27—C28—H27	109.473
C23—C24—C25	130.4 (3)	C27—C28—H28	109.469
C24—C25—C26	106.5 (2)	C27—C28—H29	109.468
N22—C26—C25	107.1 (3)	H27—C28—H28	109.478
N22—C26—C27	123.0 (3)	H27—C28—H29	109.475
C25—C26—C27	129.9 (3)	H28—C28—H29	109.465
C26—C27—C28	112.0 (3)	C27—C29—H30	109.473
C26—C27—C29	111.4 (3)	C27—C29—H31	109.475
C28—C27—C29	110.4 (3)	C27—C29—H32	109.471
P1—C41—C42	117.1 (3)	H30—C29—H31	109.477
P1—C41—C46	124.6 (3)	H30—C29—H32	109.466
C42—C41—C46	118.3 (3)	H31—C29—H32	109.466
C41—C42—C43	120.5 (3)	C41—C42—H33	119.735
C42—C43—C44	120.6 (4)	C43—C42—H33	119.743
C43—C44—C45	119.6 (3)	C42—C43—H34	119.703
C44—C45—C46	120.6 (4)	C44—C43—H34	119.705
C41—C46—C45	120.3 (3)	C43—C44—H35	120.172
P1—C47—C48	120.9 (3)	C45—C44—H35	120.182
P1—C47—C52	120.4 (2)	C44—C45—H36	119.701
C48—C47—C52	118.5 (3)	C46—C45—H36	119.685
C47—C48—C49	120.2 (3)	C41—C46—H37	119.858
C48—C49—C50	120.1 (4)	C45—C46—H37	119.860
C49—C50—C51	120.6 (4)	C47—C48—H38	119.914
C50—C51—C52	120.0 (4)	C49—C48—H38	119.914
C47—C52—C51	120.7 (3)	C48—C49—H39	119.957
P1—C53—C54	122.8 (2)	C50—C49—H39	119.960
P1—C53—C58	118.5 (2)	C49—C50—H40	119.720
C54—C53—C58	118.7 (3)	C51—C50—H40	119.724
C53—C54—C55	121.2 (3)	C50—C51—H41	119.983
C54—C55—C56	119.9 (3)	C52—C51—H41	119.982
C55—C56—C57	119.7 (3)	C47—C52—H42	119.672
C56—C57—C58	120.4 (3)	C51—C52—H42	119.665
C53—C58—C57	120.1 (3)	C53—C54—H43	119.378
N12—B1—N22	109.1 (3)	C55—C54—H43	119.384
C13—C11—H3	109.466	C54—C55—H44	120.062
C13—C11—H4	109.464	C56—C55—H44	120.065
C13—C11—H5	109.479	C55—C56—H45	120.160
H3—C11—H4	109.473	C57—C56—H45	120.159
H3—C11—H5	109.468	C56—C57—H46	119.796
H4—C11—H5	109.477	C58—C57—H46	119.790
C13—C12—H6	109.467	C53—C58—H47	119.956
C13—C12—H7	109.468	C57—C58—H47	119.944
C13—C12—H8	109.463	N12—B1—H1	109.852
H6—C12—H7	109.471	N12—B1—H2	109.850
H6—C12—H8	109.478	N22—B1—H1	109.852
H7—C12—H8	109.480	N22—B1—H2	109.849
C11—C13—H9	107.676	H1—B1—H2	108.277
C12—C13—H9	107.696
P1—Cu1—N11—N12	−151.16 (9)	N21—N22—C26—C25	−1.2 (3)
P1—Cu1—N11—C14	53.1 (3)	N21—N22—C26—C27	178.3 (2)
N11—Cu1—P1—C41	23.46 (10)	N21—N22—B1—N12	58.3 (3)
N11—Cu1—P1—C47	−97.54 (9)	C26—N22—B1—N12	−128.4 (3)
N11—Cu1—P1—C53	141.22 (9)	B1—N22—C26—C25	−174.9 (3)
P1—Cu1—N21—N22	138.55 (11)	B1—N22—C26—C27	4.6 (4)
P1—Cu1—N21—C24	−39.6 (3)	C11—C13—C14—N11	−119.8 (4)
N21—Cu1—P1—C41	−147.99 (9)	C11—C13—C14—C15	58.1 (5)
N21—Cu1—P1—C47	91.00 (10)	C12—C13—C14—N11	115.9 (4)
N21—Cu1—P1—C53	−30.24 (10)	C12—C13—C14—C15	−66.2 (5)
N11—Cu1—N21—N22	−34.64 (17)	N11—C14—C15—C16	0.1 (3)
N11—Cu1—N21—C24	147.2 (2)	C13—C14—C15—C16	−177.9 (3)
N21—Cu1—N11—N12	22.50 (16)	C14—C15—C16—N12	0.3 (3)
N21—Cu1—N11—C14	−133.24 (19)	C14—C15—C16—C17	179.3 (3)
Cu1—P1—C41—C42	21.8 (3)	N12—C16—C17—C18	85.9 (3)
Cu1—P1—C41—C46	−159.18 (18)	N12—C16—C17—C19	−150.1 (3)
Cu1—P1—C47—C48	80.86 (18)	C15—C16—C17—C18	−93.0 (4)
Cu1—P1—C47—C52	−92.91 (18)	C15—C16—C17—C19	31.0 (4)
Cu1—P1—C53—C54	−171.57 (14)	C21—C23—C24—N21	−82.7 (4)
Cu1—P1—C53—C58	6.50 (19)	C21—C23—C24—C25	95.1 (4)
C41—P1—C47—C48	−43.7 (2)	C22—C23—C24—N21	153.9 (3)
C41—P1—C47—C52	142.52 (18)	C22—C23—C24—C25	−28.3 (5)
C47—P1—C41—C42	149.28 (19)	N21—C24—C25—C26	0.4 (3)
C47—P1—C41—C46	−31.7 (3)	C23—C24—C25—C26	−177.6 (3)
C41—P1—C53—C54	−49.4 (2)	C24—C25—C26—N22	0.5 (3)
C41—P1—C53—C58	128.71 (17)	C24—C25—C26—C27	−179.0 (3)
C53—P1—C41—C42	−101.9 (2)	N22—C26—C27—C28	90.3 (3)
C53—P1—C41—C46	77.2 (3)	N22—C26—C27—C29	−145.6 (3)
C47—P1—C53—C54	60.34 (19)	C25—C26—C27—C28	−90.4 (4)
C47—P1—C53—C58	−121.59 (17)	C25—C26—C27—C29	33.8 (4)
C53—P1—C47—C48	−152.65 (17)	P1—C41—C42—C43	177.6 (2)
C53—P1—C47—C52	33.6 (2)	P1—C41—C46—C45	−178.1 (2)
Cu1—N11—N12—C16	−161.70 (12)	C42—C41—C46—C45	1.0 (5)
Cu1—N11—N12—B1	25.4 (3)	C46—C41—C42—C43	−1.5 (5)
Cu1—N11—C14—C13	−25.2 (4)	C41—C42—C43—C44	1.0 (6)
Cu1—N11—C14—C15	156.55 (16)	C42—C43—C44—C45	0.1 (6)
N12—N11—C14—C13	177.76 (18)	C43—C44—C45—C46	−0.6 (6)
N12—N11—C14—C15	−0.5 (3)	C44—C45—C46—C41	0.1 (6)
C14—N11—N12—C16	0.7 (3)	P1—C47—C48—C49	−174.87 (18)
C14—N11—N12—B1	−172.19 (17)	P1—C47—C52—C51	174.67 (17)
N11—N12—C16—C15	−0.7 (3)	C48—C47—C52—C51	0.8 (4)
N11—N12—C16—C17	−179.76 (18)	C52—C47—C48—C49	−1.0 (4)
N11—N12—B1—N22	−73.2 (3)	C47—C48—C49—C50	1.2 (5)
C16—N12—B1—N22	115.9 (3)	C48—C49—C50—C51	−1.3 (5)
B1—N12—C16—C15	170.8 (2)	C49—C50—C51—C52	1.0 (5)
B1—N12—C16—C17	−8.3 (4)	C50—C51—C52—C47	−0.8 (5)
Cu1—N21—N22—C26	−177.28 (13)	P1—C53—C54—C55	178.06 (17)
Cu1—N21—N22—B1	−2.6 (3)	P1—C53—C58—C57	−179.04 (18)
Cu1—N21—C24—C23	−4.6 (4)	C54—C53—C58—C57	−0.9 (4)
Cu1—N21—C24—C25	177.22 (17)	C58—C53—C54—C55	0.0 (4)
N22—N21—C24—C23	177.1 (2)	C53—C54—C55—C56	0.6 (5)
N22—N21—C24—C25	−1.1 (3)	C54—C55—C56—C57	−0.3 (5)
C24—N21—N22—C26	1.4 (3)	C55—C56—C57—C58	−0.6 (5)
C24—N21—N22—B1	176.03 (19)	C56—C57—C58—C53	1.2 (5)

Symmetry codes: (i) x+1/2, y−1/2, z; (ii) x−1/2, y+1/2, z; (iii) x+1/2, y+1/2, z; (iv) x−1/2, −y+3/2, z−1/2; (v) x, −y+1, z−1/2; (vi) x+1/2, −y+3/2, z−1/2; (vii) x+1, y, z; (viii) x−1/2, −y+3/2, z+1/2; (ix) x, −y+1, z+1/2; (x) x+1/2, −y+3/2, z+1/2; (xi) x+1, −y+1, z+1/2; (xii) x−1/2, y−1/2, z; (xiii) x−1, −y+1, z−1/2; (xiv) x−1, y, z.