A bis-chelated mononuclear nickel(II) complex with a dithiocarbazate ligand bearing a long saturated alkyl chain exhibits a distorted cis square planar coordination of the metal with two ligands conformationally different from the proligand.
Supporting information
CCDC references: 2254903; 2254853
S-
n-Octyl 3-(1-phenylethylidene)dithiocarbazate (H
L)
top
Crystal data top
C17H26N2S2 | Z = 2 |
Mr = 322.52 | F(000) = 348 |
Triclinic, P1 | Dx = 1.162 Mg m−3 |
a = 4.9925 (6) Å | Mo Kα radiation, λ = 0.71075 Å |
b = 12.4283 (16) Å | Cell parameters from 6282 reflections |
c = 15.0643 (19) Å | θ = 2.0–27.5° |
α = 98.420 (7)° | µ = 0.28 mm−1 |
β = 94.302 (7)° | T = 173 K |
γ = 91.150 (6)° | Plate, colorless |
V = 921.6 (2) Å3 | 0.19 × 0.10 × 0.07 mm |
Data collection top
Rigaku R-AXIS RAPID diffractometer | 3093 reflections with I > 2σ(I) |
ω scans | Rint = 0.037 |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | θmax = 27.5°, θmin = 2.3° |
Tmin = 0.410, Tmax = 0.980 | h = −6→5 |
8449 measured reflections | k = −16→16 |
4181 independent reflections | l = −19→19 |
Refinement top
Refinement on F2 | 0 restraints |
Least-squares matrix: full | Hydrogen site location: mixed |
R[F2 > 2σ(F2)] = 0.071 | H atoms treated by a mixture of independent and constrained refinement |
wR(F2) = 0.196 | w = 1/[σ2(Fo2) + (0.0649P)2 + 1.6447P] where P = (Fo2 + 2Fc2)/3 |
S = 1.08 | (Δ/σ)max < 0.001 |
4181 reflections | Δρmax = 0.55 e Å−3 |
242 parameters | Δρmin = −0.32 e Å−3 |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
N1 | −0.1043 (6) | 0.7323 (2) | 0.1266 (2) | 0.0401 (7) | |
N2 | −0.2090 (6) | 0.6296 (2) | 0.0940 (2) | 0.0409 (7) | |
H2N | −0.344 (7) | 0.616 (3) | 0.053 (2) | 0.031 (9)* | |
S1 | −0.20157 (19) | 0.41740 (7) | 0.08485 (6) | 0.0432 (3) | |
S2 | 0.16745 (18) | 0.58140 (7) | 0.20863 (6) | 0.0431 (3) | |
C1 | −0.0902 (7) | 0.9225 (3) | 0.1334 (3) | 0.0423 (8) | |
C2A | −0.2308 (19) | 1.0181 (6) | 0.1290 (6) | 0.0504 (19) | 0.5 |
H2A | −0.412706 | 1.013940 | 0.104862 | 0.060* | 0.5 |
C3A | −0.107 (2) | 1.1189 (7) | 0.1597 (7) | 0.056 (2) | 0.5 |
H3A | −0.196708 | 1.183166 | 0.149810 | 0.067* | 0.5 |
C2 | −0.1086 (16) | 1.0104 (6) | 0.0810 (6) | 0.0461 (17) | 0.5 |
H2 | −0.190437 | 0.998522 | 0.021250 | 0.055* | 0.5 |
C3 | −0.0052 (18) | 1.1128 (7) | 0.1190 (7) | 0.049 (2) | 0.5 |
H3 | −0.031247 | 1.173157 | 0.087547 | 0.058* | 0.5 |
C4 | 0.1357 (10) | 1.1268 (3) | 0.2027 (3) | 0.0619 (12) | |
H4 | 0.221191 | 1.194944 | 0.226559 | 0.074* | |
C5A | 0.283 (2) | 1.0330 (8) | 0.2134 (7) | 0.060 (2) | 0.5 |
H5A | 0.460126 | 1.039291 | 0.241511 | 0.072* | 0.5 |
C6A | 0.1629 (19) | 0.9312 (8) | 0.1820 (7) | 0.049 (2) | 0.5 |
H6A | 0.252208 | 0.867290 | 0.193560 | 0.059* | 0.5 |
C5 | 0.151 (2) | 1.0410 (8) | 0.2510 (7) | 0.057 (2) | 0.5 |
H5 | 0.230184 | 1.052526 | 0.311120 | 0.068* | 0.5 |
C6 | 0.053 (2) | 0.9385 (8) | 0.2135 (6) | 0.046 (2) | 0.5 |
H6 | 0.087011 | 0.878548 | 0.244745 | 0.055* | 0.5 |
C7 | −0.2107 (8) | 0.8138 (3) | 0.0956 (3) | 0.0471 (9) | |
C8A | −0.477 (4) | 0.804 (2) | 0.0421 (15) | 0.062 (5) | 0.5 |
H8A | −0.457921 | 0.763747 | −0.017873 | 0.075* | 0.5 |
H8B | −0.540448 | 0.877297 | 0.036156 | 0.075* | 0.5 |
H8C | −0.606766 | 0.765985 | 0.072809 | 0.075* | 0.5 |
C8 | −0.405 (4) | 0.7988 (19) | 0.0111 (15) | 0.067 (6) | 0.5 |
H8D | −0.329965 | 0.748035 | −0.036166 | 0.081* | 0.5 |
H8E | −0.430501 | 0.869171 | −0.009852 | 0.081* | 0.5 |
H8F | −0.577752 | 0.769499 | 0.024940 | 0.081* | 0.5 |
C9 | −0.0943 (7) | 0.5445 (3) | 0.1251 (2) | 0.0363 (7) | |
C10 | 0.2629 (7) | 0.4508 (3) | 0.2385 (2) | 0.0406 (8) | |
H10A | 0.105264 | 0.412724 | 0.257139 | 0.049* | |
H10B | 0.330537 | 0.404971 | 0.185987 | 0.049* | |
C11 | 0.4822 (7) | 0.4701 (3) | 0.3158 (2) | 0.0421 (8) | |
H11A | 0.637148 | 0.509765 | 0.297023 | 0.051* | |
H11B | 0.412573 | 0.515802 | 0.368017 | 0.051* | |
C12 | 0.5748 (7) | 0.3632 (3) | 0.3436 (2) | 0.0433 (8) | |
H12A | 0.651622 | 0.319515 | 0.291733 | 0.052* | |
H12B | 0.416427 | 0.321934 | 0.358284 | 0.052* | |
C13 | 0.7831 (8) | 0.3763 (3) | 0.4239 (2) | 0.0458 (8) | |
H13A | 0.941383 | 0.417864 | 0.409574 | 0.055* | |
H13B | 0.706096 | 0.419128 | 0.476121 | 0.055* | |
C14 | 0.8745 (8) | 0.2683 (3) | 0.4499 (3) | 0.0479 (9) | |
H14A | 0.714985 | 0.226115 | 0.462490 | 0.057* | |
H14B | 0.954852 | 0.226428 | 0.398009 | 0.057* | |
C15 | 1.0773 (8) | 0.2790 (4) | 0.5313 (3) | 0.0520 (9) | |
H15A | 1.237728 | 0.320556 | 0.518707 | 0.062* | |
H15B | 0.997681 | 0.321188 | 0.583283 | 0.062* | |
C16 | 1.1647 (10) | 0.1709 (4) | 0.5568 (3) | 0.0652 (12) | |
H16A | 1.244326 | 0.128450 | 0.504959 | 0.078* | |
H16B | 1.004888 | 0.129348 | 0.569939 | 0.078* | |
C17 | 1.3697 (11) | 0.1840 (5) | 0.6387 (4) | 0.0820 (16) | |
H17A | 1.429776 | 0.112155 | 0.649602 | 0.098* | |
H17B | 1.286255 | 0.219771 | 0.691591 | 0.098* | |
H17C | 1.524302 | 0.228373 | 0.627259 | 0.098* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
N1 | 0.0423 (16) | 0.0350 (14) | 0.0419 (16) | −0.0025 (12) | −0.0012 (13) | 0.0052 (12) |
N2 | 0.0427 (16) | 0.0373 (15) | 0.0416 (16) | −0.0035 (12) | −0.0029 (14) | 0.0062 (13) |
S1 | 0.0482 (5) | 0.0357 (4) | 0.0442 (5) | −0.0042 (4) | −0.0046 (4) | 0.0053 (4) |
S2 | 0.0441 (5) | 0.0387 (5) | 0.0449 (5) | −0.0039 (4) | −0.0062 (4) | 0.0064 (4) |
C1 | 0.0404 (18) | 0.0364 (17) | 0.049 (2) | 0.0006 (14) | −0.0064 (16) | 0.0067 (15) |
C2A | 0.053 (5) | 0.042 (4) | 0.054 (5) | 0.006 (4) | −0.011 (4) | 0.003 (4) |
C3A | 0.073 (7) | 0.032 (4) | 0.061 (6) | 0.005 (4) | −0.009 (5) | 0.003 (4) |
C2 | 0.043 (4) | 0.043 (4) | 0.048 (4) | 0.004 (3) | −0.012 (4) | 0.001 (4) |
C3 | 0.045 (5) | 0.037 (4) | 0.065 (6) | −0.002 (4) | −0.005 (4) | 0.017 (4) |
C4 | 0.075 (3) | 0.038 (2) | 0.067 (3) | −0.0090 (19) | −0.016 (2) | 0.0005 (19) |
C5A | 0.060 (6) | 0.050 (5) | 0.064 (6) | −0.004 (5) | −0.020 (5) | 0.002 (5) |
C6A | 0.045 (5) | 0.044 (4) | 0.058 (6) | −0.007 (4) | −0.008 (4) | 0.011 (4) |
C5 | 0.061 (6) | 0.053 (5) | 0.050 (5) | 0.000 (5) | −0.013 (4) | −0.004 (4) |
C6 | 0.053 (6) | 0.039 (4) | 0.045 (5) | −0.002 (4) | −0.007 (4) | 0.006 (4) |
C7 | 0.0436 (19) | 0.0381 (18) | 0.057 (2) | −0.0040 (15) | −0.0158 (17) | 0.0091 (16) |
C8A | 0.046 (8) | 0.047 (6) | 0.089 (15) | −0.002 (5) | −0.026 (7) | 0.007 (9) |
C8 | 0.075 (14) | 0.035 (5) | 0.083 (13) | −0.001 (8) | −0.039 (9) | 0.006 (7) |
C9 | 0.0375 (17) | 0.0376 (17) | 0.0341 (16) | −0.0016 (13) | 0.0065 (14) | 0.0047 (13) |
C10 | 0.0409 (18) | 0.0404 (18) | 0.0407 (18) | 0.0006 (14) | 0.0001 (15) | 0.0080 (15) |
C11 | 0.0419 (19) | 0.0436 (19) | 0.0394 (18) | −0.0007 (15) | −0.0022 (15) | 0.0045 (15) |
C12 | 0.0411 (19) | 0.047 (2) | 0.0403 (19) | −0.0044 (15) | −0.0051 (15) | 0.0073 (15) |
C13 | 0.046 (2) | 0.052 (2) | 0.0380 (19) | −0.0030 (16) | −0.0043 (16) | 0.0056 (16) |
C14 | 0.0417 (19) | 0.057 (2) | 0.044 (2) | −0.0016 (16) | −0.0046 (16) | 0.0084 (17) |
C15 | 0.046 (2) | 0.065 (3) | 0.045 (2) | 0.0032 (18) | −0.0029 (17) | 0.0120 (19) |
C16 | 0.059 (3) | 0.076 (3) | 0.065 (3) | 0.008 (2) | −0.004 (2) | 0.027 (2) |
C17 | 0.069 (3) | 0.114 (5) | 0.067 (3) | 0.018 (3) | −0.010 (3) | 0.034 (3) |
Geometric parameters (Å, º) top
N1—C7 | 1.284 (4) | C8A—H8A | 0.9800 |
N1—N2 | 1.377 (4) | C8A—H8B | 0.9800 |
N2—C9 | 1.340 (4) | C8A—H8C | 0.9800 |
N2—H2N | 0.87 (4) | C8—H8D | 0.9800 |
S1—C9 | 1.669 (3) | C8—H8E | 0.9800 |
S2—C9 | 1.750 (3) | C8—H8F | 0.9800 |
S2—C10 | 1810 (3) | C10—C11 | 1.526 (5) |
C1—C6 | 1.342 (10) | C10—H10A | 0.9900 |
C1—C2A | 1.399 (9) | C10—H10B | 0.9900 |
C1—C6A | 1.407 (10) | C11—C12 | 1.521 (5) |
C1—C2 | 1.438 (9) | C11—H11A | 0.9900 |
C1—C7 | 1.484 (5) | C11—H11B | 0.9900 |
C2A—C3A | 1.387 (12) | C12—C13 | 1.523 (5) |
C2A—H2A | 0.9500 | C12—H12A | 0.9900 |
C3A—C4 | 1.323 (11) | C12—H12B | 0.9900 |
C3A—H3A | 0.9500 | C13—C14 | 1.521 (5) |
C2—C3 | 1.390 (12) | C13—H13A | 0.9900 |
C2—H2 | 0.9500 | C13—H13B | 0.9900 |
C3—C4 | 1.382 (10) | C14—C15 | 1.519 (5) |
C3—H3 | 0.9500 | C14—H14A | 0.9900 |
C4—C5 | 1.377 (11) | C14—H14B | 0.9900 |
C4—C5A | 1.413 (11) | C15—C16 | 1.513 (6) |
C4—H4 | 0.9500 | C15—H15A | 0.9900 |
C5A—C6A | 1.390 (13) | C15—H15B | 0.9900 |
C5A—H5A | 0.9500 | C16—C17 | 1.530 (6) |
C6A—H6A | 0.9500 | C16—H16A | 0.9900 |
C5—C6 | 1.380 (13) | C16—H16B | 0.9900 |
C5—H5 | 0.9500 | C17—H17A | 0.9800 |
C6—H6 | 0.9500 | C17—H17B | 0.9800 |
C7—C8A | 1.50 (2) | C17—H17C | 0.9800 |
C7—C8 | 1.53 (2) | | |
| | | |
C7—N1—N2 | 118.4 (3) | H8D—C8—H8F | 109.5 |
C9—N2—N1 | 118.4 (3) | H8E—C8—H8F | 109.5 |
C9—N2—H2N | 117 (2) | N2—C9—S1 | 120.8 (3) |
N1—N2—H2N | 124 (2) | N2—C9—S2 | 113.6 (2) |
C9—S2—C10 | 102.08 (16) | S1—C9—S2 | 125.6 (2) |
C2A—C1—C6A | 117.8 (6) | C11—C10—S2 | 108.4 (2) |
C6—C1—C2 | 119.0 (6) | C11—C10—H10A | 110.0 |
C6—C1—C7 | 120.9 (5) | S2—C10—H10A | 110.0 |
C2A—C1—C7 | 121.9 (4) | C11—C10—H10B | 110.0 |
C6A—C1—C7 | 120.1 (5) | S2—C10—H10B | 110.0 |
C2—C1—C7 | 119.9 (4) | H10A—C10—H10B | 108.4 |
C3A—C2A—C1 | 120.5 (8) | C12—C11—C10 | 111.2 (3) |
C3A—C2A—H2A | 119.8 | C12—C11—H11A | 109.4 |
C1—C2A—H2A | 119.8 | C10—C11—H11A | 109.4 |
C4—C3A—C2A | 121.0 (8) | C12—C11—H11B | 109.4 |
C4—C3A—H3A | 119.5 | C10—C11—H11B | 109.4 |
C2A—C3A—H3A | 119.5 | H11A—C11—H11B | 108.0 |
C3—C2—C1 | 119.1 (7) | C11—C12—C13 | 114.1 (3) |
C3—C2—H2 | 120.4 | C11—C12—H12A | 108.7 |
C1—C2—H2 | 120.4 | C13—C12—H12A | 108.7 |
C4—C3—C2 | 119.9 (8) | C11—C12—H12B | 108.7 |
C4—C3—H3 | 120.1 | C13—C12—H12B | 108.7 |
C2—C3—H3 | 120.1 | H12A—C12—H12B | 107.6 |
C5—C4—C3 | 119.4 (6) | C14—C13—C12 | 113.2 (3) |
C3A—C4—C5A | 121.0 (6) | C14—C13—H13A | 108.9 |
C5—C4—H4 | 120.3 | C12—C13—H13A | 108.9 |
C3—C4—H4 | 120.3 | C14—C13—H13B | 108.9 |
C6A—C5A—C4 | 118.9 (8) | C12—C13—H13B | 108.9 |
C6A—C5A—H5A | 120.6 | H13A—C13—H13B | 107.8 |
C4—C5A—H5A | 120.6 | C15—C14—C13 | 114.3 (3) |
C5A—C6A—C1 | 120.2 (9) | C15—C14—H14A | 108.7 |
C5A—C6A—H6A | 119.9 | C13—C14—H14A | 108.7 |
C1—C6A—H6A | 119.9 | C15—C14—H14B | 108.7 |
C4—C5—C6 | 121.0 (8) | C13—C14—H14B | 108.7 |
C4—C5—H5 | 119.5 | H14A—C14—H14B | 107.6 |
C6—C5—H5 | 119.5 | C16—C15—C14 | 113.7 (4) |
C1—C6—C5 | 120.8 (8) | C16—C15—H15A | 108.8 |
C1—C6—H6 | 119.6 | C14—C15—H15A | 108.8 |
C5—C6—H6 | 119.6 | C16—C15—H15B | 108.8 |
N1—C7—C1 | 116.1 (3) | C14—C15—H15B | 108.8 |
N1—C7—C8A | 122.2 (10) | H15A—C15—H15B | 107.7 |
C1—C7—C8A | 120.2 (10) | C15—C16—C17 | 112.6 (4) |
N1—C7—C8 | 121.7 (9) | C15—C16—H16A | 109.1 |
C1—C7—C8 | 120.9 (9) | C17—C16—H16A | 109.1 |
C7—C8A—H8A | 109.5 | C15—C16—H16B | 109.1 |
C7—C8A—H8B | 109.5 | C17—C16—H16B | 109.1 |
H8A—C8A—H8B | 109.5 | H16A—C16—H16B | 107.8 |
C7—C8A—H8C | 109.5 | C16—C17—H17A | 109.5 |
H8A—C8A—H8C | 109.5 | C16—C17—H17B | 109.5 |
H8B—C8A—H8C | 109.5 | H17A—C17—H17B | 109.5 |
C7—C8—H8D | 109.5 | C16—C17—H17C | 109.5 |
C7—C8—H8E | 109.5 | H17A—C17—H17C | 109.5 |
H8D—C8—H8E | 109.5 | H17B—C17—H17C | 109.5 |
C7—C8—H8F | 109.5 | | |
| | | |
C7—N1—N2—C9 | 178.7 (3) | C6—C1—C7—N1 | −21.6 (7) |
C6A—C1—C2A—C3A | 9.7 (13) | C2A—C1—C7—N1 | −159.1 (6) |
C7—C1—C2A—C3A | −175.8 (8) | C6A—C1—C7—N1 | 15.2 (7) |
C1—C2A—C3A—C4 | −7.6 (16) | C2—C1—C7—N1 | 153.7 (5) |
C6—C1—C2—C3 | −7.5 (12) | C2A—C1—C7—C8A | 7.0 (11) |
C7—C1—C2—C3 | 177.2 (7) | C6A—C1—C7—C8A | −178.7 (10) |
C1—C2—C3—C4 | 6.1 (13) | C6—C1—C7—C8 | 171.6 (10) |
C2A—C3A—C4—C5A | 4.2 (15) | C2—C1—C7—C8 | −13.2 (11) |
C2—C3—C4—C5 | −5.9 (13) | N1—N2—C9—S1 | −177.0 (2) |
C3A—C4—C5A—C6A | −3.3 (15) | N1—N2—C9—S2 | 3.0 (4) |
C4—C5A—C6A—C1 | 5.7 (16) | C10—S2—C9—N2 | 177.4 (3) |
C2A—C1—C6A—C5A | −8.9 (13) | C10—S2—C9—S1 | −2.6 (3) |
C7—C1—C6A—C5A | 176.6 (8) | C9—S2—C10—C11 | −176.7 (2) |
C3—C4—C5—C6 | 7.0 (14) | S2—C10—C11—C12 | −179.2 (3) |
C2—C1—C6—C5 | 8.6 (13) | C10—C11—C12—C13 | −176.8 (3) |
C7—C1—C6—C5 | −176.0 (8) | C11—C12—C13—C14 | −179.5 (3) |
C4—C5—C6—C1 | −8.6 (16) | C12—C13—C14—C15 | −178.6 (3) |
N2—N1—C7—C1 | 179.8 (3) | C13—C14—C15—C16 | 179.6 (4) |
N2—N1—C7—C8A | 14.0 (10) | C14—C15—C16—C17 | 179.8 (4) |
N2—N1—C7—C8 | −13.4 (10) | | |
Bis[
S-
n-octyl 3-(1-phenylethylidene)dithiocarbazato]nickel(II) (NiL2)
top
Crystal data top
[Ni(C17H25N2S2)2] | F(000) = 1496 |
Mr = 701.73 | Dx = 1.264 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71075 Å |
a = 13.6399 (3) Å | Cell parameters from 26150 reflections |
b = 17.6532 (5) Å | θ = 1.8–27.5° |
c = 16.7596 (3) Å | µ = 0.78 mm−1 |
β = 114.000 (8)° | T = 173 K |
V = 3686.6 (3) Å3 | Needle, green |
Z = 4 | 0.27 × 0.09 × 0.03 mm |
Data collection top
Rigaku R-AXIS RAPID diffractometer | 6674 reflections with I > 2σ(I) |
Detector resolution: 10.000 pixels mm-1 | Rint = 0.038 |
ω scans | θmax = 27.5°, θmin = 1.8° |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | h = −17→17 |
Tmin = 0.737, Tmax = 0.977 | k = −22→22 |
35807 measured reflections | l = −20→21 |
8419 independent reflections | |
Refinement top
Refinement on F2 | 0 restraints |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.042 | H-atom parameters constrained |
wR(F2) = 0.096 | w = 1/[σ2(Fo2) + (0.0435P)2 + 1.4889P] where P = (Fo2 + 2Fc2)/3 |
S = 1.04 | (Δ/σ)max = 0.001 |
8419 reflections | Δρmax = 0.60 e Å−3 |
392 parameters | Δρmin = −0.25 e Å−3 |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Ni1 | 0.74039 (2) | 0.25330 (2) | 0.25385 (2) | 0.03168 (8) | |
S1 | 0.84963 (5) | 0.16206 (3) | 0.31516 (4) | 0.04322 (14) | |
S2 | 1.08344 (5) | 0.17784 (3) | 0.40403 (4) | 0.05019 (16) | |
S3 | 0.61639 (5) | 0.17236 (3) | 0.18452 (4) | 0.04295 (14) | |
S4 | 0.38828 (5) | 0.20819 (3) | 0.08597 (4) | 0.04600 (14) | |
N1 | 0.84293 (13) | 0.31828 (8) | 0.34158 (10) | 0.0311 (3) | |
N2 | 0.95110 (13) | 0.29419 (9) | 0.37651 (10) | 0.0357 (4) | |
N3 | 0.65212 (13) | 0.32728 (8) | 0.17072 (10) | 0.0301 (3) | |
N4 | 0.54030 (13) | 0.31270 (9) | 0.13143 (10) | 0.0345 (4) | |
C1 | 0.71951 (16) | 0.41247 (10) | 0.34871 (12) | 0.0313 (4) | |
C2 | 0.63589 (16) | 0.36389 (11) | 0.34242 (12) | 0.0353 (4) | |
H2 | 0.649382 | 0.311221 | 0.352804 | 0.042* | |
C3 | 0.53335 (17) | 0.39187 (12) | 0.32114 (14) | 0.0423 (5) | |
H3 | 0.476887 | 0.358265 | 0.316505 | 0.051* | |
C4 | 0.51303 (18) | 0.46818 (13) | 0.30670 (15) | 0.0455 (5) | |
H4 | 0.442648 | 0.487096 | 0.292229 | 0.055* | |
C5 | 0.59488 (19) | 0.51736 (12) | 0.31323 (15) | 0.0456 (5) | |
H5 | 0.580546 | 0.569943 | 0.302850 | 0.055* | |
C6 | 0.69736 (17) | 0.49012 (10) | 0.33480 (13) | 0.0369 (4) | |
H6 | 0.753509 | 0.524340 | 0.340292 | 0.044* | |
C7 | 0.82927 (16) | 0.38357 (10) | 0.37186 (12) | 0.0316 (4) | |
C8 | 0.92187 (17) | 0.43050 (11) | 0.43057 (14) | 0.0405 (5) | |
H8A | 0.967649 | 0.400021 | 0.480793 | 0.049* | |
H8B | 0.894927 | 0.474549 | 0.451068 | 0.049* | |
H8C | 0.963667 | 0.447671 | 0.398296 | 0.049* | |
C9 | 0.95825 (17) | 0.22217 (11) | 0.36603 (13) | 0.0367 (4) | |
C10 | 1.17362 (18) | 0.25061 (14) | 0.46973 (15) | 0.0509 (6) | |
H10A | 1.140263 | 0.275184 | 0.505639 | 0.061* | |
H10B | 1.240558 | 0.225943 | 0.510265 | 0.061* | |
C11 | 1.20302 (19) | 0.31163 (14) | 0.41984 (15) | 0.0513 (6) | |
H11A | 1.138161 | 0.341163 | 0.384373 | 0.062* | |
H11B | 1.230706 | 0.287810 | 0.379651 | 0.062* | |
C12 | 1.2880 (2) | 0.36459 (17) | 0.48235 (18) | 0.0684 (8) | |
H12A | 1.261218 | 0.385392 | 0.524572 | 0.082* | |
H12B | 1.353331 | 0.334666 | 0.515807 | 0.082* | |
C13 | 1.3188 (2) | 0.43029 (17) | 0.4382 (2) | 0.0740 (8) | |
H13A | 1.389438 | 0.450271 | 0.478590 | 0.089* | |
H13B | 1.326489 | 0.411161 | 0.385544 | 0.089* | |
C14 | 1.2390 (2) | 0.49362 (15) | 0.41222 (17) | 0.0594 (7) | |
H14A | 1.239582 | 0.517821 | 0.465697 | 0.071* | |
H14B | 1.166457 | 0.472263 | 0.379554 | 0.071* | |
C15 | 1.2602 (2) | 0.55481 (15) | 0.35546 (16) | 0.0587 (7) | |
H15A | 1.269751 | 0.529466 | 0.306412 | 0.070* | |
H15B | 1.195840 | 0.587481 | 0.330127 | 0.070* | |
C16 | 1.3558 (2) | 0.60421 (18) | 0.40216 (18) | 0.0683 (7) | |
H16A | 1.420947 | 0.572151 | 0.424799 | 0.082* | |
H16B | 1.348212 | 0.627938 | 0.452884 | 0.082* | |
C17 | 1.3710 (3) | 0.66657 (19) | 0.3449 (2) | 0.0846 (9) | |
H17A | 1.432010 | 0.698486 | 0.380235 | 0.102* | |
H17B | 1.305876 | 0.697621 | 0.320527 | 0.102* | |
H17C | 1.384727 | 0.643577 | 0.297226 | 0.102* | |
C18 | 0.79429 (16) | 0.40675 (10) | 0.17028 (12) | 0.0311 (4) | |
C19 | 0.86459 (16) | 0.34878 (11) | 0.17231 (12) | 0.0341 (4) | |
H19 | 0.838889 | 0.298260 | 0.159744 | 0.041* | |
C20 | 0.97162 (17) | 0.36419 (13) | 0.19250 (13) | 0.0414 (5) | |
H20 | 1.019032 | 0.324289 | 0.193909 | 0.050* | |
C21 | 1.00957 (18) | 0.43770 (14) | 0.21063 (14) | 0.0455 (5) | |
H21 | 1.082960 | 0.448151 | 0.224205 | 0.055* | |
C22 | 0.94112 (19) | 0.49591 (13) | 0.20904 (14) | 0.0457 (5) | |
H22 | 0.967704 | 0.546150 | 0.222558 | 0.055* | |
C23 | 0.83347 (17) | 0.48093 (11) | 0.18769 (13) | 0.0372 (4) | |
H23 | 0.786094 | 0.521277 | 0.184876 | 0.045* | |
C24 | 0.67924 (16) | 0.39092 (10) | 0.14602 (12) | 0.0309 (4) | |
C25 | 0.59705 (17) | 0.44680 (11) | 0.09090 (14) | 0.0386 (5) | |
H25A | 0.553452 | 0.423904 | 0.034202 | 0.046* | |
H25B | 0.633169 | 0.491993 | 0.082072 | 0.046* | |
H25C | 0.550715 | 0.461094 | 0.120355 | 0.046* | |
C26 | 0.52026 (17) | 0.24162 (11) | 0.13485 (13) | 0.0358 (4) | |
C27 | 0.31613 (18) | 0.29143 (12) | 0.02909 (14) | 0.0436 (5) | |
H27A | 0.358150 | 0.316283 | 0.000245 | 0.052* | |
H27B | 0.246964 | 0.275151 | −0.017279 | 0.052* | |
C28 | 0.29357 (18) | 0.34919 (12) | 0.08641 (14) | 0.0436 (5) | |
H28A | 0.245687 | 0.326397 | 0.111130 | 0.052* | |
H28B | 0.361711 | 0.363080 | 0.135586 | 0.052* | |
C29 | 0.24138 (18) | 0.41999 (12) | 0.03573 (14) | 0.0437 (5) | |
H29A | 0.290487 | 0.443173 | 0.012497 | 0.052* | |
H29B | 0.174836 | 0.405413 | −0.014688 | 0.052* | |
C30 | 0.2140 (2) | 0.47840 (13) | 0.08941 (15) | 0.0488 (5) | |
H30A | 0.170690 | 0.453715 | 0.117230 | 0.059* | |
H30B | 0.281430 | 0.496272 | 0.136649 | 0.059* | |
C31 | 0.15295 (19) | 0.54626 (12) | 0.03832 (15) | 0.0456 (5) | |
H31A | 0.197589 | 0.572328 | 0.012675 | 0.055* | |
H31B | 0.087024 | 0.528287 | −0.010493 | 0.055* | |
C32 | 0.1218 (2) | 0.60272 (13) | 0.09154 (15) | 0.0516 (6) | |
H32A | 0.083050 | 0.575616 | 0.121678 | 0.062* | |
H32B | 0.187996 | 0.624210 | 0.136973 | 0.062* | |
C33 | 0.0526 (2) | 0.66669 (14) | 0.03960 (17) | 0.0542 (6) | |
H33A | −0.013476 | 0.645405 | −0.006231 | 0.065* | |
H33B | 0.091524 | 0.694443 | 0.010095 | 0.065* | |
C34 | 0.0215 (2) | 0.72192 (17) | 0.0943 (2) | 0.0741 (8) | |
H34A | −0.018940 | 0.695217 | 0.122478 | 0.089* | |
H34B | −0.023206 | 0.762201 | 0.056803 | 0.089* | |
H34C | 0.086370 | 0.744135 | 0.139102 | 0.089* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ni1 | 0.04200 (15) | 0.01830 (12) | 0.03551 (14) | 0.00075 (10) | 0.01657 (11) | 0.00046 (9) |
S1 | 0.0548 (3) | 0.0224 (2) | 0.0521 (3) | 0.0068 (2) | 0.0213 (3) | 0.0038 (2) |
S2 | 0.0516 (4) | 0.0419 (3) | 0.0579 (4) | 0.0196 (3) | 0.0231 (3) | 0.0148 (3) |
S3 | 0.0504 (3) | 0.0206 (2) | 0.0551 (3) | −0.0034 (2) | 0.0186 (3) | −0.0014 (2) |
S4 | 0.0446 (3) | 0.0315 (3) | 0.0624 (4) | −0.0102 (2) | 0.0223 (3) | −0.0078 (2) |
N1 | 0.0366 (9) | 0.0239 (7) | 0.0340 (9) | 0.0022 (6) | 0.0156 (7) | 0.0030 (6) |
N2 | 0.0384 (9) | 0.0319 (9) | 0.0361 (9) | 0.0075 (7) | 0.0142 (7) | 0.0052 (7) |
N3 | 0.0372 (9) | 0.0213 (7) | 0.0337 (8) | −0.0018 (6) | 0.0164 (7) | −0.0028 (6) |
N4 | 0.0381 (9) | 0.0254 (8) | 0.0395 (9) | −0.0036 (7) | 0.0155 (7) | −0.0018 (6) |
C1 | 0.0429 (11) | 0.0253 (9) | 0.0295 (10) | 0.0009 (8) | 0.0187 (8) | −0.0022 (7) |
C2 | 0.0466 (12) | 0.0269 (9) | 0.0363 (11) | −0.0003 (8) | 0.0207 (9) | 0.0015 (8) |
C3 | 0.0435 (12) | 0.0420 (12) | 0.0464 (12) | −0.0015 (9) | 0.0235 (10) | 0.0030 (9) |
C4 | 0.0449 (13) | 0.0489 (13) | 0.0487 (13) | 0.0112 (10) | 0.0252 (10) | 0.0052 (10) |
C5 | 0.0617 (15) | 0.0316 (11) | 0.0521 (13) | 0.0112 (10) | 0.0318 (11) | 0.0041 (9) |
C6 | 0.0501 (12) | 0.0250 (9) | 0.0437 (12) | −0.0003 (8) | 0.0274 (10) | −0.0025 (8) |
C7 | 0.0400 (11) | 0.0256 (9) | 0.0318 (10) | −0.0012 (8) | 0.0174 (8) | 0.0012 (7) |
C8 | 0.0437 (12) | 0.0318 (10) | 0.0455 (12) | −0.0057 (9) | 0.0175 (10) | −0.0067 (9) |
C9 | 0.0453 (12) | 0.0318 (10) | 0.0353 (11) | 0.0084 (9) | 0.0189 (9) | 0.0084 (8) |
C10 | 0.0429 (13) | 0.0663 (16) | 0.0394 (12) | 0.0159 (11) | 0.0127 (10) | 0.0135 (11) |
C11 | 0.0460 (14) | 0.0620 (15) | 0.0448 (13) | 0.0089 (11) | 0.0173 (11) | 0.0091 (11) |
C12 | 0.0576 (17) | 0.0686 (19) | 0.0663 (17) | 0.0020 (14) | 0.0123 (14) | 0.0031 (14) |
C13 | 0.0522 (17) | 0.072 (2) | 0.093 (2) | 0.0032 (14) | 0.0239 (15) | 0.0015 (16) |
C14 | 0.0557 (16) | 0.0690 (18) | 0.0522 (15) | 0.0069 (13) | 0.0204 (12) | −0.0060 (12) |
C15 | 0.0654 (17) | 0.0623 (16) | 0.0492 (14) | 0.0117 (13) | 0.0242 (13) | −0.0067 (12) |
C16 | 0.0590 (17) | 0.083 (2) | 0.0584 (17) | 0.0056 (15) | 0.0191 (13) | −0.0046 (14) |
C17 | 0.078 (2) | 0.081 (2) | 0.095 (2) | −0.0064 (18) | 0.0353 (19) | −0.0062 (18) |
C18 | 0.0414 (11) | 0.0269 (9) | 0.0277 (9) | −0.0020 (8) | 0.0170 (8) | 0.0014 (7) |
C19 | 0.0444 (12) | 0.0314 (10) | 0.0276 (10) | 0.0006 (8) | 0.0159 (8) | 0.0001 (7) |
C20 | 0.0425 (12) | 0.0505 (13) | 0.0335 (11) | 0.0057 (10) | 0.0177 (9) | 0.0017 (9) |
C21 | 0.0420 (12) | 0.0617 (15) | 0.0364 (12) | −0.0125 (11) | 0.0196 (10) | −0.0019 (10) |
C22 | 0.0565 (14) | 0.0423 (12) | 0.0443 (13) | −0.0175 (10) | 0.0268 (11) | −0.0056 (9) |
C23 | 0.0487 (12) | 0.0283 (10) | 0.0413 (11) | −0.0049 (9) | 0.0252 (10) | −0.0011 (8) |
C24 | 0.0405 (11) | 0.0219 (9) | 0.0324 (10) | −0.0012 (8) | 0.0168 (8) | −0.0029 (7) |
C25 | 0.0452 (12) | 0.0241 (9) | 0.0453 (12) | 0.0017 (8) | 0.0172 (10) | 0.0036 (8) |
C26 | 0.0444 (12) | 0.0273 (10) | 0.0397 (11) | −0.0045 (8) | 0.0213 (9) | −0.0047 (8) |
C27 | 0.0408 (12) | 0.0426 (12) | 0.0443 (12) | −0.0029 (10) | 0.0140 (10) | −0.0072 (9) |
C28 | 0.0453 (13) | 0.0436 (12) | 0.0464 (13) | 0.0002 (10) | 0.0231 (10) | −0.0001 (9) |
C29 | 0.0476 (13) | 0.0458 (13) | 0.0416 (12) | 0.0006 (10) | 0.0222 (10) | 0.0012 (9) |
C30 | 0.0579 (15) | 0.0465 (13) | 0.0435 (13) | 0.0084 (11) | 0.0221 (11) | 0.0030 (10) |
C31 | 0.0491 (13) | 0.0419 (12) | 0.0484 (13) | 0.0033 (10) | 0.0224 (11) | −0.0014 (10) |
C32 | 0.0588 (15) | 0.0465 (13) | 0.0504 (14) | 0.0055 (11) | 0.0231 (11) | −0.0037 (10) |
C33 | 0.0506 (15) | 0.0472 (14) | 0.0673 (16) | 0.0037 (11) | 0.0267 (12) | −0.0052 (11) |
C34 | 0.072 (2) | 0.0666 (18) | 0.084 (2) | 0.0144 (15) | 0.0318 (16) | −0.0169 (16) |
Geometric parameters (Å, º) top
Ni1—N3 | 1.9318 (15) | C15—H15A | 0.9900 |
Ni1—N1 | 1.9392 (16) | C15—H15B | 0.9900 |
Ni1—S1 | 2.1506 (6) | C16—C17 | 1.529 (4) |
Ni1—S3 | 2.1573 (6) | C16—H16A | 0.9900 |
S1—C9 | 1.738 (2) | C16—H16B | 0.9900 |
S2—C9 | 1.746 (2) | C17—H17A | 0.9800 |
S2—C10 | 1.809 (3) | C17—H17B | 0.9800 |
S3—C26 | 1.738 (2) | C17—H17C | 0.9800 |
S4—C26 | 1.749 (2) | C18—C19 | 1.393 (3) |
S4—C27 | 1.809 (2) | C18—C23 | 1.400 (3) |
N1—C7 | 1.303 (2) | C18—C24 | 1.479 (3) |
N1—N2 | 1.414 (2) | C19—C20 | 1.385 (3) |
N2—C9 | 1.293 (3) | C19—H19 | 0.9500 |
N3—C24 | 1.302 (2) | C20—C21 | 1.384 (3) |
N3—N4 | 1.417 (2) | C20—H20 | 0.9500 |
N4—C26 | 1.290 (2) | C21—C22 | 1.381 (3) |
C1—C2 | 1.396 (3) | C21—H21 | 0.9500 |
C1—C6 | 1.403 (3) | C22—C23 | 1.388 (3) |
C1—C7 | 1.476 (3) | C22—H22 | 0.9500 |
C2—C3 | 1.386 (3) | C23—H23 | 0.9500 |
C2—H2 | 0.9500 | C24—C25 | 1.497 (3) |
C3—C4 | 1.377 (3) | C25—H25A | 0.9800 |
C3—H3 | 0.9500 | C25—H25B | 0.9800 |
C4—C5 | 1.383 (3) | C25—H25C | 0.9800 |
C4—H4 | 0.9500 | C27—C28 | 1.516 (3) |
C5—C6 | 1.380 (3) | C27—H27A | 0.9900 |
C5—H5 | 0.9500 | C27—H27B | 0.9900 |
C6—H6 | 0.9500 | C28—C29 | 1.516 (3) |
C7—C8 | 1.496 (3) | C28—H28A | 0.9900 |
C8—H8A | 0.9800 | C28—H28B | 0.9900 |
C8—H8B | 0.9800 | C29—C30 | 1.512 (3) |
C8—H8C | 0.9800 | C29—H29A | 0.9900 |
C10—C11 | 1.514 (3) | C29—H29B | 0.9900 |
C10—H10A | 0.9900 | C30—C31 | 1.510 (3) |
C10—H10B | 0.9900 | C30—H30A | 0.9900 |
C11—C12 | 1.526 (4) | C30—H30B | 0.9900 |
C11—H11A | 0.9900 | C31—C32 | 1.509 (3) |
C11—H11B | 0.9900 | C31—H31A | 0.9900 |
C12—C13 | 1.523 (4) | C31—H31B | 0.9900 |
C12—H12A | 0.9900 | C32—C33 | 1.502 (3) |
C12—H12B | 0.9900 | C32—H32A | 0.9900 |
C13—C14 | 1.496 (4) | C32—H32B | 0.9900 |
C13—H13A | 0.9900 | C33—C34 | 1.513 (3) |
C13—H13B | 0.9900 | C33—H33A | 0.9900 |
C14—C15 | 1.542 (4) | C33—H33B | 0.9900 |
C14—H14A | 0.9900 | C34—H34A | 0.9800 |
C14—H14B | 0.9900 | C34—H34B | 0.9800 |
C15—C16 | 1.498 (4) | C34—H34C | 0.9800 |
| | | |
N3—Ni1—N1 | 101.11 (7) | C15—C16—H16B | 108.8 |
N3—Ni1—S1 | 163.41 (5) | C17—C16—H16B | 108.8 |
N1—Ni1—S1 | 86.26 (5) | H16A—C16—H16B | 107.7 |
N3—Ni1—S3 | 86.40 (5) | C16—C17—H17A | 109.5 |
N1—Ni1—S3 | 164.97 (5) | C16—C17—H17B | 109.5 |
S1—Ni1—S3 | 90.02 (2) | H17A—C17—H17B | 109.5 |
C9—S1—Ni1 | 93.66 (7) | C16—C17—H17C | 109.5 |
C9—S2—C10 | 103.05 (10) | H17A—C17—H17C | 109.5 |
C26—S3—Ni1 | 93.75 (7) | H17B—C17—H17C | 109.5 |
C26—S4—C27 | 102.03 (10) | C19—C18—C23 | 118.78 (18) |
C7—N1—N2 | 113.29 (16) | C19—C18—C24 | 120.72 (17) |
C7—N1—Ni1 | 130.19 (14) | C23—C18—C24 | 120.44 (17) |
N2—N1—Ni1 | 116.46 (11) | C20—C19—C18 | 120.55 (19) |
C9—N2—N1 | 111.31 (16) | C20—C19—H19 | 119.7 |
C24—N3—N4 | 113.59 (15) | C18—C19—H19 | 119.7 |
C24—N3—Ni1 | 129.67 (14) | C21—C20—C19 | 120.0 (2) |
N4—N3—Ni1 | 116.71 (11) | C21—C20—H20 | 120.0 |
C26—N4—N3 | 111.30 (16) | C19—C20—H20 | 120.0 |
C2—C1—C6 | 118.27 (18) | C22—C21—C20 | 120.2 (2) |
C2—C1—C7 | 121.16 (16) | C22—C21—H21 | 119.9 |
C6—C1—C7 | 120.55 (18) | C20—C21—H21 | 119.9 |
C3—C2—C1 | 120.55 (18) | C21—C22—C23 | 119.9 (2) |
C3—C2—H2 | 119.7 | C21—C22—H22 | 120.0 |
C1—C2—H2 | 119.7 | C23—C22—H22 | 120.0 |
C4—C3—C2 | 120.3 (2) | C22—C23—C18 | 120.4 (2) |
C4—C3—H3 | 119.9 | C22—C23—H23 | 119.8 |
C2—C3—H3 | 119.9 | C18—C23—H23 | 119.8 |
C3—C4—C5 | 120.1 (2) | N3—C24—C18 | 118.85 (17) |
C3—C4—H4 | 119.9 | N3—C24—C25 | 121.78 (18) |
C5—C4—H4 | 119.9 | C18—C24—C25 | 119.33 (16) |
C6—C5—C4 | 120.1 (2) | C24—C25—H25A | 109.5 |
C6—C5—H5 | 120.0 | C24—C25—H25B | 109.5 |
C4—C5—H5 | 120.0 | H25A—C25—H25B | 109.5 |
C5—C6—C1 | 120.72 (19) | C24—C25—H25C | 109.5 |
C5—C6—H6 | 119.6 | H25A—C25—H25C | 109.5 |
C1—C6—H6 | 119.6 | H25B—C25—H25C | 109.5 |
N1—C7—C1 | 119.58 (17) | N4—C26—S3 | 124.99 (16) |
N1—C7—C8 | 121.99 (18) | N4—C26—S4 | 120.22 (16) |
C1—C7—C8 | 118.42 (16) | S3—C26—S4 | 114.79 (11) |
C7—C8—H8A | 109.5 | C28—C27—S4 | 114.80 (15) |
C7—C8—H8B | 109.5 | C28—C27—H27A | 108.6 |
H8A—C8—H8B | 109.5 | S4—C27—H27A | 108.6 |
C7—C8—H8C | 109.5 | C28—C27—H27B | 108.6 |
H8A—C8—H8C | 109.5 | S4—C27—H27B | 108.6 |
H8B—C8—H8C | 109.5 | H27A—C27—H27B | 107.5 |
N2—C9—S1 | 124.81 (16) | C29—C28—C27 | 111.69 (18) |
N2—C9—S2 | 120.52 (16) | C29—C28—H28A | 109.3 |
S1—C9—S2 | 114.67 (11) | C27—C28—H28A | 109.3 |
C11—C10—S2 | 115.86 (17) | C29—C28—H28B | 109.3 |
C11—C10—H10A | 108.3 | C27—C28—H28B | 109.3 |
S2—C10—H10A | 108.3 | H28A—C28—H28B | 107.9 |
C11—C10—H10B | 108.3 | C30—C29—C28 | 113.72 (18) |
S2—C10—H10B | 108.3 | C30—C29—H29A | 108.8 |
H10A—C10—H10B | 107.4 | C28—C29—H29A | 108.8 |
C10—C11—C12 | 110.8 (2) | C30—C29—H29B | 108.8 |
C10—C11—H11A | 109.5 | C28—C29—H29B | 108.8 |
C12—C11—H11A | 109.5 | H29A—C29—H29B | 107.7 |
C10—C11—H11B | 109.5 | C31—C30—C29 | 114.60 (18) |
C12—C11—H11B | 109.5 | C31—C30—H30A | 108.6 |
H11A—C11—H11B | 108.1 | C29—C30—H30A | 108.6 |
C13—C12—C11 | 114.6 (2) | C31—C30—H30B | 108.6 |
C13—C12—H12A | 108.6 | C29—C30—H30B | 108.6 |
C11—C12—H12A | 108.6 | H30A—C30—H30B | 107.6 |
C13—C12—H12B | 108.6 | C32—C31—C30 | 114.30 (19) |
C11—C12—H12B | 108.6 | C32—C31—H31A | 108.7 |
H12A—C12—H12B | 107.6 | C30—C31—H31A | 108.7 |
C14—C13—C12 | 113.5 (2) | C32—C31—H31B | 108.7 |
C14—C13—H13A | 108.9 | C30—C31—H31B | 108.7 |
C12—C13—H13A | 108.9 | H31A—C31—H31B | 107.6 |
C14—C13—H13B | 108.9 | C33—C32—C31 | 114.56 (19) |
C12—C13—H13B | 108.9 | C33—C32—H32A | 108.6 |
H13A—C13—H13B | 107.7 | C31—C32—H32A | 108.6 |
C13—C14—C15 | 114.0 (2) | C33—C32—H32B | 108.6 |
C13—C14—H14A | 108.8 | C31—C32—H32B | 108.6 |
C15—C14—H14A | 108.8 | H32A—C32—H32B | 107.6 |
C13—C14—H14B | 108.8 | C32—C33—C34 | 113.5 (2) |
C15—C14—H14B | 108.8 | C32—C33—H33A | 108.9 |
H14A—C14—H14B | 107.7 | C34—C33—H33A | 108.9 |
C16—C15—C14 | 115.3 (2) | C32—C33—H33B | 108.9 |
C16—C15—H15A | 108.5 | C34—C33—H33B | 108.9 |
C14—C15—H15A | 108.5 | H33A—C33—H33B | 107.7 |
C16—C15—H15B | 108.5 | C33—C34—H34A | 109.5 |
C14—C15—H15B | 108.5 | C33—C34—H34B | 109.5 |
H15A—C15—H15B | 107.5 | H34A—C34—H34B | 109.5 |
C15—C16—C17 | 113.7 (2) | C33—C34—H34C | 109.5 |
C15—C16—H16A | 108.8 | H34A—C34—H34C | 109.5 |
C17—C16—H16A | 108.8 | H34B—C34—H34C | 109.5 |
| | | |
C7—N1—N2—C9 | 161.19 (16) | C13—C14—C15—C16 | −71.2 (3) |
Ni1—N1—N2—C9 | −21.57 (19) | C14—C15—C16—C17 | −177.2 (2) |
C24—N3—N4—C26 | 159.67 (17) | C23—C18—C19—C20 | 1.0 (3) |
Ni1—N3—N4—C26 | −22.02 (19) | C24—C18—C19—C20 | 178.05 (17) |
C6—C1—C2—C3 | 1.3 (3) | C18—C19—C20—C21 | −0.2 (3) |
C7—C1—C2—C3 | 179.60 (18) | C19—C20—C21—C22 | 0.3 (3) |
C1—C2—C3—C4 | −0.6 (3) | C20—C21—C22—C23 | −1.1 (3) |
C2—C3—C4—C5 | 0.1 (3) | C21—C22—C23—C18 | 1.9 (3) |
C3—C4—C5—C6 | −0.4 (3) | C19—C18—C23—C22 | −1.8 (3) |
C4—C5—C6—C1 | 1.2 (3) | C24—C18—C23—C22 | −178.93 (18) |
C2—C1—C6—C5 | −1.7 (3) | N4—N3—C24—C18 | −169.77 (15) |
C7—C1—C6—C5 | −179.93 (18) | Ni1—N3—C24—C18 | 12.2 (3) |
N2—N1—C7—C1 | −173.58 (15) | N4—N3—C24—C25 | 7.7 (2) |
Ni1—N1—C7—C1 | 9.7 (3) | Ni1—N3—C24—C25 | −170.32 (13) |
N2—N1—C7—C8 | 5.9 (2) | C19—C18—C24—N3 | 36.4 (3) |
Ni1—N1—C7—C8 | −170.90 (14) | C23—C18—C24—N3 | −146.61 (18) |
C2—C1—C7—N1 | 38.0 (3) | C19—C18—C24—C25 | −141.20 (18) |
C6—C1—C7—N1 | −143.77 (19) | C23—C18—C24—C25 | 35.8 (3) |
C2—C1—C7—C8 | −141.45 (19) | N3—N4—C26—S3 | 2.3 (2) |
C6—C1—C7—C8 | 36.8 (3) | N3—N4—C26—S4 | −176.86 (13) |
N1—N2—C9—S1 | 0.3 (2) | Ni1—S3—C26—N4 | 14.51 (18) |
N1—N2—C9—S2 | −179.64 (13) | Ni1—S3—C26—S4 | −166.32 (10) |
Ni1—S1—C9—N2 | 16.87 (17) | C27—S4—C26—N4 | 7.20 (19) |
Ni1—S1—C9—S2 | −163.16 (10) | C27—S4—C26—S3 | −172.01 (11) |
C10—S2—C9—N2 | 10.39 (19) | C26—S4—C27—C28 | −78.59 (18) |
C10—S2—C9—S1 | −169.58 (11) | S4—C27—C28—C29 | 175.22 (15) |
C9—S2—C10—C11 | −78.20 (19) | C27—C28—C29—C30 | 178.15 (19) |
S2—C10—C11—C12 | −174.06 (18) | C28—C29—C30—C31 | −174.7 (2) |
C10—C11—C12—C13 | −177.1 (2) | C29—C30—C31—C32 | 177.5 (2) |
C11—C12—C13—C14 | 78.4 (3) | C30—C31—C32—C33 | −174.7 (2) |
C12—C13—C14—C15 | −171.3 (2) | C31—C32—C33—C34 | 179.3 (2) |