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Figure 5
Sampling-XANES spectra of the Mn complex at room temperature before (solid circles) and after (open circles) the first laser flash (predominant population of the S1 and S2 states, respectively). Spectra were obtained from time-scan traces (averaging of 5–9 scans at each energy point) according to equation (1)[link] in the text. The points represent the fluorescence intensities averaged over approximately 400 ms before and after flash illumination (F0 and F1 levels in Fig. 2-ii[link]). XANES spectra have been slightly smoothed by adjacent averaging over two data points for better comparison. The line represents the rapid-scan S1-state reference spectrum. Inset: one-flash minus zero-flash difference spectrum.

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
Volume 12| Part 1| December 2005| Pages 35-44
doi:10.1107/S0909049504027803
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