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Figure 6
Inset: room-temperature EXAFS oscillations (experimental data, dots) obtained by the sampling-XAS approach of the Mn complex predominantly in states S1 (no flash, 0F), S2 (one flash, 1F) and S3 (two flashes, 2F). Spectra have been obtained from time scans in the EXAFS region by averaging the fluorescence intensity over 200 ms before and after the laser flashes (flash spacing 200 ms). Lines have been drawn to guide the eye. The main picture shows the respective FTs (solid line, 0F; white triangles, 1F; black triangles, 2F). FTs have been calculated from EXAFS oscillations ranging over 10–350 eV above E0 (6547 eV) and using cosine windows extending over 10 and 25% at the low-k and high-k side, respectively, of the k3-weighted data.

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SYNCHROTRON
RADIATION
ISSN: 1600-5775
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