view article
Figure 4
Electron density maps contoured at 1σ from crystal structures (a) MX1, (b) MX2 and (c) MX3. The copper atom is shown as an orange sphere. Note that a water molecule is coordinated to the T2Cu centre in all cases, along with three histidine ligands. The four-coordinate geometry and clear density for the Cu-coordinated water molecule (shown as a red sphere) clearly indicate that this centre is in the oxidized Cu(II) form, consistent with the XAS data.

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
Volume 15| Part 5| July 2008| Pages 433-439
doi:10.1107/S0909049508014945
Follow J. Synchrotron Rad.
Sign up for e-alerts
E-alerts
Follow J. Synchrotron Rad. on Twitter
Twitter
Follow us on facebook
Facebook
Sign up for RSS feeds
RSS