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Figure 3
Molecular structure of PtPOP and relevant angles. PtPOP is a symmetric top molecule with the main axis of symmetry parallel to the Pt–Pt axis (Zipp, 1988BB50; Gray et al., 2017BB19). In the molecular fixed frame (black arrows): [\xi_{ij}] is the angle between the internuclear displacement [{\bf{r}}_{ij}] and the transition dipole moment [\boldmu] of the molecule, which is parallel to the main axis of symmetry of the molecule. In the laboratory frame (blue arrows): α is the angle between the laser polarization axis E and the transition dipole vector [\boldmu] of the molecule, [\theta_{Q}] is the angle between the laser polarization axis and the scattering vector.

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
Volume 25| Part 2| March 2018| Pages 306-315
https://doi.org/10.1107/S1600577517016964
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