Figure 5
(Left) The k3-weighted Rh K-edge EXAFS spectra, and (right) the corresponding Fourier transforms of: Rh2(AcO)4 solid (1) and its solution in ethanethiol, [Rh2(AcO)4(EtSH)2] (7), [Rh2(AcO)4(DHLA)]n solid (8), reaction products of Rh2(AcO)4 with excess of the sodium thiolates NaEtS (9) and Na3(DTLA) (10), and concentrated solution of RhIII–GSH product (2) with three bridging thiolato groups between the Rh(III) ions (Enriquez Garcia & Jalilehvand, 2018); see below. The curve fitting results are presented in Table 1. |