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Figure 8
Comparative fits to the S K-edge XANES spectra of [Ni(TU)6]2+ with pseudo-Voigt lines for the S 1s → C–S π*, C–S σ*, S 4p transitions and an edge-jump for the S 1s ionization, when the ratio of C–S π* to C–S σ* intensity was fixed at (a) 0.4, (b) 0.3 and (c) 0.2.

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