Figure 5
The normalized excited-state difference spectra of iron polypyridyl compounds. The red line shows Fe(bpy)3Cl2 on PVC, time-averaged between 1.0 and 2.0 ps. The blue line shows FeII(bpy)3(PF6)2 in PS, time-averaged between 1.0 and 2.0 ps. The black line gives the spectral component of the global fit to FeII(phen)3(SCN)2 data corresponding to the 5T2g state. |