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Figure 6
Definition of parameters defining the structural distortions of the MIL-53 structure: (a) hinge angle of carboxylate link to inorganic chain (α), (b) carboxylate O—C—C—C dihedral angle (β), (c) intrachain M—O—M angle (γ) and (d) dimensions of the projection of the diamond-shaped channels. Crystal data were taken from the structure of Co(BDC)(3-Br-PNO): cyan atoms are Co, red O, large grey C and small grey H.

ISSN: 2052-5206
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