A new polymorph of poly[bis­(μ2-per­chlorato-κ2O:O′)(2,2′:6′,2′′-terpyri­dine-κ3N,N′,N′′)lead(II)] with a greatly extended chain repeat distance

Blake, A.J.; Caltagirone, C.; Lippolis, V.; Shamsipur, M.

doi:10.1107/S0108270108042236

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 3
(a) A view, approximately along the b axis, showing chains of molecules running along the [201] direction. The atoms shown as spheres in the central chain are Pb3 and two of its symmetry equivalents. The shortest Pb3⋯Pb3 separation along the chain is 26.280 (4) Å and represents the fundamental repeat distance. (b) An orthogonal view, showing the alternation of hydrophilic (perchlorate) and hydrophobic (terpy) regions along the b axis.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 65| Part 1| December 2009| Pages m33-m36

doi:10.1107/S0108270108042236

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