Figure 3
(a) A packing diagram of (I) along the a axis, indicating the columns of dimers. (b) A packing diagram of (II) along the a axis, indicating the stacks of molecules. (c)/(d) Projections of the crystal packing of (I) and (II), respectively, on the C2/C8/C14 plane of the basic molecule, demonstrating the differences in the mutual orientations of neighbouring molecules. Dashed lines in (c) indicate hydrogen bonds. H atoms (except for the amino H atoms) have been omitted for clarity. |