view article

Figure 4
An illustration of the inter­porphyrin ZnTPyP coordination pattern of trigonal symmetry observed in the three-dimensional supra­molecular isomer of type (II), which was reported previously (Krupitsky et al., 1994BB10; George & Goldberg, 2005BB8); the projection of the crystal structure of the acetic acid clathrate is down the c axis (acetic acid mol­ecules and H atoms have been omitted). The C3 axes are marked by solid triangles. Labelling of the mol­ecules as A, B, C and D is related to the discussion of the supra­molecular isomorphism in the Comment[link]. The continuity of the shown framework in three dimensions is symbolized by the additional terminal ZnII ions coordinated to the pyridyl group and the N-atom sites of neighbouring species coordinated to the zinc centres. Note the roughly perpendicular mutual orientation of porphyrin cores B and C.

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296
Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds