A monoclinic pseudopolymorph of manganese squarate dihydrate, Mn(μ-C4O4)(H2O)2, built from cubic units

Gavilan, E.; Audebrand, N.

doi:10.1107/S0108270109004442

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 1
A view of the crystal structure of the title compound, showing the Mn coordination and the tetra-monodentate connection mode of the squarate anions. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) −x − $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z; (ii) −x, y, −z + $[{1\over 2}]$ ; (iii) x − $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (iv) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z; (vi) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vii) −x, −y, −z; (ix) x − $[{1\over 2}]$ , y − $[{1\over 2}]$ , z; (x) x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , z; (xi) x, −y, z − $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 65| Part 4| March 2009| Pages m156-m159

doi:10.1107/S0108270109004442

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