A bis­(amine–carboxyl­ate) copper(II) coordination compound forms a two-dimensional metal–organic framework when crystallized from water and methanol

Munro, O.Q.; Akerman, M.P.; Gillham, K.

doi:10.1107/S010827010903128X

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
Ball-and-cylinder representation of the C_i-symmetry dimer that forms the repeat unit of the two-dimensional coordination polymer, or MOF structure, in water/methanol solvate (II)

. Bonds to atoms that lead to extension of the two-dimensional array are shown as dotted lines. H atoms (except those attached to N atoms) and solvent molecules have been omitted for clarity. [Symmetry codes: (i) 1 − x, 1 − y, −z; (ii) $[{3\over 2}]$ − x, $[{1\over 2}]$ + y, $[{1\over 2}]$ − z; (iii) − $[{1\over 2}]$ + x, $[{1\over 2}]$ − y, − $[{1\over 2}]$ + z; (iv) $[{3\over 2}]$ − x, − $[{1\over 2}]$ + y, $[{1\over 2}]$ − z; (v) − $[{1\over 2}]$ + x, $[{3\over 2}]$ − y, − $[{1\over 2}]$ + z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 65| Part 9| August 2009| Pages m343-m346

doi:10.1107/S010827010903128X

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