Figure 1
The unique [Mn(C5O5)(2,2′-bipy)(H2O)]·H2O unit of (I) at 135 K, together with another `molecule' to show the π–π interactions and hydrogen bonds (dashed lines). Displacement ellipsoids are drawn at the 30% probability level and H atoms are shown as small spheres of arbitrary radii. [Symmetry codes: (i) x, −y + , z + ; (v) −x + 2, −y, −z + 2.] |