A three-dimensional heterometallic CuI/VIV 1,2-bis­(1,2,4-triazol-4-yl)ethane framework: a new insight into the structure of vanadium oxyfluoride coordination hybrids

Sharga, O.V.; Lysenko, A.B.; Krautscheid, H.; Domasevitch, K.V.

doi:10.1107/S0108270110034323

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 1
The molecular structure of (I)

, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability level and H atoms are shown as small spheres of arbitrary radii. Note the unprecedented triazole bridge between the Cu^I and V^iv ions. [Symmetry codes: (i) $[{3\over 2}]$ + x, $[{1\over 2}]$ − y, $[{1\over 2}]$ + z; (ii) $[{1\over 2}]$ − x, $[{1\over 2}]$ + y, $[{1\over 2}]$ − z; (iii) 2 − x, 1 − y, −z; (iv) 2 − x, 1 − y, 1 − z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 66| Part 9| August 2010| Pages m269-m272

doi:10.1107/S0108270110034323

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