Figure 4
A view of the centrosymmetric hydrogen-bonded pentamer containing one [Cu(PTA)2(H2O)2]2+ dication (green in the electronic version of the paper), two PTA molecules (red) and two nitrate anions (blue); the two other nitrate anions in the top right and bottom left of the figure, which co-operate in two weak N5—H5N⋯O4ii and N5—H5N⋯O6ii hydrogen bonds, assemble neighboring pentamers in a two-dimensional array. Hydrogen bonds are shown as thin dotted lines. [Symmetry codes: (i) −x + 1, −y + 1, −z + 1; (ii) x − , −y + , z − .] |