Figure 6
The intermolecular N1—H1⋯N2 hydrogen bonds in (III) (dotted lines), forming chains of equivalent molecules aligned exactly with the ac diagonal of the unit cell, resulting in a twofold helix along the [101] direction. Compound (IV) is isomorphous with (III). Ellipsoids are shown at the 30% probability level. [Symmetry codes: (i) x − , −y + , z − ; (iii) x + , −y + , z + ; (iv) x + 1, y, z + 1.] |