Figure 2
The disentangled frameworks formed by the two unique ligands L1 and L2. (a) A view of the two-dimensional Ca–L2 coordination framework, together with the folding N—H⋯O hydrogen bonds. The stabilizing O—H⋯O hydrogen bonds have been omitted for clarity. (b) A view of four Ca–L1 helical chains interconnected via N—H⋯O and O—H⋯O hydrogen bonds, drawn as dashed lines (in the electronic version of the paper, blue for N—H⋯O and red for O—H⋯O). The pyridine (C)H atoms have been omitted for clarity. |