Cadmium(II) chloride, bromide and iodide complexes with 4,4′-bipyrid­azine: when are diazine and halide bridges (in)compatible?

Domasevitch, K.V.; Rusanova, J.A.; Gural'skiy, I.A.; Solntsev, P.V.

doi:10.1107/S0108270112038048

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

IUCr IT WDC

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Figure 3
A projection of the structure of (I)

on the ab plane, showing the packing mode for the successive coordination layers with a set of weak C—H⋯N and C—H⋯Cl hydrogen bonds. The inorganic [Cd(μ-Cl)₂]_n chains are orthogonal to the plane of the figure. [Symmetry codes: (i) −x + 1, y, −z + $[{1\over 2}]$ ; (iii) −x + 1, −y + 1, z + $[{1\over 2}]$ ; (vi) −x + $[{3\over 2}]$ , y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vii) −x + $[{3\over 2}]$ , −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 68| Part 11| October 2012| Pages m295-m299

doi:10.1107/S0108270112038048

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