Cadmium(II) chloride, bromide and iodide complexes with 4,4′-bipyrid­azine: when are diazine and halide bridges (in)compatible?

Domasevitch, K.V.; Rusanova, J.A.; Gural'skiy, I.A.; Solntsev, P.V.

doi:10.1107/S0108270112038048

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 5
A projection of the structure of (III)

on the bc plane, showing the accommodation of the tetradentate organic ligands at the [Cd(μ-I)₂]_n chains with generation of corrugated layers. H atoms have been omitted for clarity. [Symmetry codes: (i) x, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (ii) x, −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 68| Part 11| October 2012| Pages m295-m299

doi:10.1107/S0108270112038048

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