Carbon­yl–carbonyl and carbon­yl–π inter­actions as directing motifs in the supra­molecular structure of carbon­yl(3-oxopenta-1,4-diene-1,5-di­yl)[tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN2)methane]­iridium(III) trifluoro­methane­sulfonate

Hernández-Juárez, M.; Salazar-Pereda, V.; Padilla-Martínez, I.I.; García-Báez, E.V.

doi:10.1107/S010827011204499X

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
Carbonyl C4=O4⋯Cg interactions (Cg1 and Cg2 are the centroids of the N13/N/14/C16–C18 and N15/N16/C21–C23 rings, respectively) and quinonoid carbonyl–metallic carbonyl C4=O4⋯C1ⁱ interactions forming C(6) chains along the c axis. Interactions are indicated by dotted lines. [Symmetry code: (i) x, −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ ; (ii) x, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 68| Part 12| December 2012| Pages m367-m369

doi:10.1107/S010827011204499X

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