Two solvatomorphic forms of a copper complex formulated as Cu(L1)(ClO4)2·1.2H2O and Cu(L1)(ClO4)2, where L1 is 3,10-C-meso-3,5,7,7,10,12,14,14-octa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane

Nath, B.C.; Suarez, S.; Doctorovich, F.; Roy, T.G.; Baggio, R.

doi:10.1107/S0108270113013711

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 4
Schematic superposition of (I)

(full lines) and (II)

(broken lines), where only the CuN₄ cores were included in a least-squares match. Note the almost perfect fit displayed by the L ligands and the (rotational) misfit in the pendant perchlorate anions. [Symmetry code: (i) −x + 1, −y + 1, −z + 1.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 69| Part 7| June 2013| Pages 689-695

doi:10.1107/S0108270113013711

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