A three-dimensional chiral crystal structure constructed from a chiral triazolate ligand showing an SrSi2 topology: poly[bis­(μ3-3,5-diethyl-1,2,4-triazolato-κ3N1:N2:N4)tris­ilver nitrate]

Jiang, F.; Dai, L.; Shi, Y.; Wang, Z.

doi:10.1107/S0108270113029788

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
(a) A view of the structure of (I)

along the [110] direction, showing the three-dimensional framework. H atoms and ethyl groups have been omitted for clarity. (b) A view of the one-dimensional chain linked by Ag1—N bonds, with only the triazolate groups shown for simplicity. (c) The trinuclear silver motif with the nitrate anion. [Symmetry codes: (iii) −y + $[{1\over 2}]$ , x − $[{1\over 2}]$ , z − $[{1\over 4}]$ ; (iv) x − $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z + $[{1\over 4}]$ ; (v) −y, −x, −z + $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 69| Part 12| November 2013| Pages 1485-1487

doi:10.1107/S0108270113029788

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