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Figure 6
Front and back views of the Hirshfeld surfaces for the components of structure (II)[link]. The interactions corresponding to the labels in figures are as follows, with the labels in parentheses: (a) phospho­rothioic tri­amide mol­ecule [the asymmetric unit of (II)[link] is shown with the phosphorothioic triamide molecule as the Hirshfeld surface map]: N1—H1n1⋯Cl1 (1), N3—H1n3⋯Cl1 (2), N2—H1n2⋯Cl1 (3), N4—H2n4⋯S1 (4), S1⋯S1 (5), N4—H2n4⋯S1 (6), C22—H2c22⋯C13 (7), C22—H2c22⋯C12 (8), C22—H2c22⋯C8 (9), C26—H1c26⋯C15 (10), C26—H1c26⋯C20 (11), C26—H1c26⋯C16 (12), C19—H1c19⋯C27 (13), C23—H2c23⋯C2 (14) and C7—H2c7a⋯C11 (15); (b) 3-methyl­piperidinium cation: C22—H2c22⋯C13 (7), C22—H2c22⋯C12 (8), C22—H2c22⋯C8 (9), C26—H1c26⋯C15 (10), C26—H1c26⋯C20 (11), C26—H1c26⋯C16 (12) and N4—H1n4⋯Cl1 (16); (c) chloride anion: N1—H1n1⋯Cl1 (1), N3—H1n3⋯Cl1 (2), N2—H1n2⋯Cl1 (3) and N4—H1n4⋯C1l (16).

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ISSN: 2053-2296
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