Four supra­molecular isomers of di­chlorido­bis­(1,10-phenanthroline)cobalt(II): synthesis, structure characterization and isomerization

Chen, X.; Han, S.; Wang, R.; Li, Y.

doi:10.1107/S2053229615022779

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 6
The supramolecular structure of (IIB), showing (a) the layer parallel to the ab plane and (b) the interactions between two neighbouring layers (blue and pink) viewed parallel to the c axis, with the DMF molecules shown in space-filling style. Green dashed lines represent C—H⋯Cl hydrogen bonds and dark dashed lines represent π–π stacking. All H atoms, except those involved in hydrogen-bonding interactions, have been omitted for clarity. [Symmetry codes: (i) −x + 1, −y + 1, −z; (ii) −x + 2, −y + 1, −z; (iii) −x + 2, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (iv) x, −y + $[{3\over 2}]$ , z + $[{1\over 2}]$ ; (v) −x + 1, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vi) x, −y + $[{3\over 2}]$ , z − $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 72| Part 1| January 2016| Pages 6-13

doi:10.1107/S2053229615022779

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