The title compound, [Cu(C
7H
4O
5S)(C
12H
8N
2)(H
2O)]
n, a polymeric copper(II) complex, was obtained by the reaction of Cu(NO
3)
2 with potassium hydrogen 4-sulfobenzoate and 1,10-phenanthroline under hydrothermal condition. Each Cu
II atom displays a square-pyramidal geometry defined by three O atoms from one water molecule and two 4-sulfonatobenzoate ligands and two N atoms from one 1,10-phenanthroline ligand. The polymeric chains are linked into ladders by O—H
O hydrogen bonds.
Supporting information
CCDC reference: 259083
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.004 Å
- R factor = 0.027
- wR factor = 0.075
- Data-to-parameter ratio = 11.4
checkCIF/PLATON results
No syntax errors found
No errors found in this datablock
Data collection: SMART (Bruker,1997); cell refinement: SMART; data reduction: SAINT and SHELXTL (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).
Poly[[aqua(1,10-phenanthroline-
κ2N,
N')copper(II)]-µ-4-sulfonatobenzoato-
κ2O4:
O1]
top
Crystal data top
[Cu(C7H4O5S)(C12H8N2)(H2O)] | Z = 2 |
Mr = 461.92 | F(000) = 470 |
Triclinic, P1 | Dx = 1.784 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 9.6864 (13) Å | Cell parameters from 7411 reflections |
b = 9.9047 (14) Å | θ = 4.0–56.6° |
c = 10.8332 (15) Å | µ = 1.44 mm−1 |
α = 66.933 (2)° | T = 293 K |
β = 77.581 (2)° | Block, blue |
γ = 64.206 (2)° | 0.45 × 0.23 × 0.21 mm |
V = 859.7 (2) Å3 | |
Data collection top
Bruker SMART CCD area-detector diffractometer | 3050 independent reflections |
Radiation source: fine-focus sealed tube | 2895 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.013 |
φ and ω scans | θmax = 25.1°, θmin = 2.1° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −11→11 |
Tmin = 0.678, Tmax = 0.739 | k = −11→11 |
6272 measured reflections | l = −12→12 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.027 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.075 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.03 | w = 1/[σ2(Fo2) + (0.0452P)2 + 0.4913P] where P = (Fo2 + 2Fc2)/3 |
3050 reflections | (Δ/σ)max < 0.001 |
268 parameters | Δρmax = 0.29 e Å−3 |
2 restraints | Δρmin = −0.35 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Cu1 | 0.20602 (3) | 0.38133 (3) | 0.28437 (2) | 0.02852 (10) | |
S1 | 0.55033 (6) | 1.06834 (6) | 0.25252 (5) | 0.02786 (13) | |
N1 | 0.23917 (19) | 0.4372 (2) | 0.08402 (17) | 0.0277 (4) | |
N2 | 0.0879 (2) | 0.2704 (2) | 0.25975 (17) | 0.0291 (4) | |
O1 | 0.25624 (19) | 0.55432 (19) | 0.27723 (15) | 0.0370 (4) | |
O2 | 0.2270 (2) | 0.5307 (2) | 0.49445 (16) | 0.0426 (4) | |
O3 | 0.68912 (17) | 0.97375 (18) | 0.32696 (16) | 0.0382 (4) | |
O4 | 0.5783 (2) | 1.1307 (2) | 0.10938 (16) | 0.0456 (4) | |
O5 | 0.44336 (18) | 1.19119 (18) | 0.30901 (15) | 0.0358 (4) | |
O6 | 0.16085 (19) | 0.31496 (19) | 0.47950 (15) | 0.0341 (3) | |
C1 | 0.2645 (2) | 0.5914 (2) | 0.3749 (2) | 0.0297 (4) | |
C2 | 0.3274 (2) | 0.7170 (2) | 0.3406 (2) | 0.0282 (4) | |
C3 | 0.3442 (2) | 0.8120 (3) | 0.2091 (2) | 0.0312 (5) | |
H3 | 0.3117 | 0.8020 | 0.1396 | 0.037* | |
C4 | 0.4087 (2) | 0.9212 (3) | 0.1807 (2) | 0.0306 (4) | |
H4 | 0.4186 | 0.9852 | 0.0924 | 0.037* | |
C5 | 0.4589 (2) | 0.9354 (2) | 0.2841 (2) | 0.0277 (4) | |
C6 | 0.4403 (3) | 0.8431 (3) | 0.4164 (2) | 0.0368 (5) | |
H6 | 0.4718 | 0.8542 | 0.4859 | 0.044* | |
C7 | 0.3749 (3) | 0.7353 (3) | 0.4438 (2) | 0.0359 (5) | |
H7 | 0.3620 | 0.6737 | 0.5325 | 0.043* | |
C8 | 0.3173 (2) | 0.5213 (3) | −0.0013 (2) | 0.0335 (5) | |
H8 | 0.3522 | 0.5758 | 0.0295 | 0.040* | |
C9 | 0.3486 (3) | 0.5304 (3) | −0.1359 (2) | 0.0378 (5) | |
H9 | 0.4054 | 0.5885 | −0.1927 | 0.045* | |
C10 | 0.2958 (3) | 0.4539 (3) | −0.1838 (2) | 0.0375 (5) | |
H10 | 0.3163 | 0.4595 | −0.2732 | 0.045* | |
C11 | 0.2099 (2) | 0.3667 (3) | −0.0967 (2) | 0.0326 (5) | |
C12 | 0.1441 (3) | 0.2860 (3) | −0.1365 (2) | 0.0414 (6) | |
H12 | 0.1597 | 0.2876 | −0.2248 | 0.050* | |
C13 | 0.0594 (3) | 0.2074 (3) | −0.0471 (3) | 0.0431 (6) | |
H13 | 0.0157 | 0.1586 | −0.0760 | 0.052* | |
C14 | 0.0357 (2) | 0.1978 (3) | 0.0905 (2) | 0.0338 (5) | |
C15 | −0.0512 (3) | 0.1194 (3) | 0.1886 (3) | 0.0394 (5) | |
H15 | −0.0981 | 0.0683 | 0.1662 | 0.047* | |
C16 | −0.0661 (3) | 0.1191 (3) | 0.3168 (2) | 0.0400 (5) | |
H16 | −0.1235 | 0.0676 | 0.3821 | 0.048* | |
C17 | 0.0044 (3) | 0.1955 (3) | 0.3502 (2) | 0.0355 (5) | |
H17 | −0.0072 | 0.1943 | 0.4381 | 0.043* | |
C18 | 0.1867 (2) | 0.3607 (2) | 0.0369 (2) | 0.0272 (4) | |
C19 | 0.1012 (2) | 0.2731 (2) | 0.1318 (2) | 0.0271 (4) | |
H6A | 0.217 (3) | 0.2227 (18) | 0.526 (2) | 0.050* | |
H6B | 0.180 (3) | 0.378 (3) | 0.501 (3) | 0.050* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Cu1 | 0.03688 (17) | 0.03313 (16) | 0.02215 (15) | −0.02089 (12) | −0.00200 (10) | −0.00752 (11) |
S1 | 0.0355 (3) | 0.0286 (3) | 0.0237 (3) | −0.0172 (2) | −0.0018 (2) | −0.0076 (2) |
N1 | 0.0294 (9) | 0.0292 (9) | 0.0252 (9) | −0.0133 (7) | −0.0034 (7) | −0.0070 (7) |
N2 | 0.0325 (9) | 0.0297 (9) | 0.0265 (9) | −0.0149 (8) | −0.0033 (7) | −0.0070 (7) |
O1 | 0.0568 (10) | 0.0400 (9) | 0.0277 (8) | −0.0309 (8) | −0.0003 (7) | −0.0124 (7) |
O2 | 0.0631 (11) | 0.0507 (10) | 0.0297 (8) | −0.0381 (9) | 0.0063 (7) | −0.0157 (7) |
O3 | 0.0343 (8) | 0.0361 (8) | 0.0458 (9) | −0.0189 (7) | −0.0063 (7) | −0.0075 (7) |
O4 | 0.0703 (12) | 0.0510 (10) | 0.0269 (8) | −0.0396 (9) | 0.0054 (8) | −0.0106 (7) |
O5 | 0.0420 (9) | 0.0329 (8) | 0.0362 (8) | −0.0120 (7) | −0.0082 (7) | −0.0153 (7) |
O6 | 0.0434 (9) | 0.0368 (8) | 0.0258 (8) | −0.0219 (7) | −0.0010 (6) | −0.0077 (7) |
C1 | 0.0315 (11) | 0.0303 (11) | 0.0297 (11) | −0.0131 (9) | −0.0016 (8) | −0.0114 (9) |
C2 | 0.0289 (10) | 0.0304 (10) | 0.0280 (10) | −0.0131 (9) | −0.0007 (8) | −0.0115 (8) |
C3 | 0.0381 (11) | 0.0338 (11) | 0.0265 (11) | −0.0144 (9) | −0.0062 (9) | −0.0124 (9) |
C4 | 0.0375 (11) | 0.0315 (11) | 0.0232 (10) | −0.0157 (9) | −0.0028 (8) | −0.0066 (8) |
C5 | 0.0306 (10) | 0.0301 (10) | 0.0264 (10) | −0.0146 (9) | −0.0009 (8) | −0.0109 (8) |
C6 | 0.0524 (14) | 0.0484 (13) | 0.0224 (11) | −0.0310 (11) | −0.0026 (9) | −0.0115 (10) |
C7 | 0.0503 (13) | 0.0442 (13) | 0.0217 (10) | −0.0298 (11) | 0.0005 (9) | −0.0080 (9) |
C8 | 0.0343 (11) | 0.0357 (11) | 0.0309 (11) | −0.0178 (9) | −0.0038 (9) | −0.0059 (9) |
C9 | 0.0358 (12) | 0.0401 (12) | 0.0307 (12) | −0.0165 (10) | 0.0009 (9) | −0.0047 (10) |
C10 | 0.0373 (12) | 0.0434 (13) | 0.0252 (11) | −0.0120 (10) | 0.0008 (9) | −0.0107 (10) |
C11 | 0.0317 (11) | 0.0337 (11) | 0.0287 (11) | −0.0065 (9) | −0.0025 (9) | −0.0135 (9) |
C12 | 0.0477 (13) | 0.0497 (14) | 0.0345 (12) | −0.0171 (11) | −0.0009 (10) | −0.0249 (11) |
C13 | 0.0486 (14) | 0.0484 (14) | 0.0480 (15) | −0.0201 (12) | −0.0043 (11) | −0.0298 (12) |
C14 | 0.0318 (11) | 0.0293 (11) | 0.0430 (13) | −0.0097 (9) | −0.0047 (9) | −0.0160 (10) |
C15 | 0.0395 (12) | 0.0345 (12) | 0.0528 (14) | −0.0184 (10) | −0.0047 (11) | −0.0176 (11) |
C16 | 0.0410 (13) | 0.0359 (12) | 0.0445 (14) | −0.0233 (11) | −0.0017 (10) | −0.0058 (10) |
C17 | 0.0397 (12) | 0.0375 (12) | 0.0298 (11) | −0.0211 (10) | −0.0026 (9) | −0.0047 (9) |
C18 | 0.0268 (10) | 0.0262 (10) | 0.0260 (10) | −0.0069 (8) | −0.0042 (8) | −0.0088 (8) |
C19 | 0.0276 (10) | 0.0237 (10) | 0.0293 (11) | −0.0082 (8) | −0.0042 (8) | −0.0091 (8) |
Geometric parameters (Å, º) top
Cu1—O1 | 1.9452 (15) | C5—C6 | 1.388 (3) |
Cu1—O6 | 1.9636 (15) | C6—C7 | 1.375 (3) |
Cu1—N1 | 2.0084 (17) | C6—H6 | 0.93 |
Cu1—N2 | 2.0103 (17) | C7—H7 | 0.93 |
Cu1—O5i | 2.2372 (15) | C8—C9 | 1.399 (3) |
S1—O4 | 1.4400 (16) | C8—H8 | 0.93 |
S1—O3 | 1.4538 (16) | C9—C10 | 1.366 (3) |
S1—O5 | 1.4637 (16) | C9—H9 | 0.93 |
S1—C5 | 1.780 (2) | C10—C11 | 1.406 (3) |
N1—C8 | 1.328 (3) | C10—H10 | 0.93 |
N1—C18 | 1.358 (3) | C11—C18 | 1.397 (3) |
N2—C17 | 1.333 (3) | C11—C12 | 1.437 (3) |
N2—C19 | 1.355 (3) | C12—C13 | 1.356 (4) |
O1—C1 | 1.275 (3) | C12—H12 | 0.93 |
O2—C1 | 1.245 (3) | C13—C14 | 1.430 (3) |
O6—H6A | 0.84 (1) | C13—H13 | 0.93 |
O6—H6B | 0.84 (3) | C14—C19 | 1.398 (3) |
C1—C2 | 1.502 (3) | C14—C15 | 1.406 (3) |
C2—C3 | 1.387 (3) | C15—C16 | 1.364 (4) |
C2—C7 | 1.396 (3) | C15—H15 | 0.93 |
C3—C4 | 1.378 (3) | C16—C17 | 1.393 (3) |
C3—H3 | 0.93 | C16—H16 | 0.93 |
C4—C5 | 1.389 (3) | C17—H17 | 0.93 |
C4—H4 | 0.93 | C18—C19 | 1.434 (3) |
| | | |
O1—Cu1—O6 | 94.51 (6) | C7—C6—C5 | 119.5 (2) |
O1—Cu1—N1 | 91.12 (7) | C7—C6—H6 | 120.3 |
O6—Cu1—N1 | 173.99 (7) | C5—C6—H6 | 120.3 |
O1—Cu1—N2 | 159.31 (7) | C6—C7—C2 | 120.9 (2) |
O6—Cu1—N2 | 92.05 (7) | C6—C7—H7 | 119.5 |
N1—Cu1—N2 | 81.94 (7) | C2—C7—H7 | 119.5 |
O1—Cu1—O5i | 97.76 (7) | N1—C8—C9 | 122.1 (2) |
O6—Cu1—O5i | 91.45 (6) | N1—C8—H8 | 119.0 |
N1—Cu1—O5i | 89.85 (6) | C9—C8—H8 | 119.0 |
N2—Cu1—O5i | 101.66 (6) | C10—C9—C8 | 119.9 (2) |
O4—S1—O3 | 114.00 (10) | C10—C9—H9 | 120.0 |
O4—S1—O5 | 112.99 (10) | C8—C9—H9 | 120.0 |
O3—S1—O5 | 110.59 (9) | C9—C10—C11 | 119.4 (2) |
O4—S1—C5 | 107.68 (10) | C9—C10—H10 | 120.3 |
O3—S1—C5 | 105.38 (9) | C11—C10—H10 | 120.3 |
O5—S1—C5 | 105.50 (9) | C18—C11—C10 | 117.0 (2) |
C8—N1—C18 | 118.18 (18) | C18—C11—C12 | 118.6 (2) |
C8—N1—Cu1 | 129.11 (15) | C10—C11—C12 | 124.4 (2) |
C18—N1—Cu1 | 112.25 (13) | C13—C12—C11 | 120.9 (2) |
C17—N2—C19 | 118.13 (19) | C13—C12—H12 | 119.6 |
C17—N2—Cu1 | 129.28 (15) | C11—C12—H12 | 119.6 |
C19—N2—Cu1 | 112.57 (14) | C12—C13—C14 | 121.6 (2) |
C1—O1—Cu1 | 128.15 (14) | C12—C13—H13 | 119.2 |
S1—O5—Cu1ii | 140.46 (9) | C14—C13—H13 | 119.2 |
Cu1—O6—H6A | 118 (2) | C19—C14—C15 | 116.8 (2) |
Cu1—O6—H6B | 102 (2) | C19—C14—C13 | 118.4 (2) |
H6A—O6—H6B | 106 (3) | C15—C14—C13 | 124.8 (2) |
O2—C1—O1 | 125.3 (2) | C16—C15—C14 | 119.4 (2) |
O2—C1—C2 | 118.40 (18) | C16—C15—H15 | 120.3 |
O1—C1—C2 | 116.27 (18) | C14—C15—H15 | 120.3 |
C3—C2—C7 | 118.94 (19) | C15—C16—C17 | 120.2 (2) |
C3—C2—C1 | 122.07 (19) | C15—C16—H16 | 119.9 |
C7—C2—C1 | 118.96 (18) | C17—C16—H16 | 119.9 |
C4—C3—C2 | 120.58 (19) | N2—C17—C16 | 121.8 (2) |
C4—C3—H3 | 119.7 | N2—C17—H17 | 119.1 |
C2—C3—H3 | 119.7 | C16—C17—H17 | 119.1 |
C3—C4—C5 | 119.88 (19) | N1—C18—C11 | 123.38 (19) |
C3—C4—H4 | 120.1 | N1—C18—C19 | 116.39 (18) |
C5—C4—H4 | 120.1 | C11—C18—C19 | 120.22 (19) |
C6—C5—C4 | 120.17 (19) | N2—C19—C14 | 123.52 (19) |
C6—C5—S1 | 118.03 (16) | N2—C19—C18 | 116.14 (18) |
C4—C5—S1 | 121.79 (16) | C14—C19—C18 | 120.34 (19) |
| | | |
O1—Cu1—N1—C8 | 19.98 (19) | C5—C6—C7—C2 | 0.2 (4) |
N2—Cu1—N1—C8 | −179.58 (19) | C3—C2—C7—C6 | −1.4 (3) |
O5i—Cu1—N1—C8 | −77.78 (19) | C1—C2—C7—C6 | 176.7 (2) |
O1—Cu1—N1—C18 | −168.04 (14) | C18—N1—C8—C9 | −1.1 (3) |
N2—Cu1—N1—C18 | −7.61 (14) | Cu1—N1—C8—C9 | 170.44 (16) |
O5i—Cu1—N1—C18 | 94.20 (14) | N1—C8—C9—C10 | 1.3 (3) |
O1—Cu1—N2—C17 | −103.8 (2) | C8—C9—C10—C11 | 0.1 (3) |
O6—Cu1—N2—C17 | 4.75 (19) | C9—C10—C11—C18 | −1.4 (3) |
N1—Cu1—N2—C17 | −175.2 (2) | C9—C10—C11—C12 | 177.8 (2) |
O5i—Cu1—N2—C17 | 96.65 (19) | C18—C11—C12—C13 | 0.9 (3) |
O1—Cu1—N2—C19 | 77.5 (2) | C10—C11—C12—C13 | −178.3 (2) |
O6—Cu1—N2—C19 | −173.94 (14) | C11—C12—C13—C14 | −1.8 (4) |
N1—Cu1—N2—C19 | 6.14 (13) | C12—C13—C14—C19 | 0.6 (3) |
O5i—Cu1—N2—C19 | −82.04 (14) | C12—C13—C14—C15 | 179.6 (2) |
O6—Cu1—O1—C1 | 4.67 (19) | C19—C14—C15—C16 | −0.6 (3) |
N1—Cu1—O1—C1 | −177.42 (19) | C13—C14—C15—C16 | −179.7 (2) |
N2—Cu1—O1—C1 | 112.8 (2) | C14—C15—C16—C17 | −0.1 (4) |
O5i—Cu1—O1—C1 | −87.42 (19) | C19—N2—C17—C16 | 1.1 (3) |
O4—S1—O5—Cu1ii | 55.43 (18) | Cu1—N2—C17—C16 | −177.53 (17) |
O3—S1—O5—Cu1ii | −175.43 (13) | C15—C16—C17—N2 | −0.1 (4) |
C5—S1—O5—Cu1ii | −61.96 (17) | C8—N1—C18—C11 | −0.4 (3) |
Cu1—O1—C1—O2 | −7.2 (3) | Cu1—N1—C18—C11 | −173.33 (16) |
Cu1—O1—C1—C2 | 171.70 (14) | C8—N1—C18—C19 | −179.18 (18) |
O2—C1—C2—C3 | −167.4 (2) | Cu1—N1—C18—C19 | 7.9 (2) |
O1—C1—C2—C3 | 13.6 (3) | C10—C11—C18—N1 | 1.7 (3) |
O2—C1—C2—C7 | 14.7 (3) | C12—C11—C18—N1 | −177.6 (2) |
O1—C1—C2—C7 | −164.4 (2) | C10—C11—C18—C19 | −179.58 (19) |
C7—C2—C3—C4 | 0.9 (3) | C12—C11—C18—C19 | 1.1 (3) |
C1—C2—C3—C4 | −177.1 (2) | C17—N2—C19—C14 | −1.9 (3) |
C2—C3—C4—C5 | 0.7 (3) | Cu1—N2—C19—C14 | 176.95 (16) |
C3—C4—C5—C6 | −1.9 (3) | C17—N2—C19—C18 | 177.45 (19) |
C3—C4—C5—S1 | 177.33 (16) | Cu1—N2—C19—C18 | −3.7 (2) |
O4—S1—C5—C6 | 171.01 (18) | C15—C14—C19—N2 | 1.7 (3) |
O3—S1—C5—C6 | 49.0 (2) | C13—C14—C19—N2 | −179.2 (2) |
O5—S1—C5—C6 | −68.08 (19) | C15—C14—C19—C18 | −177.66 (19) |
O4—S1—C5—C4 | −8.2 (2) | C13—C14—C19—C18 | 1.4 (3) |
O3—S1—C5—C4 | −130.23 (18) | N1—C18—C19—N2 | −2.8 (3) |
O5—S1—C5—C4 | 112.72 (18) | C11—C18—C19—N2 | 178.32 (18) |
C4—C5—C6—C7 | 1.4 (3) | N1—C18—C19—C14 | 176.53 (18) |
S1—C5—C6—C7 | −177.79 (19) | C11—C18—C19—C14 | −2.3 (3) |
Symmetry codes: (i) x, y−1, z; (ii) x, y+1, z. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O6—H6A···O3iii | 0.84 (1) | 1.95 (1) | 2.771 (2) | 165 (3) |
O6—H6B···O2 | 0.84 (3) | 1.73 (3) | 2.551 (2) | 163 (3) |
Symmetry code: (iii) −x+1, −y+1, −z+1. |