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Acta Cryst. (2008). E64, m709    [ doi:10.1107/S1600536808010829 ]

Chlorido(chlorodifluoroacetato-[kappa]O)bis(1,10-phenanthroline-[kappa]2N,N')manganese(II)

K. M. Lo and S. W. Ng

Abstract top

The chloride and chlorodifluoroacetate anions occupy cis positions in the octahedral coordination geometry of the title compound, [Mn(C2ClF2O2)Cl(C12H8N2)2]. The two N-heterocycles both chelate the metal atom.

Comment top

Manganese dichloride typically reacts with carboxylate anions in the presence of a neutral α,α-dimine ligand (such as 1,10-phenanthroline) to furnish the expected manganese dicarboxylate as the 1:2 adduct of the N-heterocycle. In the case of the reaction with the trichloroacetate anion, only one chloride is displaced. Chlorido-bis(1,10-phenanthroline)(trichloroacetato)manganese exists as a monomeric compound; the crystal structure displays π–π interactions that appear to stabilize the structure (Chen et al., 2006). Replacing the trichloroacetate anion by the chlorodifluoroacetate anion furnishes an isostructural compound (Scheme I, Fig. 1).

Related literature top

For isostructural chlorido(1,10-phenanthroline)(trichloroacetato)manganese, see: Chen et al. (2006).

Experimental top

Manganese dichloride dihydrate (0.5 g, 3 mmol) was dissolved in ethanol and chlorodifluoroacetic acid (0.3 ml, 3 mol) was added. The mixture was heated briefly, after which 1,10-phenanthroline (1.6 g, 6 mmol) was added. The solution when allowed to cool yielded yellow crystals.

Refinement top

Carbon-bound H-atoms were placed in calculated positions (C—H 0.95 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2Ueq(C).

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2008).

Figures top
[Figure 1] Fig. 1. 70% Probability thermal ellipsoid plot (Barbour, 2001) of Mn(C12H8N2)2(C2ClF2O2)Cl. Hydrogen atoms are drawn as spheres of arbitrary radii.
Chlorido(chlorodifluoroacetato-κO)bis(1,10-phenanthroline- κ2N,N')manganese(II) top
Crystal data top
[Mn(C2ClF2O2)Cl(C12H8N2)2]F000 = 1172
Mr = 580.27Dx = 1.566 Mg m−3
Monoclinic, P21/cMo Kα radiation
λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 2908 reflections
a = 16.8822 (4) Åθ = 2.3–21.4º
b = 10.3781 (3) ŵ = 0.80 mm−1
c = 14.8364 (5) ÅT = 100 (2) K
β = 108.813 (2)ºIrregular block, yellow
V = 2460.5 (1) Å30.20 × 0.15 × 0.10 mm
Z = 4
Data collection top
Bruker SMART APEX
diffractometer		5628 independent reflections
Radiation source: fine-focus sealed tube3863 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.104
T = 100(2) Kθmax = 27.5º
ω scansθmin = 1.3º
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		h = −21→21
Tmin = 0.856, Tmax = 0.924k = −13→13
30077 measured reflectionsl = −19→14
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.057H-atom parameters constrained
wR(F2) = 0.165  w = 1/[σ2(Fo2) + (0.0868P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.04(Δ/σ)max = 0.001
5628 reflectionsΔρmax = 1.00 e Å−3
334 parametersΔρmin = −0.62 e Å−3
Primary atom site location: structure-invariant direct methodsExtinction correction: none
Crystal data top
[Mn(C2ClF2O2)Cl(C12H8N2)2]V = 2460.5 (1) Å3
Mr = 580.27Z = 4
Monoclinic, P21/cMo Kα
a = 16.8822 (4) ŵ = 0.80 mm−1
b = 10.3781 (3) ÅT = 100 (2) K
c = 14.8364 (5) Å0.20 × 0.15 × 0.10 mm
β = 108.813 (2)º
Data collection top
Bruker SMART APEX
diffractometer		5628 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		3863 reflections with I > 2σ(I)
Tmin = 0.856, Tmax = 0.924Rint = 0.104
30077 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.057334 parameters
wR(F2) = 0.165H-atom parameters constrained
S = 1.04Δρmax = 1.00 e Å−3
5628 reflectionsΔρmin = −0.62 e Å−3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mn10.28449 (3)0.63507 (5)0.17308 (4)0.02130 (16)
Cl10.33600 (5)0.60920 (8)0.03799 (6)0.0247 (2)
Cl20.21097 (8)1.04489 (11)0.29372 (9)0.0536 (3)
F10.09738 (14)1.0724 (2)0.1347 (2)0.0545 (8)
F20.22337 (14)1.0904 (2)0.13132 (18)0.0402 (6)
O10.24710 (14)0.8334 (2)0.15829 (18)0.0264 (6)
O20.10701 (14)0.8221 (2)0.1178 (2)0.0330 (6)
N10.17254 (16)0.5061 (3)0.1004 (2)0.0240 (6)
N20.21023 (16)0.6109 (3)0.2757 (2)0.0230 (6)
N30.39971 (15)0.7160 (3)0.2897 (2)0.0219 (6)
N40.36197 (16)0.4637 (3)0.2525 (2)0.0215 (6)
C10.1249 (2)0.4714 (3)0.1547 (3)0.0239 (7)
C20.1524 (2)0.4572 (3)0.0131 (3)0.0275 (8)
H20.18570.4800−0.02540.033*
C30.0848 (2)0.3739 (3)−0.0250 (3)0.0338 (9)
H30.07200.3432−0.08850.041*
C40.0376 (2)0.3369 (3)0.0295 (3)0.0312 (9)
H4−0.00800.27930.00490.037*
C50.0572 (2)0.3857 (3)0.1237 (3)0.0279 (8)
C60.0103 (2)0.3542 (3)0.1854 (3)0.0328 (9)
H6−0.03560.29630.16380.039*
C70.0297 (2)0.4050 (4)0.2738 (3)0.0313 (9)
H7−0.00180.38130.31400.038*
C80.0975 (2)0.4944 (3)0.3072 (3)0.0266 (8)
C90.1187 (2)0.5535 (3)0.3974 (3)0.0294 (8)
H90.08850.53320.43970.035*
C100.1829 (2)0.6399 (3)0.4236 (3)0.0316 (8)
H100.19730.68190.48360.038*
C110.2276 (2)0.6658 (3)0.3604 (3)0.0248 (7)
H110.27240.72570.37950.030*
C120.14495 (19)0.5264 (3)0.2484 (3)0.0228 (7)
C130.45711 (19)0.6274 (3)0.3381 (2)0.0217 (7)
C140.4167 (2)0.8390 (3)0.3096 (3)0.0274 (8)
H140.37660.90140.27670.033*
C150.4910 (2)0.8821 (3)0.3767 (3)0.0299 (8)
H150.50060.97160.38910.036*
C160.5496 (2)0.7935 (3)0.4243 (3)0.0282 (8)
H160.60070.82100.46960.034*
C170.5338 (2)0.6622 (3)0.4060 (3)0.0251 (8)
C180.5921 (2)0.5629 (3)0.4517 (3)0.0291 (8)
H180.64460.58610.49620.035*
C190.5738 (2)0.4374 (3)0.4329 (3)0.0280 (8)
H190.61350.37370.46430.034*
C200.4951 (2)0.3985 (3)0.3662 (3)0.0241 (7)
C210.4724 (2)0.2692 (3)0.3466 (3)0.0271 (8)
H210.50970.20250.37780.033*
C220.3961 (2)0.2393 (3)0.2822 (3)0.0284 (8)
H220.37950.15200.26890.034*
C230.3430 (2)0.3395 (3)0.2362 (3)0.0249 (8)
H230.29060.31780.19090.030*
C240.43732 (19)0.4937 (3)0.3181 (2)0.0211 (7)
C250.1748 (2)0.8752 (3)0.1456 (2)0.0234 (7)
C260.1740 (2)1.0211 (3)0.1694 (3)0.0330 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mn10.0192 (3)0.0265 (3)0.0161 (3)−0.00035 (19)0.0028 (2)−0.0001 (2)
Cl10.0231 (4)0.0310 (4)0.0189 (5)0.0005 (3)0.0053 (3)0.0006 (3)
Cl20.0682 (7)0.0614 (7)0.0398 (7)−0.0225 (6)0.0291 (6)−0.0250 (5)
F10.0351 (12)0.0376 (13)0.086 (2)0.0129 (10)0.0131 (13)0.0026 (13)
F20.0446 (13)0.0359 (12)0.0427 (16)−0.0083 (10)0.0178 (11)0.0021 (11)
O10.0224 (12)0.0323 (13)0.0221 (14)0.0033 (9)0.0038 (10)0.0028 (10)
O20.0236 (12)0.0375 (14)0.0354 (17)−0.0043 (10)0.0061 (12)−0.0090 (12)
N10.0213 (13)0.0294 (15)0.0185 (16)0.0014 (11)0.0024 (12)−0.0009 (12)
N20.0199 (13)0.0282 (15)0.0185 (16)0.0015 (11)0.0028 (12)0.0013 (12)
N30.0200 (13)0.0265 (15)0.0174 (16)−0.0022 (11)0.0036 (12)0.0019 (11)
N40.0207 (13)0.0280 (15)0.0158 (16)−0.0024 (11)0.0057 (12)−0.0013 (11)
C10.0208 (15)0.0279 (17)0.0204 (19)0.0042 (13)0.0032 (14)0.0028 (14)
C20.0279 (17)0.0340 (19)0.017 (2)−0.0003 (14)0.0022 (15)−0.0027 (15)
C30.034 (2)0.037 (2)0.024 (2)−0.0029 (16)0.0000 (17)−0.0069 (16)
C40.0240 (17)0.0299 (19)0.032 (2)−0.0014 (14)−0.0015 (16)−0.0027 (16)
C50.0242 (17)0.0295 (18)0.025 (2)0.0015 (14)0.0017 (15)−0.0007 (15)
C60.0222 (17)0.035 (2)0.037 (2)−0.0039 (14)0.0042 (17)0.0015 (17)
C70.0267 (18)0.037 (2)0.033 (2)0.0002 (15)0.0130 (17)0.0044 (17)
C80.0221 (16)0.0308 (18)0.025 (2)0.0011 (14)0.0044 (15)0.0028 (15)
C90.0291 (18)0.040 (2)0.020 (2)0.0007 (15)0.0101 (16)0.0041 (16)
C100.0336 (19)0.040 (2)0.020 (2)0.0023 (16)0.0070 (16)−0.0016 (16)
C110.0225 (16)0.0343 (18)0.0140 (18)−0.0009 (13)0.0009 (14)−0.0014 (14)
C120.0177 (15)0.0279 (17)0.0197 (19)0.0032 (13)0.0018 (14)0.0015 (14)
C130.0211 (15)0.0271 (17)0.0172 (18)−0.0006 (13)0.0067 (14)0.0018 (14)
C140.0259 (17)0.0265 (18)0.028 (2)−0.0006 (13)0.0063 (16)0.0005 (15)
C150.0263 (17)0.0292 (18)0.030 (2)−0.0073 (14)0.0042 (16)−0.0041 (16)
C160.0240 (16)0.0343 (19)0.024 (2)−0.0074 (14)0.0048 (15)−0.0008 (15)
C170.0229 (16)0.0341 (19)0.0187 (19)−0.0043 (14)0.0071 (15)0.0009 (15)
C180.0202 (16)0.037 (2)0.025 (2)−0.0021 (14)0.0003 (15)−0.0001 (16)
C190.0235 (16)0.0338 (19)0.022 (2)0.0043 (14)0.0014 (15)0.0031 (15)
C200.0209 (16)0.0340 (18)0.0159 (18)0.0020 (14)0.0042 (14)0.0017 (14)
C210.0263 (17)0.0274 (18)0.026 (2)0.0048 (14)0.0061 (15)0.0028 (15)
C220.0268 (17)0.0271 (18)0.028 (2)0.0018 (14)0.0047 (15)0.0000 (15)
C230.0213 (16)0.0295 (18)0.023 (2)−0.0012 (13)0.0055 (15)0.0006 (14)
C240.0206 (15)0.0303 (17)0.0134 (17)0.0002 (13)0.0070 (13)0.0025 (13)
C250.0224 (16)0.0364 (19)0.0107 (17)0.0001 (14)0.0045 (14)0.0008 (14)
C260.0266 (17)0.037 (2)0.035 (2)0.0007 (15)0.0089 (17)−0.0015 (17)
Geometric parameters (Å, °) top
Mn1—O12.143 (2)C7—C81.432 (5)
Mn1—N12.283 (3)C7—H70.9500
Mn1—N22.277 (3)C8—C121.401 (5)
Mn1—N32.305 (3)C8—C91.410 (5)
Mn1—N42.295 (3)C9—C101.363 (5)
Mn1—Cl12.443 (1)C9—H90.9500
Cl2—C261.764 (4)C10—C111.405 (5)
F1—C261.339 (4)C10—H100.9500
F2—C261.355 (4)C11—H110.9500
O1—C251.250 (4)C13—C171.407 (5)
O2—C251.217 (4)C13—C241.436 (4)
N1—C21.330 (5)C14—C151.400 (5)
N1—C11.358 (5)C14—H140.9500
N2—C111.324 (5)C15—C161.368 (5)
N2—C121.363 (4)C15—H150.9500
N3—C141.321 (4)C16—C171.398 (5)
N3—C131.361 (4)C16—H160.9500
N4—C231.331 (4)C17—C181.436 (5)
N4—C241.365 (4)C18—C191.346 (5)
C1—C51.403 (5)C18—H180.9500
C1—C121.440 (5)C19—C201.435 (5)
C2—C31.398 (5)C19—H190.9500
C2—H20.9500C20—C211.399 (5)
C3—C41.362 (6)C20—C241.410 (4)
C3—H30.9500C21—C221.369 (5)
C4—C51.422 (5)C21—H210.9500
C4—H40.9500C22—C231.398 (5)
C5—C61.428 (6)C22—H220.9500
C6—C71.353 (6)C23—H230.9500
C6—H60.9500C25—C261.556 (5)
O1—Mn1—N1110.1 (1)C9—C10—C11119.0 (4)
O1—Mn1—N288.1 (1)C9—C10—H10120.5
O1—Mn1—N382.9 (1)C11—C10—H10120.5
O1—Mn1—N4153.8 (1)N2—C11—C10123.3 (3)
O1—Mn1—Cl1101.1 (1)N2—C11—H11118.4
N1—Mn1—N272.6 (1)C10—C11—H11118.3
N1—Mn1—N3159.7 (1)N2—C12—C8122.5 (3)
N1—Mn1—N492.1 (1)N2—C12—C1117.2 (3)
N1—Mn1—Cl190.4 (1)C8—C12—C1120.2 (3)
N2—Mn1—N393.0 (1)N3—C13—C17122.6 (3)
N2—Mn1—N485.2 (1)N3—C13—C24117.8 (3)
N2—Mn1—Cl1162.7 (1)C17—C13—C24119.7 (3)
N3—Mn1—N472.2 (1)N3—C14—C15123.2 (3)
N3—Mn1—Cl1102.6 (1)N3—C14—H14118.4
N4—Mn1—Cl192.4 (1)C15—C14—H14118.4
C25—O1—Mn1126.1 (2)C16—C15—C14119.0 (3)
C2—N1—C1117.6 (3)C16—C15—H15120.5
C2—N1—Mn1126.6 (2)C14—C15—H15120.5
C1—N1—Mn1115.7 (2)C15—C16—C17119.6 (3)
C11—N2—C12117.9 (3)C15—C16—H16120.2
C11—N2—Mn1125.9 (2)C17—C16—H16120.2
C12—N2—Mn1116.0 (2)C16—C17—C13117.6 (3)
C14—N3—C13117.9 (3)C16—C17—C18123.3 (3)
C14—N3—Mn1126.2 (2)C13—C17—C18119.1 (3)
C13—N3—Mn1115.8 (2)C19—C18—C17121.3 (3)
C23—N4—C24117.7 (3)C19—C18—H18119.3
C23—N4—Mn1126.4 (2)C17—C18—H18119.3
C24—N4—Mn1115.8 (2)C18—C19—C20121.0 (3)
N1—C1—C5123.3 (3)C18—C19—H19119.5
N1—C1—C12117.9 (3)C20—C19—H19119.5
C5—C1—C12118.7 (3)C21—C20—C24117.9 (3)
N1—C2—C3123.3 (4)C21—C20—C19123.0 (3)
N1—C2—H2118.4C24—C20—C19119.1 (3)
C3—C2—H2118.4C22—C21—C20119.7 (3)
C4—C3—C2119.5 (4)C22—C21—H21120.2
C4—C3—H3120.3C20—C21—H21120.2
C2—C3—H3120.3C21—C22—C23118.9 (3)
C3—C4—C5119.2 (3)C21—C22—H22120.6
C3—C4—H4120.4C23—C22—H22120.6
C5—C4—H4120.4N4—C23—C22123.5 (3)
C1—C5—C4117.0 (3)N4—C23—H23118.2
C1—C5—C6119.8 (4)C22—C23—H23118.2
C4—C5—C6123.1 (3)N4—C24—C20122.3 (3)
C7—C6—C5121.4 (3)N4—C24—C13117.9 (3)
C7—C6—H6119.3C20—C24—C13119.8 (3)
C5—C6—H6119.3O2—C25—O1131.3 (3)
C6—C7—C8120.3 (4)O2—C25—C26116.1 (3)
C6—C7—H7119.9O1—C25—C26112.5 (3)
C8—C7—H7119.9F1—C26—F2106.1 (3)
C12—C8—C9117.8 (3)F1—C26—C25112.2 (3)
C12—C8—C7119.5 (3)F2—C26—C25111.7 (3)
C9—C8—C7122.7 (3)F1—C26—Cl2108.6 (3)
C10—C9—C8119.5 (4)F2—C26—Cl2107.7 (2)
C10—C9—H9120.3C25—C26—Cl2110.3 (3)
C8—C9—H9120.3
N2—Mn1—O1—C25−45.9 (3)C12—C8—C9—C101.0 (5)
N1—Mn1—O1—C2524.8 (3)C7—C8—C9—C10−178.5 (3)
N4—Mn1—O1—C25−121.0 (3)C8—C9—C10—C11−1.4 (5)
N3—Mn1—O1—C25−139.1 (3)C12—N2—C11—C100.9 (5)
Cl1—Mn1—O1—C25119.4 (3)Mn1—N2—C11—C10−175.2 (2)
O1—Mn1—N1—C296.7 (3)C9—C10—C11—N20.4 (5)
N2—Mn1—N1—C2178.0 (3)C11—N2—C12—C8−1.3 (5)
N4—Mn1—N1—C2−97.7 (3)Mn1—N2—C12—C8175.2 (2)
N3—Mn1—N1—C2−135.8 (3)C11—N2—C12—C1177.6 (3)
Cl1—Mn1—N1—C2−5.3 (3)Mn1—N2—C12—C1−5.9 (4)
O1—Mn1—N1—C1−87.0 (2)C9—C8—C12—N20.4 (5)
N2—Mn1—N1—C1−5.7 (2)C7—C8—C12—N2179.9 (3)
N4—Mn1—N1—C178.7 (2)C9—C8—C12—C1−178.5 (3)
N3—Mn1—N1—C140.5 (4)C7—C8—C12—C11.0 (5)
Cl1—Mn1—N1—C1171.1 (2)N1—C1—C12—N20.7 (4)
O1—Mn1—N2—C11−66.0 (3)C5—C1—C12—N2−179.0 (3)
N1—Mn1—N2—C11−177.7 (3)N1—C1—C12—C8179.7 (3)
N4—Mn1—N2—C1188.6 (3)C5—C1—C12—C80.0 (5)
N3—Mn1—N2—C1116.7 (3)C14—N3—C13—C17−1.5 (5)
Cl1—Mn1—N2—C11171.2 (2)Mn1—N3—C13—C17174.8 (3)
O1—Mn1—N2—C12117.8 (2)C14—N3—C13—C24178.3 (3)
N1—Mn1—N2—C126.1 (2)Mn1—N3—C13—C24−5.3 (4)
N4—Mn1—N2—C12−87.6 (2)C13—N3—C14—C150.8 (5)
N3—Mn1—N2—C12−159.4 (2)Mn1—N3—C14—C15−175.1 (3)
Cl1—Mn1—N2—C12−5.0 (4)N3—C14—C15—C160.3 (6)
O1—Mn1—N3—C14−6.1 (3)C14—C15—C16—C17−0.8 (6)
N2—Mn1—N3—C14−93.8 (3)C15—C16—C17—C130.1 (5)
N1—Mn1—N3—C14−137.4 (3)C15—C16—C17—C18179.2 (4)
N4—Mn1—N3—C14−177.8 (3)N3—C13—C17—C161.1 (5)
Cl1—Mn1—N3—C1493.7 (3)C24—C13—C17—C16−178.8 (3)
O1—Mn1—N3—C13177.9 (2)N3—C13—C17—C18−178.1 (3)
N2—Mn1—N3—C1390.2 (2)C24—C13—C17—C182.1 (5)
N1—Mn1—N3—C1346.6 (4)C16—C17—C18—C19179.0 (4)
N4—Mn1—N3—C136.1 (2)C13—C17—C18—C19−1.9 (6)
Cl1—Mn1—N3—C13−82.3 (2)C17—C18—C19—C200.0 (6)
O1—Mn1—N4—C23159.6 (3)C18—C19—C20—C21−178.0 (4)
N2—Mn1—N4—C2383.7 (3)C18—C19—C20—C241.7 (5)
N1—Mn1—N4—C2311.4 (3)C24—C20—C21—C220.2 (5)
N3—Mn1—N4—C23178.4 (3)C19—C20—C21—C22179.9 (4)
Cl1—Mn1—N4—C23−79.1 (3)C20—C21—C22—C231.0 (6)
O1—Mn1—N4—C24−25.2 (4)C24—N4—C23—C22−0.3 (5)
N2—Mn1—N4—C24−101.0 (2)Mn1—N4—C23—C22174.8 (3)
N1—Mn1—N4—C24−173.4 (2)C21—C22—C23—N4−1.0 (6)
N3—Mn1—N4—C24−6.4 (2)C23—N4—C24—C201.6 (5)
Cl1—Mn1—N4—C2496.1 (2)Mn1—N4—C24—C20−174.1 (3)
C2—N1—C1—C51.2 (5)C23—N4—C24—C13−178.2 (3)
Mn1—N1—C1—C5−175.5 (2)Mn1—N4—C24—C136.1 (4)
C2—N1—C1—C12−178.5 (3)C21—C20—C24—N4−1.5 (5)
Mn1—N1—C1—C124.8 (4)C19—C20—C24—N4178.8 (3)
C1—N1—C2—C30.7 (5)C21—C20—C24—C13178.3 (3)
Mn1—N1—C2—C3176.9 (3)C19—C20—C24—C13−1.4 (5)
N1—C2—C3—C4−1.8 (5)N3—C13—C24—N4−0.5 (5)
C2—C3—C4—C51.0 (5)C17—C13—C24—N4179.3 (3)
N1—C1—C5—C4−1.8 (5)N3—C13—C24—C20179.7 (3)
C12—C1—C5—C4177.9 (3)C17—C13—C24—C20−0.5 (5)
N1—C1—C5—C6180.0 (3)Mn1—O1—C25—O2−18.7 (6)
C12—C1—C5—C6−0.3 (5)Mn1—O1—C25—C26161.9 (2)
C3—C4—C5—C10.7 (5)O2—C25—C26—F1−14.5 (5)
C3—C4—C5—C6178.8 (3)O1—C25—C26—F1164.9 (3)
C1—C5—C6—C7−0.2 (5)O2—C25—C26—F2−133.6 (3)
C4—C5—C6—C7−178.3 (3)O1—C25—C26—F245.9 (4)
C5—C6—C7—C81.2 (5)O2—C25—C26—Cl2106.7 (3)
C6—C7—C8—C12−1.6 (5)O1—C25—C26—Cl2−73.8 (3)
C6—C7—C8—C9177.9 (3)
Table 1
Selected geometric parameters (Å, °) top
Mn1—O12.143 (2)Mn1—N32.305 (3)
Mn1—N12.283 (3)Mn1—N42.295 (3)
Mn1—N22.277 (3)Mn1—Cl12.443 (1)
O1—Mn1—N1110.1 (1)N1—Mn1—Cl190.4 (1)
O1—Mn1—N288.1 (1)N2—Mn1—N393.0 (1)
O1—Mn1—N382.9 (1)N2—Mn1—N485.2 (1)
O1—Mn1—N4153.8 (1)N2—Mn1—Cl1162.7 (1)
O1—Mn1—Cl1101.1 (1)N3—Mn1—N472.2 (1)
N1—Mn1—N272.6 (1)N3—Mn1—Cl1102.6 (1)
N1—Mn1—N3159.7 (1)N4—Mn1—Cl192.4 (1)
N1—Mn1—N492.1 (1)
Acknowledgements top

The authors thank the University of Malaya for funding this study (grant No.SF022155/2007 A) and also for the purchase of the diffractometer.

references
References top

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