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Acta Cryst. (2009). E65, m259    [ doi:10.1107/S1600536809003547 ]

Bis([mu]-2-methylquinolin-8-olato)-[kappa]3N,O:O;[kappa]3O:N,O-bis[(methanol-[kappa]O)(nitrato-[kappa]2O,O')lead(II)]

G. Mohammadnezhad Sh., M. M. Amini and S. W. Ng

Abstract top

The molecule of the title compound, [Pb2(C10H8NO)2(NO3)2(CH3OH)2], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb...O interaction is considered, the geometry approximates a [Psi]-cube in which one of the sites is occupied by a stereochemically active lone pair.

Related literature top

The 8-hydroxyquinolinate group engages in µ3-bridging in dinitratohexa(quinolin-8-olato)tetralead(II); see: Zhang et al. (2008). It also exhibits this feature in the chain compound, bis(methanol)dinitratodi(quinolin-8-olato)dilead(II); see Shahverdizadeh et al. (2008). Both reports comment on lone-pair stereochemistry in this class of lead(II) compounds.

Experimental top

Lead nitrate (0.33 g, 1 mmol) and 2-methyl-8-hydroxyquinoline (0.32 g, 2 mmol) were loaded into a convection tube; the tube was filled with dry methanol and kept at 333 K. Crystals were collected from the side arm after 3 d.

Refinement top

Carbon-bound H atoms were placed in calculated positions (C—H 0.93 to 0.98 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2 to 1.5U(C). The methanol H atom was located in a difference Fourier map, and was refined with a distance restraint of O—H 0.84 (1) Å; its temperature factor was freely refined.

The crystal diffracted strongly owing to the extremely heavy metal atom; however, its presence introduced severe absorption problems that could not be corrected analytically as the crystal did not have regular faces. Although a sphere of reflections was measured, multi-scan treatment only marginally improved the quality. The final difference Fourier map had large peaks/deep holes near the Pb atom.

Computing details top

Data collection: APEX2 (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT (Bruker, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2009).

Figures top
[Figure 1] Fig. 1. Thermal ellipsoid plot (Barbour, 2001) of Pb2(NO3)2(CH4O)2(C10H8NO)2; ellipsoids are drawn at the 70% probability level and H atoms of arbitrary radius. The unlabelled atoms are related by 1-x, 2-y, 1-z.
[Figure 2] Fig. 2. Detail of the environment of the Pb atom. Symmetry codes: (i) 1 - x, 2 - y, 1 - z; (ii) 1 - x, 1 - y, 1 - z.
Bis(µ-2-methylquinolin-8-olato)- κ3N,O:O;κ3O:N,O- bis[(methanol-κO)(nitrato-κ2O,O')lead(II)] top
Crystal data top
[Pb2(C10H8NO)2(NO3)2(CH4O)2]Z = 1
Mr = 918.83F(000) = 428
Triclinic, P1Dx = 2.422 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.2579 (1) ÅCell parameters from 5067 reflections
b = 8.8052 (1) Åθ = 2.2–28.3°
c = 9.6765 (1) ŵ = 13.41 mm−1
α = 103.976 (1)°T = 100 K
β = 98.262 (1)°Block, yellow
γ = 108.190 (1)°0.20 × 0.15 × 0.05 mm
V = 630.07 (1) Å3
Data collection top
Bruker SMART APEX
diffractometer		2872 independent reflections
Radiation source: fine-focus sealed tube2754 reflections with I > 2σ(I)
graphiteRint = 0.019
ω scansθmax = 27.5°, θmin = 2.2°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		h = −10→10
Tmin = 0.175, Tmax = 0.554k = −11→11
5958 measured reflectionsl = −12→12
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.021Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.058H atoms treated by a mixture of independent and constrained refinement
S = 1.08 w = 1/[σ2(Fo2) + (0.0341P)2 + 1.3909P]
where P = (Fo2 + 2Fc2)/3
2872 reflections(Δ/σ)max = 0.001
174 parametersΔρmax = 1.41 e Å−3
1 restraintΔρmin = −2.12 e Å−3
Crystal data top
[Pb2(C10H8NO)2(NO3)2(CH4O)2]γ = 108.190 (1)°
Mr = 918.83V = 630.07 (1) Å3
Triclinic, P1Z = 1
a = 8.2579 (1) ÅMo Kα radiation
b = 8.8052 (1) ŵ = 13.41 mm−1
c = 9.6765 (1) ÅT = 100 K
α = 103.976 (1)°0.20 × 0.15 × 0.05 mm
β = 98.262 (1)°
Data collection top
Bruker SMART APEX
diffractometer		2872 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		2754 reflections with I > 2σ(I)
Tmin = 0.175, Tmax = 0.554Rint = 0.019
5958 measured reflectionsθmax = 27.5°
Refinement top
R[F2 > 2σ(F2)] = 0.021H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.058Δρmax = 1.41 e Å−3
S = 1.08Δρmin = −2.12 e Å−3
2872 reflectionsAbsolute structure: ?
174 parametersFlack parameter: ?
1 restraintRogers parameter: ?
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Pb10.403585 (18)0.747859 (17)0.434423 (15)0.01020 (6)
O10.5672 (4)0.9839 (4)0.3886 (3)0.0139 (6)
O20.7047 (5)0.7066 (4)0.4111 (4)0.0202 (7)
O30.6609 (5)0.6459 (5)0.6104 (4)0.0263 (8)
O40.8652 (5)0.5918 (5)0.5137 (4)0.0261 (8)
O50.0903 (4)0.7403 (4)0.3446 (4)0.0175 (6)
H50.006 (6)0.691 (7)0.376 (7)0.028 (17)*
N10.3858 (5)0.7002 (4)0.1665 (4)0.0114 (7)
N20.7441 (5)0.6484 (5)0.5124 (4)0.0146 (7)
C10.6165 (6)0.9696 (5)0.2615 (5)0.0123 (8)
C20.7547 (6)1.0900 (6)0.2411 (5)0.0169 (9)
H20.82191.18850.32030.020*
C30.7985 (6)1.0691 (6)0.1028 (5)0.0205 (9)
H30.89631.15290.09130.025*
C40.7024 (6)0.9308 (6)−0.0140 (5)0.0199 (9)
H40.73150.9203−0.10650.024*
C50.5592 (6)0.8028 (5)0.0032 (5)0.0141 (8)
C60.5180 (5)0.8209 (5)0.1415 (4)0.0115 (8)
C70.4520 (6)0.6577 (6)−0.1116 (5)0.0167 (9)
H70.47310.6417−0.20700.020*
C80.3161 (6)0.5389 (6)−0.0852 (5)0.0165 (9)
H80.24190.4414−0.16260.020*
C90.2879 (5)0.5628 (5)0.0573 (5)0.0121 (8)
C100.1480 (5)0.4306 (4)0.0890 (5)0.0160 (9)
H10A0.20070.36460.13580.024*
H10B0.06320.3567−0.00280.024*
H10C0.08790.48340.15490.024*
C110.0687 (6)0.8890 (4)0.3246 (5)0.0257 (11)
H11A0.09280.97170.42050.039*
H11B−0.05200.86160.27120.039*
H11C0.15040.93580.26840.039*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pb10.01050 (9)0.00980 (9)0.01087 (9)0.00331 (6)0.00258 (6)0.00458 (6)
O10.0147 (15)0.0116 (13)0.0134 (14)0.0013 (12)0.0045 (12)0.0043 (11)
O20.0235 (18)0.0268 (17)0.0212 (16)0.0148 (14)0.0101 (14)0.0161 (14)
O30.0270 (19)0.046 (2)0.0163 (16)0.0181 (17)0.0125 (14)0.0177 (16)
O40.0162 (17)0.0333 (19)0.039 (2)0.0136 (15)0.0108 (15)0.0205 (17)
O50.0129 (16)0.0205 (16)0.0227 (16)0.0073 (13)0.0072 (13)0.0098 (13)
N10.0117 (17)0.0121 (16)0.0120 (16)0.0041 (14)0.0028 (13)0.0067 (13)
N20.0126 (18)0.0164 (17)0.0159 (17)0.0051 (14)0.0036 (14)0.0068 (14)
C10.014 (2)0.0129 (18)0.0128 (19)0.0072 (16)0.0030 (16)0.0055 (16)
C20.017 (2)0.015 (2)0.017 (2)0.0048 (17)0.0033 (17)0.0049 (17)
C30.018 (2)0.019 (2)0.027 (2)0.0039 (18)0.0113 (19)0.0115 (19)
C40.021 (2)0.022 (2)0.022 (2)0.0080 (19)0.0124 (19)0.0110 (19)
C50.015 (2)0.017 (2)0.0138 (19)0.0064 (17)0.0063 (16)0.0096 (17)
C60.0095 (19)0.0148 (19)0.0134 (19)0.0071 (16)0.0022 (15)0.0067 (16)
C70.018 (2)0.021 (2)0.014 (2)0.0101 (18)0.0053 (17)0.0049 (17)
C80.014 (2)0.017 (2)0.017 (2)0.0061 (17)0.0020 (16)0.0030 (17)
C90.0088 (19)0.0137 (19)0.0140 (19)0.0047 (16)0.0011 (15)0.0045 (16)
C100.011 (2)0.0125 (19)0.020 (2)−0.0014 (16)0.0022 (16)0.0038 (16)
C110.022 (3)0.024 (2)0.036 (3)0.010 (2)0.008 (2)0.014 (2)
Geometric parameters (Å, °) top
Pb1—O12.281 (3)C2—C31.421 (6)
Pb1—O1i2.478 (3)C2—H20.9500
Pb1—N12.499 (3)C3—C41.365 (7)
Pb1—O52.583 (3)C3—H30.9500
Pb1—O22.655 (3)C4—C51.418 (6)
Pb1—O33.019 (4)C4—H40.9500
Pb1—O3ii3.248 (4)C5—C71.406 (6)
Pb1—O4ii3.320 (4)C5—C61.412 (6)
O1—C11.341 (5)C7—C81.378 (6)
O1—Pb1i2.478 (3)C7—H70.9500
O2—N21.259 (5)C8—C91.408 (6)
O3—N21.248 (5)C8—H80.9500
O4—N21.248 (5)C9—C101.490 (5)
O5—C111.430 (5)C10—H10A0.9800
O5—H50.838 (10)C10—H10B0.9800
N1—C91.326 (5)C10—H10C0.9800
N1—C61.362 (5)C11—H11A0.9800
C1—C21.369 (6)C11—H11B0.9800
C1—C61.433 (6)C11—H11C0.9800
O1—Pb1—O1i64.88 (12)O4—N2—O2119.8 (4)
O1—Pb1—N168.38 (11)O1—C1—C2123.2 (4)
O1i—Pb1—N1124.94 (11)O1—C1—C6117.8 (4)
O1—Pb1—O5100.85 (11)C2—C1—C6119.0 (4)
O1i—Pb1—O582.53 (10)C1—C2—C3120.6 (4)
N1—Pb1—O579.21 (11)C1—C2—H2119.7
O1—Pb1—O275.46 (11)C3—C2—H2119.7
O1i—Pb1—O2114.95 (11)C4—C3—C2121.2 (4)
N1—Pb1—O278.25 (11)C4—C3—H3119.4
O5—Pb1—O2156.87 (11)C2—C3—H3119.4
O1—Pb1—O3105.98 (11)C3—C4—C5119.8 (4)
O1i—Pb1—O3100.58 (10)C3—C4—H4120.1
N1—Pb1—O3119.16 (10)C5—C4—H4120.1
O5—Pb1—O3151.65 (10)C7—C5—C6117.2 (4)
O2—Pb1—O344.42 (9)C7—C5—C4123.5 (4)
O1—Pb1—O3ii144.45 (10)C6—C5—C4119.3 (4)
O1i—Pb1—O3ii144.84 (9)N1—C6—C5122.2 (4)
N1—Pb1—O3ii89.96 (10)N1—C6—C1117.7 (4)
O5—Pb1—O3ii102.30 (10)C5—C6—C1120.2 (4)
O2—Pb1—O3ii72.63 (10)C8—C7—C5119.8 (4)
O3—Pb1—O3ii59.42 (12)C8—C7—H7120.1
O1—Pb1—O4ii175.03 (10)C5—C7—H7120.1
O1i—Pb1—O4ii114.40 (10)C7—C8—C9119.6 (4)
N1—Pb1—O4ii109.62 (11)C7—C8—H8120.2
O5—Pb1—O4ii74.21 (9)C9—C8—H8120.2
O2—Pb1—O4ii108.83 (9)N1—C9—C8121.5 (4)
O3—Pb1—O4ii78.99 (10)N1—C9—C10118.5 (4)
O3ii—Pb1—O4ii38.47 (9)C8—C9—C10120.0 (4)
C1—O1—Pb1119.2 (2)C9—C10—H10A109.5
C1—O1—Pb1i124.9 (2)C9—C10—H10B109.5
Pb1—O1—Pb1i115.12 (12)H10A—C10—H10B109.5
N2—O2—Pb1106.1 (2)C9—C10—H10C109.5
N2—O3—Pb188.6 (2)H10A—C10—H10C109.5
C11—O5—Pb1118.7 (2)H10B—C10—H10C109.5
C11—O5—H5108 (4)O5—C11—H11A109.5
Pb1—O5—H5122 (4)O5—C11—H11B109.5
C9—N1—C6119.7 (4)H11A—C11—H11B109.5
C9—N1—Pb1127.4 (3)O5—C11—H11C109.5
C6—N1—Pb1111.6 (3)H11A—C11—H11C109.5
O3—N2—O4120.2 (4)H11B—C11—H11C109.5
O3—N2—O2119.9 (4)
O1i—Pb1—O1—C1−170.3 (4)O1—Pb1—N1—C617.3 (3)
N1—Pb1—O1—C1−20.3 (3)O1i—Pb1—N1—C650.8 (3)
O5—Pb1—O1—C1−93.9 (3)O5—Pb1—N1—C6123.7 (3)
O2—Pb1—O1—C162.6 (3)O2—Pb1—N1—C6−61.5 (3)
O3—Pb1—O1—C195.3 (3)O3—Pb1—N1—C6−79.4 (3)
O3ii—Pb1—O1—C136.0 (4)O3ii—Pb1—N1—C6−133.8 (3)
O4ii—Pb1—O1—C1−87.4 (12)O4ii—Pb1—N1—C6−167.5 (3)
O1i—Pb1—O1—Pb1i0.0Pb1—O3—N2—O4−170.3 (4)
N1—Pb1—O1—Pb1i150.03 (17)Pb1—O3—N2—O29.0 (4)
O5—Pb1—O1—Pb1i76.34 (14)Pb1—O2—N2—O3−10.7 (5)
O2—Pb1—O1—Pb1i−127.07 (15)Pb1—O2—N2—O4168.6 (3)
O3—Pb1—O1—Pb1i−94.40 (14)Pb1—O1—C1—C2−159.2 (3)
O3ii—Pb1—O1—Pb1i−153.76 (12)Pb1i—O1—C1—C231.5 (6)
O4ii—Pb1—O1—Pb1i82.9 (12)Pb1—O1—C1—C621.2 (5)
O1—Pb1—O2—N2137.6 (3)Pb1i—O1—C1—C6−148.1 (3)
O1i—Pb1—O2—N284.7 (3)O1—C1—C2—C3−178.8 (4)
N1—Pb1—O2—N2−152.0 (3)C6—C1—C2—C30.8 (7)
O5—Pb1—O2—N2−138.9 (3)C1—C2—C3—C41.4 (7)
O3—Pb1—O2—N25.4 (2)C2—C3—C4—C5−1.8 (7)
O3ii—Pb1—O2—N2−58.3 (3)C3—C4—C5—C7179.0 (5)
O4ii—Pb1—O2—N2−45.1 (3)C3—C4—C5—C60.1 (7)
O1—Pb1—O3—N2−53.6 (3)C9—N1—C6—C5−2.1 (6)
O1i—Pb1—O3—N2−120.3 (3)Pb1—N1—C6—C5166.0 (3)
N1—Pb1—O3—N220.2 (3)C9—N1—C6—C1178.0 (4)
O5—Pb1—O3—N2145.9 (3)Pb1—N1—C6—C1−13.9 (4)
O2—Pb1—O3—N2−5.3 (2)C7—C5—C6—N13.2 (6)
O3ii—Pb1—O3—N290.9 (3)C4—C5—C6—N1−177.8 (4)
O4ii—Pb1—O3—N2126.7 (3)C7—C5—C6—C1−176.9 (4)
O1—Pb1—O5—C11−16.8 (3)C4—C5—C6—C12.0 (6)
O1i—Pb1—O5—C1145.7 (3)O1—C1—C6—N1−3.0 (6)
N1—Pb1—O5—C11−82.1 (3)C2—C1—C6—N1177.4 (4)
O2—Pb1—O5—C11−95.2 (4)O1—C1—C6—C5177.1 (4)
O3—Pb1—O5—C11144.2 (3)C2—C1—C6—C5−2.5 (6)
O3ii—Pb1—O5—C11−169.7 (3)C6—C5—C7—C8−1.5 (6)
O4ii—Pb1—O5—C11163.8 (3)C4—C5—C7—C8179.6 (4)
O1—Pb1—N1—C9−175.7 (4)C5—C7—C8—C9−1.0 (7)
O1i—Pb1—N1—C9−142.2 (3)C6—N1—C9—C8−0.7 (6)
O5—Pb1—N1—C9−69.4 (3)Pb1—N1—C9—C8−166.7 (3)
O2—Pb1—N1—C9105.4 (4)C6—N1—C9—C10178.1 (4)
O3—Pb1—N1—C987.5 (4)Pb1—N1—C9—C1012.1 (5)
O3ii—Pb1—N1—C933.2 (4)C7—C8—C9—N12.3 (7)
O4ii—Pb1—N1—C9−0.6 (4)C7—C8—C9—C10−176.5 (4)
Symmetry codes: (i) −x+1, −y+2, −z+1; (ii) −x+1, −y+1, −z+1.
Hydrogen-bond geometry (Å, °) top
D—H···AD—HH···AD···AD—H···A
O5—H5···O4iii0.84 (1)2.06 (2)2.869 (5)161 (6)
Symmetry codes: (iii) x−1, y, z.
Acknowledgements top

The authors thank Shahid Beheshti University and the University of Malaya for supporting this study.

references
References top

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