Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diiso­propyl-1,2,4-triazolato-κ2N1:N2)trigold(I) under high pressure

Woodall, C.H.; Christensen, J.; Skelton, J.M.; Hatcher, L.E.; Parlett, A.; Raithby, P.R.; Walsh, A.; Parker, S.C.; Beavers, C.M.; Teat, S.J.; Intissar, M.; Reber, C.; Allan, D.R.

doi:10.1107/S2052252516013129

Figure 9
(a) Packing diagrams showing the molecular overlap between one layer (blue) and the layer above (orange) in Form-I (left) and Form-II (right). Shaded areas indicate those which are not near the isopropyl groups of the molecules, and thus areas where atoms are likely to have the most freedom to change position. (b) Comparison of the ambient and 2.88 GPa structures of Form-II. Note the distortion of the triazole ring and the associated isopropyl groups on the closest triazole.

IUCrJ

Volume 3| Part 5| September 2016| Pages 367-376

ISSN: 2052-2525

doi:10.1107/S2052252516013129

CHEMISTRY | CRYSTENG

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