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Figure 11
(a) Near-edge X-ray excitation spectra of [(TPP)Fe]2O recorded by tuning the crystal analyzer to the maximum intensity of either the [K_{\beta1-3}] fluorescence line or its [K_{\beta'}] satellite. Note the different intensities and location of the pre-edge structure. The excitation spectrum obtained by recording the total fluorescence yield is also shown for reference. (b) High-resolution emission spectrum of [(TPP)Fe]2O in the energy range of the [K_{\beta1-3}] fluorescence line. Note the presence of the spin-polarized [K_{\beta'}] satellite.

Journal logoJOURNAL OF
SYNCHROTRON
RADIATION
ISSN: 1600-5775
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