Tris-amidoximate uranyl complexes via η2 binding mode coordinated in aqueous solution shown by X-ray absorption spectroscopy and density functional theory methods

Zhang, L.; Qie, M.; Su, J.; Zhang, S.; Zhou, J.; Li, J.; Wang, Y.; Yang, S.; Wang, S.; Li, J.; Wu, G.; Wang, J.-Q.

doi:10.1107/S160057751800067X

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Figure 1
Three possible binding motifs between the amidoxime ligand and UO₂²⁺ cation. (a) Monodentate binding to the oxygen atom of the oxime ligand, (b) bidentate chelation involving the oxime oxygen atom and amide nitrogen atom, and (c) η² binding with the N—O bond.

JOURNAL OF
SYNCHROTRON
RADIATION

ISSN: 1600-5775

Volume 25| Part 2| March 2018| Pages 514-522

https://doi.org/10.1107/S160057751800067X

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