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October 1995 issue
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Cover illustration: (Methyldiphenylphosphine)(trimethylsiloxy)gold(I), see Bauer, Schier & Schmidbauer, pages 2030-2032. Displacement ellipsoids are at the 50% probability level.
inorganic compounds
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The structure of the low-temperature form of LiGaSi2O6 has been determined from diffractometer data obtained at 273K. The structure is similar to that of pigeonite.
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TaOI2 contains sheets of distorted TaO2I4 octahedra which share trans I–I edges and trans O corners. . The Ta atoms are displaced from the centres of the octahedra forming Ta⋯Ta pairs.
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The simple orthoborate BaNaBO3 contains BaO9 polyhedra and chains of face-sharing Na-centered octahedra which are bridged by BO3 groups.
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Sm2Ta3S2O8 is isostructural with La2Ta3S2O8. The structure comprises alternate layers of Sm tricapped trigonal prisms and Ta octahedra.
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The structure of Cd4GeS6 comprises GeS4 and CdS4 tetrahedra. Each vertex of a GeS4 tetrahedron is shared with two CdS4 tetrahedra.
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Barium orthoperiodate adopts a structure which consists of Ba2+ and (H3IO6)2− ions. The H atom is positionally disordered and the IO6 octahedra are linked by O-H⋯O hydrogen bonds to form a three-dimensional network.
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KYP4O12 is isostructural with RbNdP4O12. The structure contains centrosymmetric P4O12 rings and YO8 polyhedra.
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Cs1.33Li0.67Si2O5 exhibits a novel sheet topology with four-eight-twelve-membered rings. The sheets are interconnected by Li atoms, threefold coordinated by non-bridging O atoms, forming tunnels in which the Cs atoms are located.
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Lanthanum strontium tetraoxogallate adopts a K2NiF4-type structure. SrII and LaIII are distributed statistically on one site and GaIII has a stretched octahedral coordination geometry.
metal-organic compounds
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organic compounds
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