K₃Nb₃Ti₂O₁₁F₄

The asymmetric unit of K₃Nb₃Ti₂O₁₁F₄ contains two STX₆ octahedra where X = O, F or OF (= 1/4 F + 3/4 O) and ST = (3/5 Nb + 2/5 Ti). The K-atom environment is similar to that in ferroelectric phases, but the weak distortion of the octahedra and the occupation of their centres by Nb⁵⁺ and Ti⁴⁺ cations result in paraelectric behaviour.

Fe₂Al₃Si₃

The structure of Fe₂Al₃Si₃ consists of a compact three-dimensional arrangement of FeM₁₀ and FeM₉ iron-centred polyhedra (M = Al or Si). Si has 9 to 11 neighbours and Al 11 or 12 neighbours at distances less than 3.1Å.

Rhombohedral Ce₂Ni₅Zn₂ and Hexagonal CeNi₂Zn: the First Ternary Compounds from the Ce–Ni–Zn System

Dicerium pentanickel dizinc, Ce₂Ni₅Zn₂, crystallizes as a new ordered substitution variant of the Er₂Co₇ structure type, and cerium dinickel zinc, CeNi₂Zn, crystallizes with the YRh₂Si structure type.

An Acid Terbium(III) Cerium(IV) Sulfate Hydrate, H₉Tb₇Ce₆(SO₄)₂₇.72.2H₂O

H₉Tb₇Ce₆(SO₄)₂₇.72.2H₂O is isomorphous with the Nd compound reported previously, but is less stable and features unexpectedly long Tb-O distances.

Monoclinic Mg₂B₂O₅

The structure of Mg₂B₂O₅ is built from tetrameric Mg₄O₁₈ chains of trans-edge-sharing Mg octahedra held together by B atoms which form B₂O₅ groups.

Tripraseodymium Chloride Bis(orthosilicate), Pr₃(SiO₄)₂Cl

Pr₃(SiO₄)₂Cl is isostructural with La₃(SiO₄)₂Cl. The structure comprises layers of Pr(2)(SiO₄)₄Cl₂ octahedra separated in the a direction by Pr(1) cations occupying Pr(1)O₇Cl polyhedral sites.

Potassium Vanadium Selenite, K(VO₂)₃(SeO₃)₂

K(VO₂)₃(SeO₃)₂ is a new layered phase based on hexagonal tungsten-oxide-like sheets of vertex-sharing VO₆ octahedra. It is isostructural with NH₄(VO₂)₃(SeO₃)₂.

Low-Density Form of NaGaSi₂O₆

The structure of NaGaSi₂O₆ is similar to that of jadeite (NaAlSi₂O₆). Comparison of the structure of NaGaSi₂O₆ with those of eleven other NaM³⁺Si₂O₆ pyroxenes suggests that the octahedrally coordinated Ga³⁺ ions exist in two different electronic states.

Redetermination of 1,5-Di­chloro­cyclo­tetra(azathiene) at 120 K

The structure of S₄N₄Cl₂ has been redetermined at 120K. The results are compared with those of an earlier study using photographic data obtained at ambient temperature.

[Bis(3-amino­propyl)phenylphosphine-N,P]tetra­carbonylmolybdenum(0)

Penta­carbonyl(di­fluoro­methyl isocyanide)chromium at 128 K

Tris(O,O'-di­cyclo­hexyl di­thiophosphato-S,S')chromium(III)

A cis-Oxo[di­phenylhydrazido(2–)]molybdenum Complex: (Et₃NH)₂[MoO(NNPh₂)(SC₆H₄CO₂)₂]

(N,N-Di­methylthiocarbamoylthio­acetato)tri­phenyltin

Bis(2-methoxycarbonylethyl)bis­(quinolin-8-olato-N,O)tin

Intramolecular Coordination of the Di­methylamino Group in a Rhodium–Oxalate Complex with the 1-[2-(Di­methylamino)ethyl]-2,3,4,5-tetra­methylcyclo­pentadienyl Ligand

Non-Coordination of the Di­methylamino Group in a Dinuclear Molybdenum Complex with the 1-[2-(Di­methylamino)ethyl]-2,3,4,5-tetra­methylcyclo­pentadienyl Ligand

(η⁵-Cyclo­pentadienyl)oxo(peroxo-O,O')(tri­methylsilylmethyl)tungsten and the Related (η⁵-Penta­methylcyclo­pentadienyl)oxo(peroxo-O,O')(tri­methylsilylmethyl)tungsten-Tetra­cyano­ethylene (2/1) Complex

A Trigonal Prismatic Cluster Compound of Tin and Lithium: Structure of [{Sn(OCMe₂C₆H₄)₂}₃Li₂O].2HOCMe₂Ph

Three α,β-Unsaturated (Carbene)penta­carbonylchromium Complexes

A Cationic Rhenium–Platinum Complex: fac-Tri­carbonylrhenium-bis­[μ-methylaminobis(di­fluorophosphine)]-tri­phenylphosphineplatinum Tri­fluoro­methane­sulfonate

Tris(1,2-di­methoxyethane)lithium 1,1,4,4-Tetra­phenyl-1,3-butadiene Radical Anion

mer,trans-[Bis(2-di­phenylphosphino­ethyl)(n-propyl)amine-N,P,P']di­chloro(tri­phenylphosphine)ruthenium(II) 0.5-Di­chloro­methane Solvate

[Ru(ND₃)₆](SCN)₃ at 20 K by Time-of-Flight Neutron Diffraction

{1-[(2-Hydroxybenzyl­idene)amino­methyl]-naphthalen-2-olato(2–)-N,O,O'}(piperidine-N)nickel(II)

The Helical Packing of a Chiral Alkyl Cobaloxime in the Solid State

Tetra­ethylammonium (2-Thioxo-1,3-di­thiole-4,5-di­thiolato-S⁴,S⁵)tri­phenylphosphinecopper(I)

Europium(III) Tris[di­cyanoargentate(I)] Trihydrate, Eu[Ag(CN)₂]₃.3H₂O

Distant Copper–Copper Interactions in a Metal-Organic Compound in the Solid State: Hexa­kis­[(μ₃-4,6-di­methylpyrimidine-2-thiolato-N:S:S)copper(I)] Dihydrate

Bis(4,6-di­amino-2-methylthiopyrimidinium) Tetra­bromozincate(II)

Bis(4-nitroanilinium) Tetra­chlorocadmate

Di­methylammonium Penta­chlorobismuthate(III)

Molecular Adducts of Inorganic Salts. III. Non-Centrosymmetric 3Pb(ReO₄)₂.2tu.2H₂O (tu = Thiourea)

Tetra­kis­(N,N'-di­phenylbenzamidinato)dicopper(II) Di­chloro­methane Solvate

Bis[(2-hydroxyethyl)di­methylammonium] Tetra­kis­(μ-benzoato-O:O')bis­[(benzoato-O)cuprate(II)]

Tri­benzyltin Acetate, a Redetermination

Bis(μ-tri­fluoro­acetato-O,O')bis­{[3-chloro-6-methyl-2-(N-methyl-N-nitroso­amino)phenyl-C,N^N=O]palladium(II)}

(1,3-Di­methyl-2,6-dioxo-2,3,6,7-tetra­hydro-1H-purin-7-yl)(di­methylphenylphosphine)gold(I)

3,5-Di­methoxycarbonyl-2,6-di­methyl-4-(2-nitroso­phenyl)pyridine and Di­chlorobis[3,5-di­methoxycarbonyl-2,6-di­methyl-4-(2-nitro­phenyl)pyridine]copper(II)

[4-Chloro-3-(2-nitro­phenylthio)butyl]tri­phenylstannane

Bis(1,1'-di­methyl-5-nitro-2,2'-biimidazol-3'-ium) trans-Tetra­chlorodi­methylstannate

Bromotri­phenyltin–Tri­phenylphosphine Oxide (1/1)

exo-π-(Benzonorbornadiene)tri­carbonylchromium

8,9-Di­methoxybenzo[b]carbazole

Acetyl-L-carnitine Hydrochloride

Dimeric 3-Vinylindoles as Potential Antitumor Active Compounds: 1,1,3,4-Tetra­methyl-3-(1-methyl-1H-indol-3-yl)-1,2,3,4-tetra­hydro­cyclo­penta[b]indole and 1,1,3-Tri­methyl-4-phenylsulfonyl-3-(1-phenylsulfonyl-1H-indol-3-yl)-1,2,3,4-tetra­hydro­cyclo­penta[b]indole

A Thyrotropin-Releasing Hormone Analogue: pGlu-Phe-D-Pro-Ψ[CN₄]-NMe at 293 and 107K

trans-3-(p-Chloro­phenylthio)-1,4,6-tri­methylpiperazine-2,5-dione

3-Hy­droxy-2,6-di­nitroaceto­phenone: an Unusual Substitution Pattern Resulting from Nitration of 3-Hydroxyaceto­phenone

Homochiral Methyl (S)-2-Benzoyl­oxy-4-bromo-4-methylpentanoate

4-(4-Chloroanilino­methyl)-6-methylcoumarin

Structural Investigation of Di­hydrooxazinones

cis-1,5-Di­amino-2,4,6,8-tetra­azabi­cyclo[3.3.0]octane-3,7-dione

A Precursor to Highly Unsaturated Cyclophanes: 7,19,28-Tri­thia­tetra­cyclo[11.11.7.1^3,23.1^11,15]tritriaconta-1,3(32),11(33),12,14,23-hexa­ene-4,9,16,22,25,30-hexayne

Novel 2- and 5-Azido-N-(di­phenylcarbamoyl)proline Methyl Esters. Examples of a Novel Proline Oxidation

N^α-tert-Butoxycarbonyl-N^τ-benzylhistidine p-Nitro­benzyl Ester

N-(5-Hydroxysalicylidène)-2,4,6-triméthylaniline

4,5-Bis(4-bromo­benzylthio)-1,3-di­thiole-2-thione

7-[3-(Di­benzylamino)-2-hydroxypropyl]-8-(furfurylamino)theophylline

8-Benzylamino-7-{2-hy­droxy-3-[4-(2-hydroxyethyl)-1-piperazinyl]propyl}theophylline

Anti-Inflammatory Drugs. II. Salt of 2-(2,6-Di­chloro­phenylamino)phenylacetic Acid with Di­ethanolamine

(±)-3-Oxo-trans-2-phenylcyclo­hexane­acetic Acid: Structure and Hydrogen-Bonding Pattern of a Partially Hydrated δ-Keto Acid

cis-2-Oxo-1,3-cyclo­hexanedipropionic Acid: Structure and Hydrogen-Bonding Pattern of a δ-Keto 1,9-Diacid

3-(4-Bromo­benzyl)-5-(4-fluoro­benzyl­idene)imidazolidine-2,4-dione

8,16-Methano-16H-di­naphtho[2,1-d:1',2'-g][1,3]dioxocine-2,14-diol

1-(p-Carbamoylphenyl)-3,3-di­methyltriazene, an Antitumour Agent

Ondansetron Hydrochloride: a Competitive Serotonin 5-HT₃ Receptor Blocker

Molecular Co-Crystals of Carboxylic Acids. 22. The Adducts of Pyrazine-2,3-di­carboxylic Acid with 2-Amino­benzoic Acid (1:2) and 3-Amino­benzoic Acid (1:1 Dihydrate)

Novel Six- and Eight-Membered Heterocycles. A Tri­thiadi­aza­phosphorinane and a Penta­thiadi­aza­phosphocine

5-Acet­oxy-6-(1,1-di­methyl-2-propenyl)-2H-furo[2,3-h][1]benzo­pyran-2-one

Tri­cyclo[8.2.1.0^2,9]trideca-5,11-dien-3-ol

N-Benzoyl-2-phenyldeca­hydroquinolin-4-one, C₂₂H₂₃NO₂

o-Phenylenedi­ammonium Bis(hydrogensulfide)

Muscarinic Antagonist: 8,8-Di­methyl-3',3'-di­phenylspiro(8-azoniabi­cyclo[3.2.1]octane-3,2'-1',3'-dioxolane)-4'-one Iodide

(E)- and (Z)-Enamine Dewar Pyrimidinones

2-Nitro­benzenesulfenyl Thio­cyanate

3-Methylphthalic Anhydride

Ethyl 3-(3-Bromo-4-hydroxyphenyl)-2(E)-(hydroxyimino)propanoate

1,3-Di­phenylpropan-1-one

2β,3β-Ep­oxy-α-trans-himachalene and 2β,3β,11α,15α-Di­epoxy-trans-himachalane Derivatives

Six Substituted Thiazolidine-2-thiones

4-n-Heptylbenzoic Acid

Redetermination of the Structures of 1,4,7-Trioxa-10,13-di­thia­cyclo­penta­decane and 1,4,7,10-Tetraoxa-13,16-di­thia­cyclo­octa­decane

Diflufenican, N-(2,4-Di­fluoro­phenyl)-2-[3-(tri­fluoro­methyl)phen­oxy]-3-pyridinecarboxamide

Tetra­hydro-6-methyl-1H,3H-thieno[3,4-b]pyrrol-2-one, an Analogue of Biotin

1,1-Di­phenyl-3-propyn-1-ol

Absolute Configuration of Mutilin, 5-Acetylmutilin and 5-Bromo­acetylmutilin

3-Nitrodibenzo­furan and 3-Iododibenzo­furan

Hexyltris(2,4,6-tri­methoxyphenyl)phosphonium Iodide

Photochemistry of Di­methyl 1,8-Di­chloro-9,10-di­hydro-9,10-ethenoanthracene-11,12-di­carboxylate

Tri­cyclo[22.2.2.2^11,14]triaconta-11,13,24,26,27,29-hexa­ene-6,19-dione

3,3,18,18-Tetra­methyl-1,5,16,20-tetraoxadi­spiro[5.8.5.8]octa­cosane

Di­methyl 1-Chloro-4b,8b,8c,8d-tetra­hydrodibenzo[a,f]cyclopropa[cd]pentalene-8c,8d-di­carboxylate

Di­methyl 4b,8b,8c,8d-Tetra­hydrodibenzo[a,f]cyclopropa[cd]pentalene-8b-carboxylate-8c-thiono­carboxylate and the Corresponding 8c-Thiolo­carboxylate

Styrylboronic Acid

5-Iodocytosine

(Z)-2,3-Bis(3,4-di­methoxyphenyl)propenoic Acid

2-[2-(3,4-Di­chloro­phenyl)vinyl]benzo[d]thiazole

trans-1-Cyano-2-phenylcyclo­propanecarboxamide

trans-2-Fluoro­cyclo­hexyl p-Toluene­sulfonate and trans-2-Fluoro­cyclo­heptyl p-Toluene­sulfonate

N-Acetyl-3,6-di-tert-butyl-2-(3,6-di-tert-butyl-3H-azepin-2-yl)-2,3-di­hydro-1H-azepine

Anomalin. A Di­hydro­pyranocoumarin Derivative from the Plant Lingusticum elatum

7-Hy­droxy-3-phenylcoumarin, C₁₅H₁₀O₃

Unusual Chlorination During an Epoxidation Reaction of an Etheno­cyclopropa[b]naphthalene Derivative

2-Cyano-2-phenylsparteine

L-Glycyl-L-Glutamine Monohydrate

Xanthyletin

N-Methyl-1,1,4-tri­phenyl-1,2-di­hydro­naphthalene-2,3-dicarboximide

Methyl 2,2¹-Anhydro-4,6-O-benzyl­idene-3-de­oxy-3-C-[(R)-2-hydroxyethyl]-α-D-allo-pyranoside at 173 K. Addendum

(Aceto­nitrile)-trans-di­chloro-mer-tris­[(di­methyl)phenylphosphine]osmium(II); the kinetically controlled electrogenerated isomer. Erratum

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