In_1.08Gd_0.92Ge₂O₇: a new member of the thortveitite family

The novel title indium gadolinium germanate, In_1.08Gd_0.92Ge₂O₇, belongs to the thortveitite family, with the single octahedral site occupied by both In and Gd atoms. This compound showed a remarkable photoluminescence effect when it was irradiated both with the X-ray beam during the X-ray diffraction measurements and with the α beam during the Rutherford back-scattering spectrometry experiments.

Tetrastrontium dimanganese copper nonaoxide, Sr₄Mn₂CuO₉

The structure of Sr₄Mn₂CuO₉ consists of chains of face-sharing polyhedra, in a sequence of two [MnO₆] octahedra and one trigonal prism, with Cu atoms disordered over its square faces. The chains are held together by Sr atoms.

Dipotassium tris­trontium dimanganese tris­(diphosphate)

The title mixed trimetallic diphosphate exists as a solid matrix of Sr₃Mn₂(P₂O₇)₃ stoichiometry in which are found tunnels of dimensions 5.43 × 9.28 Å containing K⁺ ions. The presence of several cations differing in size in the solid matrix leads to the formation of large tunnels and potential conductivity.

[Ni(H₂O)₆]₂[Na(H₂O)₃]₂[V₁₀O₂₈]·4H₂O, bis­(nickel hexahydrate) bis­(sodium trihydrate) decavanadate tetrahydrate

The title compound consists of [V₁₀O₂₈]⁶⁻ anions, trimeric {[Na(H₂O)₃][Ni(H₂O)₆][Na(H₂O)₃]}⁴⁺ cations, [Ni(H₂O)₆]²⁺ cations and water molecules of crystallization. The connection of the trimeric cations and the decavanadate anions results in a one-dimensional polycation–polyanion hybrid polymer. The polymers are bound together via hydrogen bonds.

Polymeric di­aqua(μ₂-2,2′-bipyrimidinyl-κ⁴N¹,N^1′:N³,N^3′)-di-μ₃-hy­droxy-bis­(μ₅-benzene-1,3,5-tri­carboxylato-κ⁵O¹:O²:O³:O³:O⁵)tetracobalt(II) dihydrate

Cu₂(dien)₂Ag₅(CN)₉ containing the one-dimensional polymeric cation [Cu(dien)Ag(CN)₂]_nⁿ⁺ and the unusual [Ag₂(CN)₃]⁻ anion (dien is di­ethylenetri­amine)

The calcium-binding properties of pamidronate, a bone-resorption inhibitor

Bis(μ-acetato-κ³O,O′:O′)bis­[bis­(acetato-κ²O,O′)di­aquadysprosium(III)] tetrahydrate

Li⁺ cation coordination in [Li₂(CF₃SO₃)₂(diglyme)] and [Li₃(C₂F₃O₂)₃(diglyme)]

Propane-1,2-di­ammonium tetra­fluoroberyllate

catena-Poly­[[[aqua(2-methyl-4-oxo-4H-pyran-3-olato-κO³,O⁴)copper(II)]-μ-chloro] monohydrate]

A novel titanium–μ-O–zirconium complex: bis­(μ-methyliminodi­ethanolato-1κ³O,N,O′;1:2κ²O)(methyliminodi­ethanolato-2κ³O,N,O′)di­propanolato-1κO,2κO-titanium(IV)zirconium(IV)

5-n-Butylpyridine-2-carboxylate–copper(II) and –iron(III) complexes

Transition metal complexes with thiosemicarbazide-based ligands. XLIV. Aqua(3-hy­droxy-5-hydroxymethyl-2-methylpyridine-4-carboxaldehyde 3-methyliso­thiosemicarbazone-κ³O,N¹,N⁴)nitratocopper(II) nitrate

A neodymium(III)–ammonium complex involving oxalate and carbonate ligands: (NH₄)₂[Nd₂(C₂O₄)₃(CO₃)(H₂O)]·H₂O

Single crystals of a new open-framework polymeric complex containing neodymium(III) ions and oxalate and carbonate ligands have been synthesized hydrothermally at 423 K. The three-dimensional structure presents tunnels where ammonium ions and a water molecule are located.

trans-Bis(iso­thio­cyanato-κN)bis­(methanol-κO)bis­[2,4,6-tri(4-pyridyl)-1,3,5-triazine-κN²]manganese(II)

Low-dimensional compounds containing cyano groups. IV. Bis(2,2′-bi­pyridine-κ²N,N¹)(dicyanamido-κN′)copper(II) perchlorate and μ-dicyanamido-κ²N¹:N⁵-bis­[bis­(2,2′-bi­pyridine-κ²N,N′)copper(II)] triperchlorate ethanol hemisolvate, complexes with unusual dicyanamide coordination

(–)-(1′S,4aS,7R,8aR)-4a-Ethyl-7-hy­droxy-1-(1′-phenylethyl)perhydroquinolinium bromide

The regioisomeric 1H(2H)-pyrazolo[3,4-d]pyrimidine N¹- and N²-(2′-de­oxy-β-D-ribo­furanosides)

Fleroxacin hydrochloride hydrate

3β-(1-Allyl-1-pyrrolidinio)-16-(2-pyridylmethylene)androst-5-en-17β-ol bromide hemihydrate

The 2:1 complex of maleic acid and 1,4-di­azabi­cyclo[2.2.2]octane: hydrogen-bonded sheets linked by C–H⋯O hydrogen bonds

2,6-Di­iodo­pyridine

2-Amino­anilinium phosphite

6-Acetonyldi­hydro­avicine

N,N′-Di­benzyldi­thiooxamide

1,3,5,7-Tetraselena-2,4,6,8(2,5)-tetra­thiophena­octaphane

(R)-Mandelic acid (S)-alanine hemihydrate

The low-temperature phase transition of 9-methylfluoren-9-ol: comparison of the crystal structures at 100 and 200 K

2-Methyl-1,4,5-tri­phenyl-1H-imidazole

N-tert-Butyl-N′-(2-cyclo­hexylamino-5-nitro­benzene­sulfonyl)urea, BM531, a dual-acting agent for thromboxane receptor antagonism and thromboxane synthase inhibition

(E)-(4-Hydroxyphenyl)(4-nitrophenyl)diazene, (E)-(4-meth­oxyphenyl)(4-nitro­phenyl)diazene and (E)-[4-(6-bromo­hexyl­oxy)phenyl](4-cyano­phenyl)diazene

Tris[(1-methylimidazol-2-yl)methyl]amine–boric acid (1/1)

A zwitterionic viologen di­sulfonate–hydro­quinone charge-transfer crystal: 2,2′-(4,4′-bipyridinium-1,1′-diyl)di(ethane­sulfonate)–hydro­quinone (1/2)

A 1:1 molecular complex of bis­(4-amino­phenyl) di­sulfide and 4-amino­thiophenol