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January 2010 issue
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Cover illustration: A single [ZnBO3]n layer in CdZn2KB2O6F, viewed along the c axis, showing the BO3 (smaller) and ZnO3 (larger) triangles connected to each other via shared corners. See Zhang, Jiao, Shen, Shen & Wang [Acta Cryst. (2010), C66, i1-i3].
international union of crystallography
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inorganic compounds
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CdZn2KB2O6F consists of (001) layers with corner-sharing ZnO3F tetrahedra and BO3 triangles. The Cd atoms occupy six-coordinated interlayer sites and the K atoms are located in interlayer channels.
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The cation disorder in the crystal structure of the mixed valent lithium/cobalt(II/III) phosphate Li4.03Co1.97(P2O7)2 is elucidated both from the analysis of the structural data and by means of the charge-distribution method which validate the proposed structural model.
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KBa7Mg2B14O28F5, with a nominal 7:1 composition of BaB2O4 to KMg2F5, is formed by isolated B7O14 groups and double perovskite units.
metal-organic compounds
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organic compounds
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