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February 2013 issue
inorganic compounds
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Cu2ScZr(PO4)3 adopts a NASICON-type structure. Changes in the site-occupancy factors of the nonframework Cu+ cations suggest increased mobility around a circular orbit close to the M1 site at room temperature, but no movement into or out of the M2 site.
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Racemically twinned crystals of the title compound were studied. The CrVIO4 tetrahedron is disordered on a threefold axis, while two CrVO4 tetrahedra are ordered. Ca atoms are coordinated by six (on a threefold axis), seven and eight O atoms.
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Single crystals of the new layered title compound, barium di-μ-hydroxido-di-μ-vanadato-tricobaltate(II), were prepared under hydrothermal conditions. The octahedral Co3O6(OH)2 Kagomé layers alternate with barium vanadate heteropolyhedral layers along the c axis.
metal-organic compounds
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organic compounds
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