Ternary K₂Zn₅As₄-type pnictides Rb₂Cd₅As₄ and Rb₂Zn₅Sb₄, and the solid solution Rb₂Cd₅(As,Sb)₄

Rb₂Cd₅As₄ and Rb₂Zn₅Sb₄ are new ternary pnictides with a complex orthorhombic structure. In the absence of homoatomic interactions, the chemical bonding can be understood as (Rb⁺)₂(Cd²⁺)₅(As³⁻)₄ and (Rb⁺)₂(Zn²⁺)₅(Sb³⁻)₄, respectively, following the Zintl concept.

A new oxyfluoro­tellurate(IV), InTe₂O₅F

The crystal structure of a new oxyfluoro­tellurate(IV) compound, InTe₂O₅F, consists of a three-dimensional framework formed by InO₄F₂ o­cta­hedra linked through the F atoms, giving rise to helical chains inter­connected via Te₂O₅ units.

A square-pyramidal copper(II) complex with strong intra­molecular hydrogen bonds: di­aqua­(N,N′-di­methyl­formamide-κO)bis­[2-(di­phenyl­phosphor­yl)benzoato-κO]copper(II)

A new three-dimensional silver(I) coordination framework with a diamondoid topology constructed from 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarb­oxy­lic acid

Binuclear and chain-structure zinc(II) complexes constructed from 3,4-di­meth­oxy-trans-cinnamic acid and N-donor coligands 4-(1H-pyrazol-3-yl)pyridine and 4,4′-bi­pyridine

Two one-dimensional coordination polymers generated from a new benzimidazole bridging ligand and CdX₂ (X = Br and I)

The correct assignment of stereochemistry in di-μ-di­chlorido-bis­{bis­[2-(5-benzyl­sulfonyl)-3-fluoro-2-(pyridin-2-yl)phenyl-κ²N,C¹]iridium(III)} toluene monosolvate

A three-dimensional manganese(II) metal–organic framework based on 5-meth­oxy­benzene-1,3-di­carb­oxy­lic acid and exhibiting a pts net

A one-dimensional zinc(II) coordination polymer incorporating [1,1′-bi­phen­yl]-4,4′-di­carboxyl­ate and N,N′-bis­(pyridin-3-ylmeth­yl)-[1,1′-bi­phen­yl]-4,4′-dicarboxamide ligands

A one-dimensional ABX₃-type coordination polymer: catena-poly[benzyl­tri­methyl­ammonium [tri-μ-chlorido-cadmium(II)]]

Poly[bis­(μ-5-iodo­isophthal­ato)(methanol)dilead(II)] exhibiting a novel centrosymmetric rhombus-shaped I₄ unit

X-ray and synchrotron diffraction studies of 2-(pyridin-2-yl)-1,10-phenanthroline in the role of ligand for two copper polymorphs or hydrogen bonded with 2,2,6,6-tetra­methyl-4-oxopiperidinium hexa­fluoro­phosphate

A clothes-peg-shaped binuclear trans-bis­(2-amino­tropon­ato)­palladium(II) complex bearing penta­methyl­ene spacers

catena-Poly[tris­(μ₃-acetyl­aceton­ato)nickelate(II)sodium(I)]

A cocrystal of two Mo^VI complexes bearing different diastereomers of the 2,4-di-tert-butyl-6-{[(1-oxido-1-phenyl­propan-2-yl)(meth­yl)amino]­meth­yl}phenolate ligand derived from (+)-ephedrine

A simple and safe method for the preparation of bis­[2-(2H-tetra­zol-5-yl)pyridinium] tetra­chloridozincate(II)

Semi-maleate salts of L- and DL-serin­ium: the first example of chiral and racemic serinium salts with the same composition and stoichiometry

Isomeric 3- and 4-chloro-N-[1-(1H-pyrrol-2-yl)ethyl­idene]aniline

Pentane-1,5-diaminium dibromide

Bi­phenyl- and phenylnaphthalenyl-substituted 1H-imid­azole-4,5-dicarbo­nitrile catalysts for the coupling reaction of nucleoside methyl phos­phon­amidites

Hydrogen bonding in two ammonium salts of 5-sulfosalicylic acid: ammonium 3-carb­oxy-4-hy­droxy­benzene­sulfonate monohydrate and tri­ammonium 3-carb­oxy-4-hy­droxy­benzene­sulfonate 3-carboxyl­ato-4-hy­droxy­benzene­sulfonate

Proton-transfer compounds with 4-amino-N-(4,6-di­methyl­pyrimidin-2-yl)benzene­sulfonamide (sulfa­meth­azine): the structures and hydrogen bonding in the salts with 5-nitro­salicylic acid and picric acid

A chain of π-stacked mol­ecules in 4-(2-chloro­phenyl)­pyrrolo­[1,2-a]quinoxaline and a hydrogen-bonded sheet in (4RS)-4-(1,3-1,3-benzo­dioxol-6-yl)-4,5-di­hydro­pyrrolo­[1,2-a]quinoxaline

Five N′-benzyl­idene-N-methyl­pyrazine-2-carbohydrazides

A water wire in L-prolyl-L-serine monohydrate

Tri­benzyl­phosphane and its hydro­chloride salt, tri­benzyl­phospho­nium hydrogen di­chlo­ride–tri­benzyl­phosphane (1/1)