Figure 2
(a) The asymmetric unit of complex (II) represented with displacement ellipsoids at the 50% probability level. H atoms not involved in hydrogen bonding are omitted for clarity. The donor–acceptor distances are shown as green for intramolecular hydrogen bonds and shown as blue for intermolecular hydrogen bonds (O10–O15) and inter-asymmetric unit hydrogen bonds (O9 –O13). Additional symmetry-related atoms O10 and O15 were generated by the symmetry operator 1 − x, −y, 1 − z, and O9 and O13 were generated via the inversion center 1 − x, 1 − y, 1 − z at the center of the hexanuclear complex. (b) The asymmetric unit of complex (II) oriented to show donor–acceptor distances of intramolecular hydrogen bonds, in green, of the protonated dhbp ligands. |