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Acta Cryst. (2008). E64, m703    [ doi:10.1107/S1600536808010763 ]

Bis[1,3-bis(diphenylphosphino)propane-[kappa]2P:P']silver(I) bis(chlorodifluoroacetato-[kappa]O)triphenylstannate(IV)

Y. Y. Teo, K. M. Lo and S. W. Ng

Abstract top

In the title salt, [Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)], the AgI atom exists in a tetrahedral coordination geometry formed by four P atoms [Ag-P = 2.460 (1)-2.501 (1) Å], whereas the SnIV atom exists in a trans-trigonal-bipyramidal coordination geometry formed by two O [Sn-O = 2.208 (3) and 2.233 (3) Å] and three C atoms [Sn-C = 2.115 (4)-2.128 (4) Å;([Sigma] C-Sn-C)= 360.0 (6)°].

Comment top

The structural chemistry of di(carboxylato)triorganostannates has been reviewed by Tiekink (1991, 1994). This study continues our studies on bis(chlorodifluoroacetato)triorganostannates (Ng & Hook, 1999; Teo et al., 2004, 2007, 2008). One of these studies used the bis[1,3-bis(diphenylphosphine)ethane]silver cation as counterion. Herewith we present the crystal structure of the title compound, (I), where [Ag(Ph2(CH2)3Ph2)2] cation is the counterion for [SnPh3(ClF2CCO2)2] anion (Scheme I).

In (I) (Fig. 1), the silver(I) and tin(IV) atoms show tetrahedral and trans-trigonal bipyramidal coordinations, respectively.

Related literature top

For the crystal structures of other bis(chlorodifluoroacetato)triorganostannates, see: Ng & Hook (1999); Teo et al. (2004, 2007, 2008). The structural chemistry of organotin carboxylates has been reviewed by Tiekink (1991, 1994).

Experimental top

Triphenyltin hydroxide (0.18 g, 0.5 mmol) and chorodifluoroacetic acid (0.05 ml, 0.5 mmol) were dissolved in dichloromethane/methanol (25 ml). The mixture was heated until the hydroxide dissolved completely. Another solution containing 1,3-bis(diphenylphosphino)propane (0.41 g, 1.0 mmol) and silver trifluoroacetate (0.11 g, 0.5 mmol) was prepared; this was also heated until the reagents dissolved completely. The two solutions were mixed; crystals were obtained by allowing the solvent to evaporate in about 70% yield.

Refinement top

Carbon-bound H-atoms were placed in calculated positions (C—H 0.95 to 0.99 Å) and were included in the refinement in the riding model approximation, with U(H) set to 1.2Ueq(C).

One of the phenyl rings shows large displacement ellipsoids. This ring, C44-C49, was restrained to be nearly planar; the bonded C-atoms were restrained to 1.39 (1) Å and 1,4-related ones to 2.78 (1) Å. The anisotropic displacement parameters of atoms C44-C49 were restrained to be nearly isotropic.

Computing details top

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2008).

Figures top
[Figure 1] Fig. 1. The 70% probability displacement ellipsoids plot (Barbour, 2001) of (I). Hydrogen atoms are drawn as spheres of arbitrary radii.
Bis[1,3-bis(diphenylphosphino)propane-κ2P:P']silver(I) bis(chlorodifluoroacetato-κO)triphenylstannate(IV) top
Crystal data top
[Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)]Z = 2
Mr = 1541.64F000 = 1564
Triclinic, P1Dx = 1.490 Mg m−3
Hall symbol: -P 1Mo Kα radiation
λ = 0.71073 Å
a = 10.5554 (2) ÅCell parameters from 4777 reflections
b = 17.6600 (4) Åθ = 2.2–24º
c = 19.1383 (4) ŵ = 0.88 mm−1
α = 91.581 (1)ºT = 100 (2) K
β = 94.931 (1)ºBlock, colourless
γ = 104.535 (1)º0.18 × 0.12 × 0.05 mm
V = 3436.1 (1) Å3
Data collection top
Bruker SMART APEX
diffractometer		15398 independent reflections
Radiation source: fine-focus sealed tube10993 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.065
T = 100(2) Kθmax = 27.5º
ω scansθmin = 1.1º
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		h = −13→13
Tmin = 0.858, Tmax = 0.957k = −22→18
35712 measured reflectionsl = −24→24
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.049H-atom parameters constrained
wR(F2) = 0.112  w = 1/[σ2(Fo2) + 1.3097P]
where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max = 0.001
15398 reflectionsΔρmax = 0.86 e Å−3
829 parametersΔρmin = −0.76 e Å−3
48 restraintsExtinction correction: none
Primary atom site location: structure-invariant direct methods
Crystal data top
[Ag(C27H26P2)2][Sn(C6H5)3(C2ClF2O2)]γ = 104.535 (1)º
Mr = 1541.64V = 3436.1 (1) Å3
Triclinic, P1Z = 2
a = 10.5554 (2) ÅMo Kα
b = 17.6600 (4) ŵ = 0.88 mm−1
c = 19.1383 (4) ÅT = 100 (2) K
α = 91.581 (1)º0.18 × 0.12 × 0.05 mm
β = 94.931 (1)º
Data collection top
Bruker SMART APEX
diffractometer		15398 independent reflections
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)		10993 reflections with I > 2σ(I)
Tmin = 0.858, Tmax = 0.957Rint = 0.065
35712 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04948 restraints
wR(F2) = 0.112H-atom parameters constrained
S = 1.05Δρmax = 0.86 e Å−3
15398 reflectionsΔρmin = −0.76 e Å−3
829 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.02753 (3)0.730942 (18)0.273935 (14)0.01420 (8)
Ag10.41787 (3)0.227571 (19)0.254989 (15)0.01370 (8)
Cl1−0.23532 (11)0.56238 (7)0.09181 (6)0.0289 (3)
Cl20.08334 (11)0.88104 (8)0.50499 (6)0.0294 (3)
P10.21513 (10)0.14129 (7)0.19532 (5)0.0140 (2)
P20.30050 (10)0.27516 (7)0.34838 (5)0.0164 (2)
P30.56274 (10)0.32427 (7)0.18763 (6)0.0154 (2)
P40.59289 (10)0.17736 (7)0.31680 (6)0.0153 (2)
F1−0.0366 (3)0.56467 (16)0.02666 (12)0.0289 (6)
F2−0.0553 (3)0.49132 (16)0.11555 (13)0.0301 (6)
F3−0.1207 (3)0.92144 (19)0.46015 (14)0.0399 (8)
F40.0540 (3)0.97475 (16)0.41018 (14)0.0335 (7)
O1−0.0013 (3)0.62288 (17)0.20477 (14)0.0173 (6)
O20.0963 (3)0.68053 (19)0.11296 (15)0.0253 (7)
O30.0474 (3)0.83204 (18)0.34826 (14)0.0202 (7)
O4−0.1681 (3)0.8079 (2)0.36239 (16)0.0278 (8)
C1−0.0392 (4)0.6519 (3)0.3528 (2)0.0168 (9)
C2−0.1432 (4)0.5862 (3)0.3396 (2)0.0245 (10)
H2−0.18910.57590.29400.029*
C3−0.1815 (4)0.5347 (3)0.3923 (2)0.0291 (11)
H3−0.25410.49020.38290.035*
C4−0.1132 (5)0.5486 (3)0.4585 (2)0.0265 (11)
H4−0.13820.51360.49470.032*
C5−0.0085 (5)0.6138 (3)0.4714 (2)0.0277 (11)
H50.03940.62320.51640.033*
C60.0270 (4)0.6650 (3)0.4197 (2)0.0237 (10)
H60.09820.71010.42970.028*
C70.2352 (4)0.7673 (3)0.2721 (2)0.0147 (9)
C80.3074 (4)0.7132 (3)0.2625 (2)0.0228 (10)
H80.26380.65920.25480.027*
C90.4436 (4)0.7373 (3)0.2641 (2)0.0243 (10)
H90.49270.69940.25990.029*
C100.5081 (4)0.8157 (3)0.2717 (2)0.0223 (10)
H100.60090.83190.27140.027*
C110.4365 (4)0.8706 (3)0.2799 (2)0.0211 (10)
H110.47950.92490.28430.025*
C120.3011 (4)0.8455 (3)0.2815 (2)0.0185 (9)
H120.25260.88310.28930.022*
C13−0.0893 (4)0.7739 (3)0.1972 (2)0.0152 (9)
C14−0.2241 (4)0.7448 (3)0.1842 (2)0.0241 (10)
H14−0.26830.70570.21300.029*
C15−0.2964 (4)0.7710 (3)0.1308 (2)0.0263 (11)
H15−0.38900.75040.12360.032*
C16−0.2335 (4)0.8270 (3)0.0883 (2)0.0286 (12)
H16−0.28240.84420.05070.034*
C17−0.0999 (5)0.8582 (3)0.1001 (2)0.0344 (13)
H17−0.05680.89770.07120.041*
C18−0.0276 (4)0.8320 (3)0.1543 (2)0.0277 (11)
H180.06460.85380.16220.033*
C190.0206 (4)0.6297 (3)0.1401 (2)0.0171 (9)
C20−0.0680 (4)0.5614 (3)0.0928 (2)0.0212 (10)
C21−0.0532 (4)0.8413 (3)0.3756 (2)0.0185 (9)
C22−0.0145 (4)0.9070 (3)0.4342 (2)0.0228 (10)
C230.1159 (4)0.1904 (3)0.1391 (2)0.0155 (9)
C240.1817 (4)0.2448 (3)0.0947 (2)0.0197 (10)
H240.27490.25670.09670.024*
C250.1131 (4)0.2815 (3)0.0481 (2)0.0256 (11)
H250.15880.31800.01750.031*
C26−0.0226 (4)0.2651 (3)0.0458 (2)0.0264 (11)
H26−0.07000.29040.01360.032*
C27−0.0893 (4)0.2119 (3)0.0902 (2)0.0229 (10)
H27−0.18230.20170.08920.028*
C28−0.0209 (4)0.1735 (3)0.1364 (2)0.0192 (9)
H28−0.06700.13600.16600.023*
C290.2263 (4)0.0595 (3)0.1382 (2)0.0158 (9)
C300.1691 (4)0.0471 (3)0.0691 (2)0.0195 (10)
H300.11660.08000.05120.023*
C310.1881 (4)−0.0129 (3)0.0260 (2)0.0251 (11)
H310.1506−0.0197−0.02140.030*
C320.2605 (4)−0.0625 (3)0.0513 (2)0.0246 (10)
H320.2705−0.10450.02200.030*
C330.3193 (4)−0.0510 (3)0.1201 (2)0.0249 (11)
H330.3708−0.08460.13760.030*
C340.3023 (4)0.0096 (3)0.1626 (2)0.0223 (10)
H340.34310.01740.20940.027*
C350.1064 (4)0.0964 (3)0.2607 (2)0.0182 (9)
H350.07740.04130.26410.022*
C360.0654 (4)0.1549 (3)0.3099 (2)0.0204 (10)
H36A0.04310.19630.28100.025*
H36B−0.01590.12690.32980.025*
C370.1649 (4)0.1948 (3)0.3706 (2)0.0193 (10)
H37A0.20290.15460.39310.023*
H37B0.11720.21540.40600.023*
C380.2178 (4)0.3504 (3)0.3206 (2)0.0174 (9)
C390.2053 (4)0.3658 (3)0.2501 (2)0.0208 (10)
H390.24140.33800.21710.025*
C400.1405 (4)0.4214 (3)0.2269 (2)0.0220 (10)
H400.13030.43030.17820.026*
C410.0911 (4)0.4635 (3)0.2747 (2)0.0260 (11)
H410.04820.50220.25930.031*
C420.1047 (5)0.4489 (3)0.3456 (2)0.0372 (14)
H420.07150.47810.37880.045*
C430.1659 (5)0.3927 (3)0.3679 (2)0.0324 (13)
H430.17280.38250.41640.039*
C440.3843 (4)0.3140 (3)0.4337 (2)0.0210 (10)
C450.4909 (5)0.3775 (3)0.4357 (2)0.0566 (18)
H45A0.46070.41950.41140.068*
H45B0.55500.36250.40690.068*
C460.5602 (5)0.4111 (3)0.4991 (3)0.085 (3)
H460.63360.45520.49940.102*
C470.5213 (5)0.3798 (3)0.5610 (2)0.0516 (16)
H470.56830.40220.60440.062*
C480.4156 (4)0.3168 (3)0.5608 (2)0.0359 (13)
H480.38900.29550.60380.043*
C490.3468 (4)0.2837 (3)0.4974 (2)0.0298 (11)
H490.27330.23980.49760.036*
C500.6527 (4)0.0962 (3)0.2826 (2)0.0179 (9)
C510.6416 (4)0.0806 (3)0.2098 (2)0.0214 (10)
H510.59980.11030.17920.026*
C520.6915 (4)0.0218 (3)0.1824 (3)0.0275 (11)
H520.68500.01190.13310.033*
C530.7504 (4)−0.0222 (3)0.2263 (3)0.0293 (12)
H530.7842−0.06240.20710.035*
C540.7605 (4)−0.0080 (3)0.2983 (3)0.0295 (12)
H540.8009−0.03880.32850.035*
C550.7116 (4)0.0513 (3)0.3266 (2)0.0220 (10)
H550.71880.06090.37610.026*
C560.5544 (4)0.1494 (3)0.4043 (2)0.0180 (9)
C570.4425 (4)0.0884 (3)0.4092 (2)0.0232 (10)
H570.39460.06170.36760.028*
C580.4006 (4)0.0663 (3)0.4738 (2)0.0278 (11)
H580.32550.02390.47630.033*
C590.4674 (5)0.1057 (3)0.5348 (2)0.0315 (12)
H590.43720.09110.57910.038*
C600.5778 (5)0.1660 (3)0.5311 (2)0.0327 (12)
H600.62460.19280.57300.039*
C610.6211 (4)0.1882 (3)0.4658 (2)0.0245 (10)
H610.69700.23010.46370.029*
C620.7435 (4)0.2573 (3)0.3283 (2)0.0179 (9)
H62A0.72770.30020.35790.022*
H62B0.81410.23810.35360.022*
C630.7910 (4)0.2905 (3)0.2587 (2)0.0165 (9)
H63A0.88780.31070.26520.020*
H63B0.77030.24700.22240.020*
C640.7316 (4)0.3561 (3)0.2311 (2)0.0183 (9)
H64A0.78930.38520.19740.022*
H64B0.73210.39310.27100.022*
C650.5173 (4)0.4162 (3)0.1735 (2)0.0160 (9)
C660.4562 (4)0.4311 (3)0.1095 (2)0.0223 (10)
H660.44270.39410.07090.027*
C670.4145 (4)0.5001 (3)0.1019 (2)0.0245 (11)
H670.37480.51050.05800.029*
C680.4318 (5)0.5522 (3)0.1582 (3)0.0305 (12)
H680.40230.59850.15330.037*
C690.4916 (5)0.5385 (3)0.2223 (2)0.0310 (12)
H690.50440.57550.26090.037*
C700.5325 (4)0.4702 (3)0.2293 (2)0.0227 (10)
H700.57200.46030.27340.027*
C710.5872 (4)0.2907 (3)0.0999 (2)0.0154 (9)
C720.6675 (4)0.3406 (3)0.0568 (2)0.0187 (9)
H720.71130.39250.07350.022*
C730.6833 (4)0.3150 (3)−0.0097 (2)0.0214 (10)
H730.73630.3496−0.03900.026*
C740.6222 (4)0.2389 (3)−0.0339 (2)0.0245 (11)
H740.63490.2212−0.07940.029*
C750.5432 (4)0.1889 (3)0.0076 (2)0.0225 (10)
H750.50110.1367−0.00920.027*
C760.5250 (4)0.2150 (3)0.0746 (2)0.0180 (9)
H760.46960.18070.10310.022*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.01322 (14)0.01595 (17)0.01312 (15)0.00299 (12)0.00177 (11)0.00034 (12)
Ag10.01216 (15)0.01514 (18)0.01399 (16)0.00362 (13)0.00165 (12)0.00158 (13)
Cl10.0229 (6)0.0264 (7)0.0336 (7)0.0011 (5)−0.0020 (5)0.0000 (5)
Cl20.0327 (6)0.0326 (7)0.0199 (6)0.0051 (5)−0.0038 (5)−0.0009 (5)
P10.0130 (5)0.0145 (6)0.0143 (5)0.0029 (4)0.0007 (4)0.0020 (5)
P20.0162 (5)0.0194 (6)0.0145 (5)0.0057 (5)0.0034 (4)0.0006 (5)
P30.0160 (5)0.0140 (6)0.0155 (6)0.0025 (5)0.0017 (4)0.0011 (5)
P40.0131 (5)0.0161 (6)0.0164 (6)0.0036 (5)0.0001 (4)0.0023 (5)
F10.0449 (16)0.0296 (17)0.0143 (13)0.0131 (14)0.0064 (12)−0.0045 (12)
F20.0426 (16)0.0179 (16)0.0309 (15)0.0121 (13)−0.0032 (12)0.0003 (12)
F30.0325 (16)0.055 (2)0.0360 (17)0.0216 (15)0.0027 (13)−0.0212 (15)
F40.0470 (17)0.0209 (17)0.0308 (16)0.0071 (14)−0.0009 (13)−0.0018 (13)
O10.0225 (15)0.0171 (17)0.0119 (14)0.0036 (13)0.0036 (12)−0.0004 (13)
O20.0261 (17)0.026 (2)0.0215 (17)−0.0005 (15)0.0089 (13)0.0020 (15)
O30.0196 (15)0.0210 (18)0.0205 (16)0.0057 (13)0.0043 (12)−0.0019 (14)
O40.0175 (16)0.034 (2)0.0298 (18)0.0040 (15)0.0013 (13)−0.0066 (16)
C10.019 (2)0.020 (3)0.013 (2)0.0068 (19)0.0038 (16)0.0006 (19)
C20.025 (2)0.029 (3)0.017 (2)0.003 (2)0.0011 (18)0.002 (2)
C30.025 (2)0.026 (3)0.031 (3)−0.005 (2)0.005 (2)0.005 (2)
C40.037 (3)0.027 (3)0.020 (2)0.013 (2)0.012 (2)0.010 (2)
C50.036 (3)0.028 (3)0.019 (2)0.008 (2)−0.002 (2)0.006 (2)
C60.028 (2)0.022 (3)0.019 (2)0.003 (2)−0.0019 (19)−0.003 (2)
C70.0094 (18)0.018 (2)0.014 (2)−0.0011 (17)−0.0001 (15)0.0000 (18)
C80.018 (2)0.018 (3)0.031 (3)0.0037 (19)0.0032 (19)−0.004 (2)
C90.016 (2)0.019 (3)0.038 (3)0.007 (2)0.0031 (19)−0.003 (2)
C100.014 (2)0.028 (3)0.024 (2)0.005 (2)0.0010 (18)0.000 (2)
C110.017 (2)0.017 (3)0.027 (2)−0.0002 (19)−0.0009 (18)0.003 (2)
C120.017 (2)0.017 (2)0.023 (2)0.0062 (19)0.0043 (17)0.004 (2)
C130.019 (2)0.014 (2)0.012 (2)0.0052 (18)−0.0009 (16)−0.0007 (18)
C140.020 (2)0.021 (3)0.032 (3)0.004 (2)0.0048 (19)0.009 (2)
C150.014 (2)0.028 (3)0.035 (3)0.004 (2)−0.0036 (19)0.003 (2)
C160.026 (2)0.040 (3)0.022 (2)0.014 (2)−0.0053 (19)0.004 (2)
C170.027 (3)0.044 (4)0.032 (3)0.006 (2)0.003 (2)0.021 (3)
C180.020 (2)0.030 (3)0.030 (3)0.000 (2)0.0010 (19)0.013 (2)
C190.020 (2)0.018 (3)0.015 (2)0.0077 (19)0.0034 (17)0.0015 (19)
C200.027 (2)0.014 (2)0.023 (2)0.006 (2)0.0040 (19)0.003 (2)
C210.025 (2)0.020 (3)0.014 (2)0.010 (2)0.0025 (17)0.0058 (19)
C220.020 (2)0.022 (3)0.027 (3)0.008 (2)−0.0014 (19)−0.002 (2)
C230.019 (2)0.013 (2)0.014 (2)0.0039 (18)−0.0011 (16)−0.0006 (18)
C240.017 (2)0.022 (3)0.021 (2)0.0057 (19)0.0027 (17)0.002 (2)
C250.028 (2)0.026 (3)0.027 (3)0.011 (2)0.005 (2)0.015 (2)
C260.024 (2)0.038 (3)0.022 (2)0.016 (2)0.0017 (19)0.004 (2)
C270.018 (2)0.036 (3)0.016 (2)0.012 (2)−0.0037 (17)−0.002 (2)
C280.018 (2)0.020 (3)0.018 (2)0.0033 (19)0.0011 (17)0.000 (2)
C290.017 (2)0.016 (2)0.013 (2)0.0013 (18)0.0039 (16)0.0049 (18)
C300.018 (2)0.020 (3)0.022 (2)0.0084 (19)−0.0018 (17)0.001 (2)
C310.027 (2)0.031 (3)0.018 (2)0.010 (2)−0.0003 (19)0.001 (2)
C320.027 (2)0.020 (3)0.027 (3)0.006 (2)0.006 (2)−0.007 (2)
C330.025 (2)0.021 (3)0.031 (3)0.010 (2)0.004 (2)0.003 (2)
C340.021 (2)0.027 (3)0.019 (2)0.010 (2)−0.0058 (18)0.000 (2)
C350.022 (2)0.014 (2)0.018 (2)−0.0008 (18)0.0095 (17)0.0034 (19)
C360.017 (2)0.026 (3)0.018 (2)0.0040 (19)0.0037 (17)0.002 (2)
C370.023 (2)0.024 (3)0.012 (2)0.009 (2)0.0033 (17)0.0010 (19)
C380.020 (2)0.018 (2)0.016 (2)0.0072 (19)0.0037 (17)0.0048 (19)
C390.023 (2)0.024 (3)0.017 (2)0.008 (2)0.0058 (18)0.000 (2)
C400.028 (2)0.024 (3)0.013 (2)0.006 (2)−0.0013 (18)0.001 (2)
C410.028 (2)0.018 (3)0.036 (3)0.011 (2)0.004 (2)0.008 (2)
C420.061 (4)0.038 (4)0.024 (3)0.033 (3)0.004 (2)−0.003 (2)
C430.052 (3)0.037 (3)0.018 (2)0.026 (3)0.010 (2)0.007 (2)
C440.021 (2)0.029 (3)0.014 (2)0.008 (2)0.0034 (17)−0.0028 (19)
C450.056 (4)0.068 (5)0.026 (3)−0.022 (3)0.007 (3)−0.002 (3)
C460.073 (4)0.108 (6)0.034 (3)−0.047 (4)0.003 (3)−0.011 (4)
C470.045 (3)0.072 (5)0.023 (3)−0.007 (3)−0.003 (2)−0.010 (3)
C480.045 (3)0.040 (3)0.021 (3)0.008 (3)0.001 (2)0.008 (2)
C490.037 (3)0.032 (3)0.019 (2)0.008 (2)−0.001 (2)0.003 (2)
C500.0111 (19)0.015 (2)0.027 (2)0.0020 (17)0.0006 (17)0.0003 (19)
C510.019 (2)0.023 (3)0.024 (2)0.004 (2)0.0077 (18)0.006 (2)
C520.029 (3)0.019 (3)0.032 (3)−0.001 (2)0.014 (2)−0.005 (2)
C530.019 (2)0.015 (3)0.053 (3)0.000 (2)0.011 (2)−0.007 (2)
C540.012 (2)0.016 (3)0.059 (4)0.0017 (19)−0.004 (2)0.005 (2)
C550.013 (2)0.025 (3)0.025 (2)0.0022 (19)−0.0049 (17)0.001 (2)
C560.014 (2)0.021 (3)0.022 (2)0.0112 (19)0.0004 (17)0.007 (2)
C570.021 (2)0.024 (3)0.024 (2)0.006 (2)−0.0025 (18)0.004 (2)
C580.026 (2)0.029 (3)0.031 (3)0.007 (2)0.011 (2)0.018 (2)
C590.040 (3)0.040 (3)0.018 (2)0.013 (3)0.010 (2)0.011 (2)
C600.040 (3)0.039 (3)0.020 (3)0.010 (3)0.004 (2)0.007 (2)
C610.025 (2)0.026 (3)0.020 (2)0.003 (2)0.0018 (19)0.008 (2)
C620.019 (2)0.016 (2)0.018 (2)0.0033 (18)−0.0002 (17)0.0016 (19)
C630.0113 (19)0.017 (2)0.020 (2)0.0021 (17)0.0008 (16)−0.0005 (19)
C640.020 (2)0.018 (2)0.014 (2)0.0021 (19)0.0011 (17)−0.0015 (19)
C650.016 (2)0.016 (2)0.015 (2)0.0003 (18)0.0032 (16)0.0011 (18)
C660.022 (2)0.022 (3)0.020 (2)0.002 (2)0.0018 (18)−0.008 (2)
C670.030 (2)0.020 (3)0.026 (3)0.012 (2)0.000 (2)−0.001 (2)
C680.038 (3)0.021 (3)0.036 (3)0.012 (2)0.005 (2)0.006 (2)
C690.046 (3)0.026 (3)0.022 (3)0.012 (3)0.002 (2)−0.004 (2)
C700.031 (2)0.016 (3)0.021 (2)0.006 (2)0.0006 (19)0.000 (2)
C710.0111 (19)0.019 (2)0.016 (2)0.0042 (18)−0.0014 (16)0.0001 (19)
C720.018 (2)0.017 (2)0.021 (2)0.0038 (19)0.0001 (17)0.005 (2)
C730.021 (2)0.028 (3)0.021 (2)0.012 (2)0.0069 (18)0.008 (2)
C740.025 (2)0.039 (3)0.017 (2)0.022 (2)0.0037 (18)0.001 (2)
C750.022 (2)0.023 (3)0.024 (2)0.013 (2)−0.0079 (18)−0.010 (2)
C760.0110 (19)0.021 (3)0.022 (2)0.0046 (18)0.0010 (17)0.002 (2)
Geometric parameters (Å, °) top
Sn1—C12.128 (4)C33—C341.384 (6)
Sn1—C72.128 (4)C33—H330.9500
Sn1—C132.115 (4)C34—H340.9500
Sn1—O12.233 (3)C35—C361.543 (6)
Sn1—O32.208 (3)C35—H350.9500
Ag1—P12.460 (1)C36—C371.524 (6)
Ag1—P22.501 (1)C36—H36A0.9900
Ag1—P32.463 (1)C36—H36B0.9900
Ag1—P42.470 (1)C37—H37A0.9900
Cl1—C201.769 (4)C37—H37B0.9900
Cl2—C221.773 (4)C38—C391.385 (5)
P1—C291.821 (4)C38—C431.390 (6)
P1—C231.822 (4)C39—C401.392 (6)
P1—C351.833 (4)C39—H390.9500
P2—C441.818 (4)C40—C411.379 (6)
P2—C381.831 (4)C40—H400.9500
P2—C371.834 (5)C41—C421.390 (6)
P3—C651.825 (4)C41—H410.9500
P3—C711.827 (4)C42—C431.373 (6)
P3—C641.845 (4)C42—H420.9500
P4—C561.810 (4)C43—H430.9500
P4—C501.831 (4)C44—C451.373 (6)
P4—C621.835 (4)C44—C491.394 (6)
F1—C201.334 (5)C45—C461.396 (6)
F2—C201.358 (5)C45—H45A0.9900
F3—C221.342 (4)C45—H45B0.9900
F4—C221.348 (5)C46—C471.373 (6)
O1—C191.282 (4)C46—H460.9500
O2—C191.204 (5)C47—C481.363 (6)
O3—C211.268 (4)C47—H470.9500
O4—C211.209 (5)C48—C491.391 (5)
C1—C21.382 (6)C48—H480.9500
C1—C61.390 (6)C49—H490.9500
C2—C31.395 (6)C50—C551.386 (5)
C2—H20.9500C50—C511.403 (6)
C3—C41.386 (6)C51—C521.386 (6)
C3—H30.9500C51—H510.9500
C4—C51.381 (7)C52—C531.371 (6)
C4—H40.9500C52—H520.9500
C5—C61.371 (6)C53—C541.385 (7)
C5—H50.9500C53—H530.9500
C6—H60.9500C54—C551.396 (6)
C7—C121.380 (6)C54—H540.9500
C7—C81.382 (5)C55—H550.9500
C8—C91.391 (6)C56—C611.386 (6)
C8—H80.9500C56—C571.396 (6)
C9—C101.378 (6)C57—C581.381 (6)
C9—H90.9500C57—H570.9500
C10—C111.384 (6)C58—C591.382 (7)
C10—H100.9500C58—H580.9500
C11—C121.390 (5)C59—C601.376 (7)
C11—H110.9500C59—H590.9500
C12—H120.9500C60—C611.399 (6)
C13—C141.384 (6)C60—H600.9500
C13—C181.398 (6)C61—H610.9500
C14—C151.382 (6)C62—C631.542 (5)
C14—H140.9500C62—H62A0.9900
C15—C161.375 (7)C62—H62B0.9900
C15—H150.9500C63—C641.535 (5)
C16—C171.376 (6)C63—H63A0.9900
C16—H160.9500C63—H63B0.9900
C17—C181.393 (6)C64—H64A0.9900
C17—H170.9500C64—H64B0.9900
C18—H180.9500C65—C701.383 (6)
C19—C201.543 (6)C65—C661.396 (6)
C21—C221.544 (6)C66—C671.402 (6)
C23—C241.392 (6)C66—H660.9500
C23—C281.394 (5)C67—C681.368 (6)
C24—C251.378 (5)C67—H670.9500
C24—H240.9500C68—C691.386 (6)
C25—C261.385 (6)C68—H680.9500
C25—H250.9500C69—C701.385 (6)
C26—C271.385 (6)C69—H690.9500
C26—H260.9500C70—H700.9500
C27—C281.390 (5)C71—C761.385 (6)
C27—H270.9500C71—C721.400 (6)
C28—H280.9500C72—C731.375 (6)
C29—C301.394 (6)C72—H720.9500
C29—C341.396 (5)C73—C741.384 (7)
C30—C311.389 (6)C73—H730.9500
C30—H300.9500C74—C751.375 (7)
C31—C321.371 (6)C74—H740.9500
C31—H310.9500C75—C761.396 (5)
C32—C331.393 (6)C75—H750.9500
C32—H320.9500C76—H760.9500
C1—Sn1—C7115.2 (2)C33—C34—C29121.3 (4)
C1—Sn1—C13127.2 (2)C33—C34—H34119.4
C1—Sn1—O184.9 (1)C29—C34—H34119.4
C1—Sn1—O390.8 (1)C36—C35—P1114.9 (3)
C7—Sn1—C13117.6 (2)C36—C35—H35122.5
C7—Sn1—O195.8 (1)P1—C35—H35122.5
C7—Sn1—O386.9 (1)C37—C36—C35117.3 (3)
C13—Sn1—O393.2 (1)C37—C36—H36A108.0
C13—Sn1—O188.7 (1)C35—C36—H36A108.0
O1—Sn1—O3175.6 (1)C37—C36—H36B108.0
P1—Ag1—P293.58 (4)C35—C36—H36B108.0
P1—Ag1—P3119.54 (4)H36A—C36—H36B107.2
P1—Ag1—P4122.91 (4)C36—C37—P2116.3 (3)
P2—Ag1—P3118.95 (4)C36—C37—H37A108.2
P2—Ag1—P4106.23 (4)P2—C37—H37A108.2
P3—Ag1—P496.64 (4)C36—C37—H37B108.2
C29—P1—C23102.35 (18)P2—C37—H37B108.2
C29—P1—C35104.7 (2)H37A—C37—H37B107.4
C23—P1—C35104.52 (18)C39—C38—C43118.5 (4)
C29—P1—Ag1119.20 (13)C39—C38—P2119.3 (3)
C23—P1—Ag1115.03 (15)C43—C38—P2122.2 (3)
C35—P1—Ag1109.63 (14)C38—C39—C40120.9 (4)
C44—P2—C38103.21 (19)C38—C39—H39119.6
C44—P2—C37103.13 (19)C40—C39—H39119.6
C38—P2—C37103.20 (19)C41—C40—C39119.9 (4)
C44—P2—Ag1121.75 (12)C41—C40—H40120.1
C38—P2—Ag1114.10 (13)C39—C40—H40120.1
C37—P2—Ag1109.46 (14)C40—C41—C42119.5 (4)
C65—P3—C71103.91 (18)C40—C41—H41120.3
C65—P3—C64103.5 (2)C42—C41—H41120.3
C71—P3—C64103.10 (18)C43—C42—C41120.4 (4)
C65—P3—Ag1116.75 (13)C43—C42—H42119.8
C71—P3—Ag1115.99 (15)C41—C42—H42119.8
C64—P3—Ag1112.00 (14)C42—C43—C38120.9 (4)
C56—P4—C50103.42 (19)C42—C43—H43119.6
C56—P4—C62106.1 (2)C38—C43—H43119.6
C50—P4—C62102.09 (19)C45—C44—C49117.7 (4)
C56—P4—Ag1111.49 (12)C45—C44—P2118.1 (3)
C50—P4—Ag1124.14 (14)C49—C44—P2124.3 (3)
C62—P4—Ag1108.08 (13)C44—C45—C46121.6 (4)
C19—O1—Sn1119.0 (3)C44—C45—H45A106.9
C21—O3—Sn1119.3 (3)C46—C45—H45A106.9
C2—C1—C6118.3 (4)C44—C45—H45B106.9
C2—C1—Sn1122.7 (3)C46—C45—H45B106.9
C6—C1—Sn1118.9 (3)H45A—C45—H45B106.7
C1—C2—C3120.9 (4)C47—C46—C45119.3 (5)
C1—C2—H2119.6C47—C46—H46120.3
C3—C2—H2119.6C45—C46—H46120.3
C4—C3—C2119.8 (5)C48—C47—C46120.4 (5)
C4—C3—H3120.1C48—C47—H47119.8
C2—C3—H3120.1C46—C47—H47119.8
C5—C4—C3119.3 (4)C47—C48—C49119.9 (4)
C5—C4—H4120.4C47—C48—H48120.0
C3—C4—H4120.4C49—C48—H48120.0
C6—C5—C4120.6 (4)C48—C49—C44121.0 (4)
C6—C5—H5119.7C48—C49—H49119.5
C4—C5—H5119.7C44—C49—H49119.5
C5—C6—C1121.1 (5)C55—C50—C51119.2 (4)
C5—C6—H6119.5C55—C50—P4121.8 (3)
C1—C6—H6119.5C51—C50—P4119.0 (3)
C12—C7—C8118.5 (4)C52—C51—C50120.1 (4)
C12—C7—Sn1120.7 (3)C52—C51—H51120.0
C8—C7—Sn1120.8 (3)C50—C51—H51120.0
C7—C8—C9120.3 (4)C53—C52—C51120.4 (4)
C7—C8—H8119.8C53—C52—H52119.8
C9—C8—H8119.8C51—C52—H52119.8
C10—C9—C8120.7 (4)C52—C53—C54120.1 (4)
C10—C9—H9119.7C52—C53—H53119.9
C8—C9—H9119.7C54—C53—H53119.9
C9—C10—C11119.4 (4)C53—C54—C55120.2 (4)
C9—C10—H10120.3C53—C54—H54119.9
C11—C10—H10120.3C55—C54—H54119.9
C10—C11—C12119.3 (4)C50—C55—C54120.0 (4)
C10—C11—H11120.3C50—C55—H55120.0
C12—C11—H11120.3C54—C55—H55120.0
C7—C12—C11121.6 (4)C61—C56—C57118.3 (4)
C7—C12—H12119.2C61—C56—P4124.7 (4)
C11—C12—H12119.2C57—C56—P4116.7 (3)
C14—C13—C18117.4 (4)C58—C57—C56120.9 (4)
C14—C13—Sn1123.6 (3)C58—C57—H57119.6
C18—C13—Sn1118.9 (3)C56—C57—H57119.6
C15—C14—C13122.1 (4)C57—C58—C59120.4 (5)
C15—C14—H14118.9C57—C58—H58119.8
C13—C14—H14118.9C59—C58—H58119.8
C16—C15—C14119.6 (4)C60—C59—C58119.6 (4)
C16—C15—H15120.2C60—C59—H59120.2
C14—C15—H15120.2C58—C59—H59120.2
C15—C16—C17120.1 (4)C59—C60—C61120.1 (5)
C15—C16—H16120.0C59—C60—H60119.9
C17—C16—H16120.0C61—C60—H60119.9
C16—C17—C18120.1 (4)C56—C61—C60120.6 (5)
C16—C17—H17120.0C56—C61—H61119.7
C18—C17—H17120.0C60—C61—H61119.7
C17—C18—C13120.7 (4)C63—C62—P4113.8 (3)
C17—C18—H18119.6C63—C62—H62A108.8
C13—C18—H18119.6P4—C62—H62A108.8
O2—C19—O1129.8 (4)C63—C62—H62B108.8
O2—C19—C20118.3 (4)P4—C62—H62B108.8
O1—C19—C20111.9 (4)H62A—C62—H62B107.7
F1—C20—F2106.7 (3)C64—C63—C62115.4 (3)
F1—C20—C19111.8 (4)C64—C63—H63A108.4
F2—C20—C19111.0 (3)C62—C63—H63A108.4
F1—C20—Cl1108.0 (3)C64—C63—H63B108.4
F2—C20—Cl1108.2 (3)C62—C63—H63B108.4
C19—C20—Cl1111.0 (3)H63A—C63—H63B107.5
O4—C21—O3130.4 (4)C63—C64—P3115.7 (3)
O4—C21—C22118.8 (4)C63—C64—H64A108.4
O3—C21—C22110.9 (4)P3—C64—H64A108.4
F3—C22—F4107.1 (4)C63—C64—H64B108.4
F3—C22—C21111.6 (4)P3—C64—H64B108.4
F4—C22—C21111.4 (3)H64A—C64—H64B107.4
F3—C22—Cl2107.4 (3)C70—C65—C66118.3 (4)
F4—C22—Cl2108.2 (3)C70—C65—P3119.4 (3)
C21—C22—Cl2110.9 (3)C66—C65—P3122.1 (3)
C24—C23—C28119.4 (4)C65—C66—C67120.6 (4)
C24—C23—P1117.1 (3)C65—C66—H66119.7
C28—C23—P1123.4 (3)C67—C66—H66119.7
C25—C24—C23120.7 (4)C68—C67—C66119.3 (4)
C25—C24—H24119.6C68—C67—H67120.3
C23—C24—H24119.6C66—C67—H67120.3
C24—C25—C26119.8 (4)C67—C68—C69121.1 (4)
C24—C25—H25120.1C67—C68—H68119.5
C26—C25—H25120.1C69—C68—H68119.5
C27—C26—C25120.1 (4)C70—C69—C68119.1 (5)
C27—C26—H26119.9C70—C69—H69120.5
C25—C26—H26119.9C68—C69—H69120.5
C26—C27—C28120.3 (4)C65—C70—C69121.6 (4)
C26—C27—H27119.9C65—C70—H70119.2
C28—C27—H27119.9C69—C70—H70119.2
C27—C28—C23119.6 (4)C76—C71—C72118.9 (4)
C27—C28—H28120.2C76—C71—P3120.1 (3)
C23—C28—H28120.2C72—C71—P3121.0 (4)
C30—C29—C34118.0 (4)C73—C72—C71120.5 (4)
C30—C29—P1122.8 (3)C73—C72—H72119.8
C34—C29—P1119.1 (3)C71—C72—H72119.8
C31—C30—C29120.7 (4)C72—C73—C74120.1 (4)
C31—C30—H30119.7C72—C73—H73119.9
C29—C30—H30119.7C74—C73—H73119.9
C32—C31—C30120.6 (4)C75—C74—C73120.4 (4)
C32—C31—H31119.7C75—C74—H74119.8
C30—C31—H31119.7C73—C74—H74119.8
C31—C32—C33119.7 (4)C74—C75—C76119.7 (5)
C31—C32—H32120.1C74—C75—H75120.2
C33—C32—H32120.1C76—C75—H75120.2
C34—C33—C32119.7 (4)C71—C76—C75120.5 (4)
C34—C33—H33120.2C71—C76—H76119.8
C32—C33—H33120.2C75—C76—H76119.8
P3—Ag1—P1—C2975.36 (15)C26—C27—C28—C231.7 (7)
P4—Ag1—P1—C29−46.32 (16)C24—C23—C28—C27−0.8 (6)
P2—Ag1—P1—C29−158.28 (15)P1—C23—C28—C27−177.8 (3)
P3—Ag1—P1—C23−46.74 (14)C23—P1—C29—C301.2 (4)
P4—Ag1—P1—C23−168.42 (14)C35—P1—C29—C30110.0 (4)
P2—Ag1—P1—C2379.62 (14)Ag1—P1—C29—C30−127.0 (3)
P3—Ag1—P1—C35−164.15 (14)C23—P1—C29—C34176.8 (3)
P4—Ag1—P1—C3574.18 (15)C35—P1—C29—C34−74.3 (4)
P2—Ag1—P1—C35−37.79 (15)Ag1—P1—C29—C3448.6 (4)
P1—Ag1—P2—C44156.14 (18)C34—C29—C30—C31−0.3 (6)
P3—Ag1—P2—C44−77.05 (18)P1—C29—C30—C31175.4 (3)
P4—Ag1—P2—C4430.32 (18)C29—C30—C31—C321.8 (7)
P1—Ag1—P2—C38−79.03 (17)C30—C31—C32—C33−2.2 (7)
P3—Ag1—P2—C3847.78 (17)C31—C32—C33—C341.1 (7)
P4—Ag1—P2—C38155.16 (16)C32—C33—C34—C290.4 (7)
P1—Ag1—P2—C3736.01 (14)C30—C29—C34—C33−0.8 (6)
P3—Ag1—P2—C37162.82 (14)P1—C29—C34—C33−176.7 (4)
P4—Ag1—P2—C37−89.80 (14)C29—P1—C35—C36−172.0 (3)
P1—Ag1—P3—C6581.93 (16)C23—P1—C35—C36−64.8 (3)
P4—Ag1—P3—C65−144.06 (16)Ag1—P1—C35—C3659.0 (3)
P2—Ag1—P3—C65−31.36 (16)P1—C35—C36—C37−78.9 (4)
P1—Ag1—P3—C71−41.11 (14)C35—C36—C37—P277.1 (4)
P4—Ag1—P3—C7192.90 (14)C44—P2—C37—C36173.6 (3)
P2—Ag1—P3—C71−154.41 (13)C38—P2—C37—C3666.4 (3)
P1—Ag1—P3—C64−159.07 (15)Ag1—P2—C37—C36−55.4 (3)
P4—Ag1—P3—C64−25.07 (15)C44—P2—C38—C39145.2 (4)
P2—Ag1—P3—C6487.63 (15)C37—P2—C38—C39−107.6 (4)
P1—Ag1—P4—C56−81.76 (17)Ag1—P2—C38—C3911.0 (4)
P3—Ag1—P4—C56146.44 (17)C44—P2—C38—C43−35.2 (5)
P2—Ag1—P4—C5623.66 (17)C37—P2—C38—C4371.9 (4)
P1—Ag1—P4—C5042.89 (17)Ag1—P2—C38—C43−169.4 (4)
P3—Ag1—P4—C50−88.92 (17)C43—C38—C39—C40−1.0 (7)
P2—Ag1—P4—C50148.30 (17)P2—C38—C39—C40178.6 (4)
P1—Ag1—P4—C62162.07 (14)C38—C39—C40—C411.9 (7)
P3—Ag1—P4—C6230.26 (14)C39—C40—C41—C42−1.1 (7)
P2—Ag1—P4—C62−92.52 (14)C40—C41—C42—C43−0.5 (8)
C13—Sn1—O1—C1950.2 (3)C41—C42—C43—C381.4 (9)
C7—Sn1—O1—C19−67.4 (3)C39—C38—C43—C42−0.7 (8)
C1—Sn1—O1—C19177.8 (3)P2—C38—C43—C42179.8 (4)
C13—Sn1—O3—C2167.1 (3)C38—P2—C44—C45−71.1 (3)
C7—Sn1—O3—C21−175.4 (3)C37—P2—C44—C45−178.3 (3)
C1—Sn1—O3—C21−60.2 (3)Ag1—P2—C44—C4558.6 (3)
C13—Sn1—C1—C242.7 (4)C38—P2—C44—C49108.5 (3)
C7—Sn1—C1—C2−135.7 (3)C37—P2—C44—C491.3 (3)
O3—Sn1—C1—C2137.3 (3)Ag1—P2—C44—C49−121.9 (3)
O1—Sn1—C1—C2−41.7 (3)C49—C44—C45—C460.1 (2)
C13—Sn1—C1—C6−139.8 (3)P2—C44—C45—C46179.7 (3)
C7—Sn1—C1—C641.9 (4)C44—C45—C46—C470.2 (3)
O3—Sn1—C1—C6−45.1 (3)C45—C46—C47—C48−0.3 (5)
O1—Sn1—C1—C6135.8 (3)C46—C47—C48—C490.2 (6)
C6—C1—C2—C30.7 (6)C47—C48—C49—C440.0 (6)
Sn1—C1—C2—C3178.2 (3)C45—C44—C49—C48−0.2 (4)
C1—C2—C3—C4−1.2 (7)P2—C44—C49—C48−179.7 (3)
C2—C3—C4—C50.4 (7)C56—P4—C50—C55−27.5 (4)
C3—C4—C5—C60.8 (7)C62—P4—C50—C5582.5 (4)
C4—C5—C6—C1−1.4 (7)Ag1—P4—C50—C55−155.6 (3)
C2—C1—C6—C50.6 (6)C56—P4—C50—C51154.2 (3)
Sn1—C1—C6—C5−177.0 (3)C62—P4—C50—C51−95.8 (4)
C13—Sn1—C7—C1261.2 (4)Ag1—P4—C50—C5126.1 (4)
C1—Sn1—C7—C12−120.2 (3)C55—C50—C51—C52−1.3 (6)
O3—Sn1—C7—C12−30.8 (3)P4—C50—C51—C52177.1 (3)
O1—Sn1—C7—C12152.7 (3)C50—C51—C52—C530.9 (7)
C13—Sn1—C7—C8−119.6 (3)C51—C52—C53—C54−0.1 (7)
C1—Sn1—C7—C858.9 (4)C52—C53—C54—C55−0.4 (7)
O3—Sn1—C7—C8148.3 (3)C51—C50—C55—C540.8 (6)
O1—Sn1—C7—C8−28.2 (3)P4—C50—C55—C54−177.5 (3)
C12—C7—C8—C91.6 (6)C53—C54—C55—C500.0 (7)
Sn1—C7—C8—C9−177.5 (3)C50—P4—C56—C61112.9 (4)
C7—C8—C9—C10−3.3 (7)C62—P4—C56—C615.9 (4)
C8—C9—C10—C111.8 (7)Ag1—P4—C56—C61−111.5 (3)
C9—C10—C11—C121.2 (7)C50—P4—C56—C57−72.6 (3)
C8—C7—C12—C111.5 (6)C62—P4—C56—C57−179.7 (3)
Sn1—C7—C12—C11−179.4 (3)Ag1—P4—C56—C5762.9 (3)
C10—C11—C12—C7−2.9 (6)C61—C56—C57—C58−1.1 (6)
C7—Sn1—C13—C14168.2 (3)P4—C56—C57—C58−175.9 (3)
C1—Sn1—C13—C14−10.1 (4)C56—C57—C58—C591.5 (7)
O3—Sn1—C13—C14−103.6 (4)C57—C58—C59—C60−1.4 (7)
O1—Sn1—C13—C1472.4 (4)C58—C59—C60—C610.8 (7)
C7—Sn1—C13—C18−8.4 (4)C57—C56—C61—C600.5 (6)
C1—Sn1—C13—C18173.3 (3)P4—C56—C61—C60174.9 (3)
O3—Sn1—C13—C1879.9 (4)C59—C60—C61—C56−0.4 (7)
O1—Sn1—C13—C18−104.2 (4)C56—P4—C62—C63−178.9 (3)
C18—C13—C14—C150.6 (7)C50—P4—C62—C6373.1 (3)
Sn1—C13—C14—C15−176.0 (3)Ag1—P4—C62—C63−59.2 (3)
C13—C14—C15—C160.7 (7)P4—C62—C63—C6487.4 (4)
C14—C15—C16—C17−1.7 (8)C62—C63—C64—P3−77.9 (4)
C15—C16—C17—C181.3 (8)C65—P3—C64—C63172.3 (3)
C16—C17—C18—C130.1 (8)C71—P3—C64—C63−79.7 (3)
C14—C13—C18—C17−1.0 (7)Ag1—P3—C64—C6345.7 (3)
Sn1—C13—C18—C17175.8 (4)C71—P3—C65—C70−159.1 (3)
Sn1—O1—C19—O229.7 (6)C64—P3—C65—C70−51.7 (4)
Sn1—O1—C19—C20−149.2 (2)Ag1—P3—C65—C7071.8 (4)
O2—C19—C20—F16.8 (5)C71—P3—C65—C6626.9 (4)
O1—C19—C20—F1−174.1 (3)C64—P3—C65—C66134.3 (3)
O2—C19—C20—F2125.8 (4)Ag1—P3—C65—C66−102.2 (3)
O1—C19—C20—F2−55.1 (4)C70—C65—C66—C671.6 (6)
O2—C19—C20—Cl1−113.8 (4)P3—C65—C66—C67175.7 (3)
O1—C19—C20—Cl165.3 (4)C65—C66—C67—C68−1.4 (7)
Sn1—O3—C21—O4−9.4 (6)C66—C67—C68—C691.1 (7)
Sn1—O3—C21—C22171.0 (2)C67—C68—C69—C70−1.0 (7)
O4—C21—C22—F3−4.1 (6)C66—C65—C70—C69−1.5 (7)
O3—C21—C22—F3175.5 (3)P3—C65—C70—C69−175.8 (4)
O4—C21—C22—F4−123.8 (4)C68—C69—C70—C651.2 (7)
O3—C21—C22—F455.8 (4)C65—P3—C71—C76−129.0 (3)
O4—C21—C22—Cl2115.6 (4)C64—P3—C71—C76123.3 (3)
O3—C21—C22—Cl2−64.8 (4)Ag1—P3—C71—C760.6 (3)
C29—P1—C23—C24−85.8 (4)C65—P3—C71—C7250.4 (3)
C35—P1—C23—C24165.2 (3)C64—P3—C71—C72−57.3 (4)
Ag1—P1—C23—C2445.0 (4)Ag1—P3—C71—C72180.0 (3)
C29—P1—C23—C2891.3 (4)C76—C71—C72—C730.5 (6)
C35—P1—C23—C28−17.7 (4)P3—C71—C72—C73−178.9 (3)
Ag1—P1—C23—C28−137.9 (3)C71—C72—C73—C74−1.5 (6)
C28—C23—C24—C25−0.5 (7)C72—C73—C74—C751.3 (6)
P1—C23—C24—C25176.7 (3)C73—C74—C75—C76−0.2 (6)
C23—C24—C25—C260.9 (7)C72—C71—C76—C750.6 (6)
C24—C25—C26—C270.0 (7)P3—C71—C76—C75180.0 (3)
C25—C26—C27—C28−1.3 (7)C74—C75—C76—C71−0.8 (6)
Acknowledgements top

The authors thank the University of Malaya for funding this study (grant No. SF022155/2007 A) and also for the purchase of the diffractometer.

references
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