Crystal structures of 5-amino-N-phenyl-3H-1,2,4-di­thia­zol-3-iminium chloride and 5-amino-N-(4-chloro­phen­yl)-3H-1,2,4-di­thia­zol-3-iminium chloride monohydrate

Yeo, C.I.; Tan, Y.S.; Tiekink, E.R.T.

doi:10.1107/S2056989015016655

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 6
Detail of the hydrogen bonding operating in the crystal structure of (II)

. The charge-assisted amino-N—H⋯Cl⁻ hydrogen bonds are shown as orange dashed lines and lead to zigzag chains along [001]. The charge-assisted imino-N⁺—H⋯O(water) hydrogen bonds are shown as blue dashed lines and both water-O—H⋯Cl⁻ and water-O—H⋯O(water) hydrogen bonds are shown as brown dashed lines. For reasons of clarity, H atoms not involved in hydrogen bonding have been omitted.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 71| Part 10| September 2015| Pages 1159-1164

doi:10.1107/S2056989015016655

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