Crystal structures of tris­[1-oxo­pyridine-2-olato(1−)]silicon(IV) chloride chloro­form-d1 disolvate, tris­[1-oxo­pyridine-2-olato(1−)]silicon(IV) chloride aceto­nitrile unqu­anti­fied solvate, and fac-tris­[1-oxo­pyridine-2-thiol­ato(1−)]silicon(IV) chloride chloro­form-d1 disolvate

Kraft, B.M.; Brennessel, W.W.; Ryan, A.E.; Benjamin, C.K.

doi:10.1107/S2056989015022203

Acta Crystallographica Section E
Acta Crystallographica
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Figure 3
The structures of the molecular components and the Cl⁻ anion (III)

with displacement ellipsoids drawn at the 50% probability level. All species lie along crystallographic threefold axes, and full molecules are generated with the following symmetry codes. Si(OPTO)₃⁺: (y, z, x) and (z, x, y); CDCl₃ (containing atom C6): (y, z, x) and (z, x, y); CDCl₃ (containing atom C7): (− $[{1\over 2}]$ + z, $[{1\over 2}]$ − x, 1 − y) and ( $[{1\over 2}]$ − y, 1 − z, $[{1\over 2}]$ + x).

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 71| Part 12| December 2015| Pages 1531-1535

https://doi.org/10.1107/S2056989015022203

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